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Journal of Materials Science

Erschienen in:

11.05.2016 | Original Paper

Synthesis and properties of graphene and graphene/carbon nanotube-reinforced soft magnetic FeCo alloy composites by spark plasma sintering

verfasst von: Amar J. Albaaji, Elinor G. Castle, Mike J. Reece, Jeremy P. Hall, Sam L. Evans

Erschienen in: Journal of Materials Science | Ausgabe 16/2016

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Abstract

The effect of the addition of graphene nanoplatelets (GNP) and graphene nanoplatelet/carbon nanotube (GNT) mixtures on the mechanical and magnetic properties of spark plasma sintered soft magnetic FeCo alloys was studied. Three different volume fractions (0.5, 1 and 2 vol%) of GNPs and GNTs were investigated. Ball milling was used to disperse the GNPs in monolithic FeCo powder, while magnetic stirring and ultrasonic agitation were used to prepare hybrid GNT prior to ball milling. The highest saturation induction (B _sat) of 2.39 T was observed in the 1 vol% GNP composite. An increase in the volume fraction of the ordered nanocrystalline structure was found to reduce the coercivity (H _c) of the composites. The addition of CNTs to the GNP composite prevented grain growth, leading to grain refinement. An 18 % increase in hardness was observed in the 1 vol% GNP composite as compared to the as-received FeCo alloy. A reduction in tensile strength was observed in all of the composite materials, except for the 0.5 vol% GNT composite, for which a value of 643 MPa was observed. Raman spectroscopy indicated a reduction in the defect density of the GNPs after adding CNTs.

Vorheriger Artikel Growth, structural, dielectric, ferroelectric, and mechanical properties of l-prolinium tartrate single crystal

Nächster Artikel Magnetic, magnetocaloric properties, and critical behavior in a layered perovskite La1.4(Sr0.95Ca0.05)1.6Mn2O7

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Kim H, Abdala AA, Macosko CW (2010) Graphene/polymer nanocomposites. Macromolecules 43:6515–6530. doi:10.1021/ma100572e CrossRef

Tjong SC (2013) Recent progress in the development and properties of novel metal matrix nanocomposites reinforced with carbon nanotubes and graphene nanosheets. Mater Sci Eng Rep 74:281–350. doi:10.1016/j.mser.2013.08.001 CrossRef

Chen LY, Konishi H, Fehrenbacher A, Ma C, Xu JQ, Choi H, Xu HF, Pfefferkorn FE, Li XC (2012) Novel nanoprocessing route for bulk graphene nanoplatelets reinforced metal matrix nanocomposites. Scr Mater 67:29. doi:10.1016/j.scriptamat.2012.03.013 CrossRef

Huang X, Qi X, Boey F, Zhang H (2012) Graphene-based composites. Chem Soc Rev 41:666–686. doi:10.1039/c1cs15078b CrossRef

Wu ZS, Zhou GM, Yin LC, Ren W, Li F, Cheng HM (2012) Graphene/metal oxide composite electrode materials for energy storage. Nano Energy 1:107. doi:10.1016/j.nanoen.2011.11.001 CrossRef

Matsuda M, Yamashita K, Sago R, Akamine K, Takashima K, Nishida M (2012) Development of ductile B2-Type FeCo based alloys. Mater Trans 53:1826. doi:10.2320/matertrans.M2012205 CrossRef

Kawahara K, Uehara M (1984) A possibility for developing high strength soft magnetic materials in FeCo-X alloys. J Mater Sci 19:2575–2581. doi:10.1007/Bf00550812 CrossRef

Kawahara K (1983) Effect of carbon on mechanical properties in Fe0·5Co0·5 alloys. J Mater Sci 18:2047–2055. doi:10.1007/BF00554997 CrossRef

Yu RH, Ren L, Basu S, Unruh KM, Parvizi-Majidi A, Xiao JQ (2000) Novel soft magnetic composites fabricated by electrodeposition. J Appl Phys 87:5840–5842. doi:10.1063/1.372540 CrossRef

10.

