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Erschienen in: Journal of Materials Science 6/2018

12.12.2017 | Energy materials

Synergistic carbon-based hole transporting layers for efficient and stable perovskite solar cells

verfasst von: Ruijia Zhang, Yun Chen, Jian Xiong, Xiaowen Liu

Erschienen in: Journal of Materials Science | Ausgabe 6/2018

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Abstract

Modification of hole transporting layers has proved an effective approach to improve the photoelectric conversion efficiency of perovskite solar cells. In this work, we report a highly dispersed graphene composite prepared by skillfully using the synergistic ππ interaction between graphene sheets and functional carbon nanotubes (f-CNTs). The graphene:f-CNTs HTLs demonstrate excellent conductivity and hole mobility. The hydrophobic graphene:f-CNTs HTL can also act as a scaffold for crystallization of perovskite layer and improve the device stability due to the beneficial interface. As a result, an improved PCE of 14.8% has been achieved with significant reproducibility. In addition, the optimized device with graphene:f-CNTs HTLs shows excellent stability and performance without encapsulation due to its neutral property. This approach can provide a good way for the future structure of perovskite solar cells.

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Literatur
1.
Zurück zum Zitat Bi C, Chen B, Wei H, DeLuca S, Huang J (2017) Efficient flexible solar cell based on composition-tailored hybrid perovskite. Adv Mater Bi C, Chen B, Wei H, DeLuca S, Huang J (2017) Efficient flexible solar cell based on composition-tailored hybrid perovskite. Adv Mater
2.
Zurück zum Zitat Smith IC, Hoke ET, Solis-Ibarra D, McGehee MD, Karunadasa HI (2014) A layered hybrid perovskite solar-cell absorber with enhanced moisture stability. Angew Chem Int Ed Engl 53:11232–11235CrossRef Smith IC, Hoke ET, Solis-Ibarra D, McGehee MD, Karunadasa HI (2014) A layered hybrid perovskite solar-cell absorber with enhanced moisture stability. Angew Chem Int Ed Engl 53:11232–11235CrossRef
3.
Zurück zum Zitat Pazoki M, Jacobsson TJ, Kullgren J, Johansson EM, Hagfeldt A, Boschloo G et al (2017) Photoinduced stark effects and mechanism of ion displacement in perovskite solar cell materials. ACS Nano 11:2823–2834CrossRef Pazoki M, Jacobsson TJ, Kullgren J, Johansson EM, Hagfeldt A, Boschloo G et al (2017) Photoinduced stark effects and mechanism of ion displacement in perovskite solar cell materials. ACS Nano 11:2823–2834CrossRef
4.
Zurück zum Zitat Mei A, Li X, Liu L, Ku Z, Liu T, Rong Y et al (2014) A hole-conductor-free, fully printable mesoscopic perovskite solar cell with high stability. Science 345:295–298CrossRef Mei A, Li X, Liu L, Ku Z, Liu T, Rong Y et al (2014) A hole-conductor-free, fully printable mesoscopic perovskite solar cell with high stability. Science 345:295–298CrossRef
5.
Zurück zum Zitat Yaghoobi Nia N, Matteocci F, Cina L, Di Carlo A (2017) High efficiency perovskite solar cell based on poly (3-hexylthiophene) (P3HT): the influence of P3HT molecular weight and mesoscopic scaffold layer. ChemSusChem Yaghoobi Nia N, Matteocci F, Cina L, Di Carlo A (2017) High efficiency perovskite solar cell based on poly (3-hexylthiophene) (P3HT): the influence of P3HT molecular weight and mesoscopic scaffold layer. ChemSusChem
6.
Zurück zum Zitat Gapol MA, Balanay MP, Kim DH (2017) Molecular engineering of tetraphenylbenzidine-based hole transport material for perovskite solar cell. J Phys Chem A 121:1371–1380CrossRef Gapol MA, Balanay MP, Kim DH (2017) Molecular engineering of tetraphenylbenzidine-based hole transport material for perovskite solar cell. J Phys Chem A 121:1371–1380CrossRef
