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Journal of Materials Science
Erschienen in: Journal of Materials Science 7/2016

17.12.2015 | Original Paper

Solvothermal synthesis of YBO3:Ce3+, Tb3+ nanophosphor: influence of B/(Y + Ce + Tb) ratio on particle size and photoluminescence intensity

verfasst von: Akihiro Nohara, Satoru Takeshita, Yoshiki Iso, Tetsuhiko Isobe

Erschienen in: Journal of Materials Science | Ausgabe 7/2016

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Abstract

Well-dispersed YBO3:Ce3+, Tb3+ nanoparticles of 30–75 nm in size were prepared by a size-controllable solvothermal method in a 1,4-butanediol/water mixed solvent. The mean particle size could be increased from 32 to 73 nm by increasing the B/(Y + Ce + Tb) ratio in the starting materials from 1 to 3. Transmission electron microscopy, specific surface area analysis, and dynamic light scattering measurements confirmed that the nanoparticles were highly dispersed in solvent without any aggregation. Subsequently, the relationship between particle size and photoluminescence (PL) intensity was investigated. The nanoparticles showed green emission corresponding to 4f → 4f transitions of Tb3+ under near-UV excitation. The PL intensity and quantum yield increased with increasing particle size, thus indicating that surface defects acted as the predominant PL quenchers within the studied size range.
Vorheriger Artikel Densities of Fe–Ni melts and thermodynamic correlations
Nächster Artikel Post-peak collapse and energy absorption in stochastic honeycombs

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Metadaten
Titel
Solvothermal synthesis of YBO3:Ce3+, Tb3+ nanophosphor: influence of B/(Y + Ce + Tb) ratio on particle size and photoluminescence intensity
verfasst von
Akihiro Nohara
Satoru Takeshita
Yoshiki Iso
Tetsuhiko Isobe
Publikationsdatum
17.12.2015
Verlag
Springer US
Erschienen in
Journal of Materials Science / Ausgabe 7/2016
Print ISSN: 0022-2461
Elektronische ISSN: 1573-4803
DOI
https://doi.org/10.1007/s10853-015-9645-1

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