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Journal of Polymer Research
Erschienen in: Journal of Polymer Research 5/2011

01.09.2011 | Original Paper

Synthesis and characterization of side-chain maleimide-styrene copolymers with new pendant azobenzene moieties

verfasst von: Florica Adriana Nicolescu, Valentin Victor Jerca, Ioan Dancus, Adrian Petris, Tanta Verona Nicolescu, Ileana Brandusa Rau, Valentin Ionel Vlad, Dan Sorin Vasilescu, Dumitru Mircea Vuluga

Erschienen in: Journal of Polymer Research | Ausgabe 5/2011

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Abstract

Four side-chain maleimide-styrene polymers have been synthesized from maleimide-alt-styrene copolymer (MASt) and some original azo-moieties using polymer analogous reactions. The structures have been obtained with good yields; remarkably, they showed a high chromophore load, up to ~100%. The polymers were characterized by means of SEC, FT-IR, 1H-NMR, DSC-TGA, and elemental analysis. The side-chain polymers exhibited improved solubility and enhanced thermal stability up to 320ºC, while their glass transition temperatures have been found to be as high as 210ºC. The third-order NLO refraction (n2) and susceptibility χ(3) coefficients were measured by Z-scan technique. The results of Z-scan measurements showed that the polymers have only nonlinear refraction, the nonlinear absorption being negligible.
Vorheriger Artikel Effect of photosensitive groups on the photoefficiency of polymeric photoinitiators
Nächster Artikel A novel route for the synthesis of poly(2-hydroxyethyl methacrylate-co-methyl methacrylate) grafted titania nanoparticles via ATRP

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Metadaten
Titel
Synthesis and characterization of side-chain maleimide-styrene copolymers with new pendant azobenzene moieties
verfasst von
Florica Adriana Nicolescu
Valentin Victor Jerca
Ioan Dancus
Adrian Petris
Tanta Verona Nicolescu
Ileana Brandusa Rau
Valentin Ionel Vlad
Dan Sorin Vasilescu
Dumitru Mircea Vuluga
Publikationsdatum
01.09.2011
Verlag
Springer Netherlands
Erschienen in
Journal of Polymer Research / Ausgabe 5/2011
Print ISSN: 1022-9760
Elektronische ISSN: 1572-8935
DOI
https://doi.org/10.1007/s10965-010-9501-6

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