7.
Zurück zum Zitat Yan K, Long M, Zhang T, Wei Z, Chen H, Yang S et al (2015) Hybrid halide perovskite solar cell precursors: colloidal chemistry and coordination engineering behind device processing for high efficiency. J Am Chem Soc 137:4460–4468CrossRef Yan K, Long M, Zhang T, Wei Z, Chen H, Yang S et al (2015) Hybrid halide perovskite solar cell precursors: colloidal chemistry and coordination engineering behind device processing for high efficiency. J Am Chem Soc 137:4460–4468CrossRef
8.
Zurück zum Zitat Rao HS, Chen BX, Wang XD, Kuang DB, Su CY (2017) A micron-scale laminar MAPbBr 3 single crystal for an efficient and stable perovskite solar cell. Chem Commun (Camb) 53:5163–5166CrossRef Rao HS, Chen BX, Wang XD, Kuang DB, Su CY (2017) A micron-scale laminar MAPbBr 3 single crystal for an efficient and stable perovskite solar cell. Chem Commun (Camb) 53:5163–5166CrossRef
9.
Zurück zum Zitat Li L, Chen Y, Liu Z, Chen Q, Wang X, Zhou H (2016) The additive coordination effect on hybrids perovskite crystallization and high-performance solar cell. Adv Mater 28:9862–9868CrossRef Li L, Chen Y, Liu Z, Chen Q, Wang X, Zhou H (2016) The additive coordination effect on hybrids perovskite crystallization and high-performance solar cell. Adv Mater 28:9862–9868CrossRef
10.
Zurück zum Zitat Shinde DV, Pyeon L, Pei M, Kim GW, Yang H, Park T (2017) Enhanced efficiency and stability of an aqueous lead-nitrate-based organometallic perovskite solar cell. ACS Appl Mater Interfaces 9:14023–14030CrossRef Shinde DV, Pyeon L, Pei M, Kim GW, Yang H, Park T (2017) Enhanced efficiency and stability of an aqueous lead-nitrate-based organometallic perovskite solar cell. ACS Appl Mater Interfaces 9:14023–14030CrossRef
11.
Zurück zum Zitat Cha M, Da P, Wang J, Wang W, Chen Z, Xiu F et al (2016) Enhancing perovskite solar cell performance by interface engineering using CH3NH3PbBr 0.9I2.1 quantum dots. J Am Chem Soc 138:8581–8587CrossRef Cha M, Da P, Wang J, Wang W, Chen Z, Xiu F et al (2016) Enhancing perovskite solar cell performance by interface engineering using CH3NH3PbBr 0.9I2.1 quantum dots. J Am Chem Soc 138:8581–8587CrossRef
12.
Zurück zum Zitat Liu J, Gao C, He X, Ye Q, Ouyang L, Zhuang D et al (2015) Improved crystallization of perovskite films by optimized solvent annealing for high efficiency solar cell. ACS Appl Mater Interfaces 7:24008–24015CrossRef Liu J, Gao C, He X, Ye Q, Ouyang L, Zhuang D et al (2015) Improved crystallization of perovskite films by optimized solvent annealing for high efficiency solar cell. ACS Appl Mater Interfaces 7:24008–24015CrossRef
13.
Zurück zum Zitat Kim J, Hwang T, Lee S, Lee B, Kim J, Jang GS et al (2016) Solvent and intermediate phase as boosters for the perovskite transformation and solar cell performance. Sci Rep 6:25648CrossRef Kim J, Hwang T, Lee S, Lee B, Kim J, Jang GS et al (2016) Solvent and intermediate phase as boosters for the perovskite transformation and solar cell performance. Sci Rep 6:25648CrossRef
14.
Zurück zum Zitat Huang A, Lei L, Yu Y, Liu Y, Yang S, Bao S et al (2017) Enhanced electrical property of Ni-doped CoOx hole transport layer for inverted perovskite solar cells. Nanotechnology 28:20LT02CrossRef Huang A, Lei L, Yu Y, Liu Y, Yang S, Bao S et al (2017) Enhanced electrical property of Ni-doped CoOx hole transport layer for inverted perovskite solar cells. Nanotechnology 28:20LT02CrossRef
15.
Zurück zum Zitat Wang F, Endo M, Mouri S, Miyauchi Y, Ohno Y, Wakamiya A et al (2016) Highly stable perovskite solar cells with an all-carbon hole transport layer. Nanoscale 8:11882–11888CrossRef Wang F, Endo M, Mouri S, Miyauchi Y, Ohno Y, Wakamiya A et al (2016) Highly stable perovskite solar cells with an all-carbon hole transport layer. Nanoscale 8:11882–11888CrossRef
16.
Zurück zum Zitat Peiris TAN, Baranwal AK, Kanda H, Fukumoto S, Kanaya S, Cojocaru L et al (2017) Enhancement of the hole conducting effect of NiO by a N2 blow drying method in printable perovskite solar cells with low-temperature carbon as the counter electrode. Nanoscale 9:5475–5482CrossRef Peiris TAN, Baranwal AK, Kanda H, Fukumoto S, Kanaya S, Cojocaru L et al (2017) Enhancement of the hole conducting effect of NiO by a N2 blow drying method in printable perovskite solar cells with low-temperature carbon as the counter electrode. Nanoscale 9:5475–5482CrossRef
17.
Zurück zum Zitat Xu X, Liu Z, Zuo Z, Zhang M, Zhao Z, Shen Y et al (2015) Hole selective NiO contact for efficient perovskite solar cells with carbon electrode. Nano Lett 15:2402–2408CrossRef Xu X, Liu Z, Zuo Z, Zhang M, Zhao Z, Shen Y et al (2015) Hole selective NiO contact for efficient perovskite solar cells with carbon electrode. Nano Lett 15:2402–2408CrossRef
18.
Zurück zum Zitat Nishimura H, Ishida N, Shimazaki A, Wakamiya A, Saeki A, Scott LT et al (2015) Hole-transporting materials with a two-dimensionally expanded pi-system around an azulene core for efficient perovskite solar cells. J Am Chem Soc 137:15656–15659CrossRef Nishimura H, Ishida N, Shimazaki A, Wakamiya A, Saeki A, Scott LT et al (2015) Hole-transporting materials with a two-dimensionally expanded pi-system around an azulene core for efficient perovskite solar cells. J Am Chem Soc 137:15656–15659CrossRef
19.
Zurück zum Zitat Schulz P, Tiepelt JO, Christians JA, Levine I, Edri E, Sanehira EM et al (2016) High-work-function molybdenum oxide hole extraction contacts in hybrid organic-inorganic perovskite solar cells. ACS Appl Mater Interfaces 8:31491–31499CrossRef Schulz P, Tiepelt JO, Christians JA, Levine I, Edri E, Sanehira EM et al (2016) High-work-function molybdenum oxide hole extraction contacts in hybrid organic-inorganic perovskite solar cells. ACS Appl Mater Interfaces 8:31491–31499CrossRef
20.
Zurück zum Zitat Matsui T, Petrikyte I, Malinauskas T, Domanski K, Daskeviciene M, Steponaitis M et al (2016) Additive-free transparent triarylamine-based polymeric hole-transport materials for stable perovskite solar cells. Chemsuschem 9:2567–2571CrossRef Matsui T, Petrikyte I, Malinauskas T, Domanski K, Daskeviciene M, Steponaitis M et al (2016) Additive-free transparent triarylamine-based polymeric hole-transport materials for stable perovskite solar cells. Chemsuschem 9:2567–2571CrossRef
21.
Zurück zum Zitat Qian J, Liu QS, Li G, Jiang KJ, Yang LM, Song Y (2011) P3HT as hole transport material and assistant light absorber in CdS quantum dots-sensitized solid-state solar cells. Chem Commun (Camb) 47:6461–6463CrossRef Qian J, Liu QS, Li G, Jiang KJ, Yang LM, Song Y (2011) P3HT as hole transport material and assistant light absorber in CdS quantum dots-sensitized solid-state solar cells. Chem Commun (Camb) 47:6461–6463CrossRef
22.
Zurück zum Zitat Choi H, Jo H, Paek S, Koh K, Ko HM, Lee JK et al (2016) Efficient hole-transporting materials with triazole core for high-efficiency perovskite solar cells. Chem Asian J 11:548–554CrossRef Choi H, Jo H, Paek S, Koh K, Ko HM, Lee JK et al (2016) Efficient hole-transporting materials with triazole core for high-efficiency perovskite solar cells. Chem Asian J 11:548–554CrossRef
23.
Zurück zum Zitat Hossain J, Liu Q, Miura T, Kasahara K, Harada D, Ishikawa R et al (2016) Nafion-modified PEDOT:PSS as a transparent hole-transporting layer for high-performance crystalline-si/organic heterojunction solar cells with improved light soaking stability. ACS Appl Mater Interfaces 8:31926–31934CrossRef Hossain J, Liu Q, Miura T, Kasahara K, Harada D, Ishikawa R et al (2016) Nafion-modified PEDOT:PSS as a transparent hole-transporting layer for high-performance crystalline-si/organic heterojunction solar cells with improved light soaking stability. ACS Appl Mater Interfaces 8:31926–31934CrossRef
24.
Zurück zum Zitat Girotto C, Voroshazi E, Cheyns D, Heremans P, Rand BP (2011) Solution-processed MoO(3) thin films as a hole-injection layer for organic solar cells. ACS Appl Mater Interfaces 3:3244–3247CrossRef Girotto C, Voroshazi E, Cheyns D, Heremans P, Rand BP (2011) Solution-processed MoO(3) thin films as a hole-injection layer for organic solar cells. ACS Appl Mater Interfaces 3:3244–3247CrossRef
25.
Zurück zum Zitat Bi H, Zhang Y (2015) Influence of the additives in poly(3-hexylthiophene) hole transport layer on the performance of perovskite solar cells. Mater Lett 161:767–769CrossRef Bi H, Zhang Y (2015) Influence of the additives in poly(3-hexylthiophene) hole transport layer on the performance of perovskite solar cells. Mater Lett 161:767–769CrossRef
26.
Zurück zum Zitat Niu J, Yang D, Ren X, Yang Z, Liu Y, Zhu X et al (2017) Graphene-oxide doped PEDOT:PSS as a superior hole transport material for high-efficiency perovskite solar cell. Org Electron 48:165–171CrossRef Niu J, Yang D, Ren X, Yang Z, Liu Y, Zhu X et al (2017) Graphene-oxide doped PEDOT:PSS as a superior hole transport material for high-efficiency perovskite solar cell. Org Electron 48:165–171CrossRef
27.
Zurück zum Zitat Zhu Z, Ma J, Wang Z, Mu C, Fan Z, Du L et al (2014) Efficiency enhancement of perovskite solar cells through fast electron extraction: the role of graphene quantum dots. J Am Chem Soc 136:3760–3763CrossRef Zhu Z, Ma J, Wang Z, Mu C, Fan Z, Du L et al (2014) Efficiency enhancement of perovskite solar cells through fast electron extraction: the role of graphene quantum dots. J Am Chem Soc 136:3760–3763CrossRef
28.
Zurück zum Zitat Huang X, Guo H, Yang J, Wang K, Niu X, Liu X (2016) Moderately reduced graphene oxide/PEDOT:PSS as hole transport layer to fabricate efficient perovskite hybrid solar cells. Org Electron 39:288–295CrossRef Huang X, Guo H, Yang J, Wang K, Niu X, Liu X (2016) Moderately reduced graphene oxide/PEDOT:PSS as hole transport layer to fabricate efficient perovskite hybrid solar cells. Org Electron 39:288–295CrossRef
29.
Zurück zum Zitat Aitola K, Domanski K, Correa-Baena JP, Sveinbjornsson K, Saliba M, Abate A, et al. High temperature-stable perovskite solar cell based on low-cost carbon nanotube hole contact. Adv Mater. 2017;29 Aitola K, Domanski K, Correa-Baena JP, Sveinbjornsson K, Saliba M, Abate A, et al. High temperature-stable perovskite solar cell based on low-cost carbon nanotube hole contact. Adv Mater. 2017;29
30.
Zurück zum Zitat Ye J, Li X, Zhao J, Mei X, Li Q (2016) Efficient and stable perovskite solar cells based on functional graphene-modified P3HT hole-transporting layer. RSC Adv 6:36356–36361CrossRef Ye J, Li X, Zhao J, Mei X, Li Q (2016) Efficient and stable perovskite solar cells based on functional graphene-modified P3HT hole-transporting layer. RSC Adv 6:36356–36361CrossRef
Metadaten
Titel
Synergistic carbon-based hole transporting layers for efficient and stable perovskite solar cells
verfasst von
Ruijia Zhang
Yun Chen
Jian Xiong
Xiaowen Liu
Publikationsdatum
12.12.2017
Verlag
Springer US
Erschienen in
Journal of Materials Science / Ausgabe 6/2018
Print ISSN: 0022-2461
Elektronische ISSN: 1573-4803
DOI
https://doi.org/10.1007/s10853-017-1876-x

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