Turgut Z, Huang M, Horwath JC, Fingers RT (2008) High strength bulk Fe–Co alloys produced by powder metallurgy. J Appl Phys 131–134:07E724. doi:10.1063/1.2838466

11.

Rutz HG, Hanejko FG (1994) High density processing of high performance ferrous materials. In: International conference & exhibition on powder metallurgy & particulate material, Toronto

12.

Xu CY, Jia SS, Cao ZY (2005) Synthesis of Al–Mn–Ce alloy by the spark plasma sintering. Mater Charact 54:394–398. doi:10.1016/j.matchar.2004.12.006 CrossRef

13.

Groza JR, Garcia M, Schneider JA (2001) Surface effects in field-assisted sintering. J Mater Res 16:286–292. doi:10.1557/Jmr.2001.0043 CrossRef

14.

Munir ZA, Anselmi-Tamburini U, Ohyanagi M (2006) The effect of electric field and pressure on the synthesis and consolidation of materials: a review of the spark plasma sintering method. J Mater Sci 41:763–777. doi:10.1007/s10853-006-6555-2 CrossRef

15.

Mani MK, Viola G, Reece MJ, Hall JP, Evans SL (2013) Structural and magnetic characterization of spark plasma sintered Fe-50Co alloys. In: MRS proceedings, vol 1516. Cambridge University Press, Cambridge, pp 201–207. doi: 10.1557/opl.2012

16.

Mani MK, Viola G, Reece MJ, Hall JP, Evans SL (2014) Improvement of interfacial bonding in carbon nanotube reinforced Fe–50Co composites by Ni–P coating: effect on magnetic and mechanical properties. Mater Sci Eng B 188:94–101. doi:10.1016/j.mseb.2014.06.009 CrossRef

17.

Mani MK, Viola G, Hall JP, Grasso S, Reece MJ (2015) Observation of Curie transition during spark plasma sintering of ferromagnetic materials. J Magn Magn Mater 382:202–205. doi:10.1016/j.jmmm.2015.01.066 CrossRef

18.

Porwal H, Grasso S, Reece MJ (2014) Review of graphene–ceramic matrix composites. Adv Appl Ceram 112:443. doi:10.1179/174367613x13764308970581 CrossRef

19.

Kim J, Cote LJ, Kim F, Yuan W, Shull KR, Huang J (2010) Graphene oxide sheets at interfaces. J Am Chem Soc 132:8180–8186. doi:10.1021/ja102777p CrossRef

20.

Wimalasiri Y, Zou LD (2013) Carbon nanotube/graphene composite for enhanced capacitive deionization performance. Carbon 59:464–471. doi:10.1016/j.carbon.2013.03.040 CrossRef

21.

Yazdani B, Porwal H, Xia YD, Yan HX, Reece MJ, Zhu YQ (2015) Role of synthesis method on microstructure and mechanical properties of graphene/carbon nanotube toughened Al₂O₃ nanocomposites. Ceram Int 41:9813–9822. doi:10.1016/j.ceramint.2015.04.054 CrossRef

22.

Yazdani B, Xia YD, Ahmad I, Zhu YQ (2015) Graphene and carbon nanotube (GNT)-reinforced alumina nanocomposites. J Eur Ceram Soc 35:179–186. doi:10.1016/j.jeurceramsoc.2014.08.043 CrossRef

23.

Wang PN, Hsieh TH, Chiang CL, Shen MY (2015) Synergetic effects of mechanical properties on graphene nanoplatelet and multiwalled carbon nanotube hybrids reinforced epoxy/carbon fiber composites. J Nanomater 2015:1–9

24.

Rashad M, Pan FS, Tang AT, Asif M, Aamir M (2014) Synergetic effect of graphene nanoplatelets (GNPs) and multi-walled carbon nanotube (MW-CNTs) on mechanical properties of pure magnesium. J Alloy Compd 603:111–118. doi:10.1016/j.jallcom.2014.03.038 CrossRef

25.

Dieter GE (1986) Mechanical metallurgy, 3rd edn. McGraw-Hill, New York

26.

Anderson P (2008) A universal DC characterisation system for hard and soft magnetic materials. J Magn Magn Mater 320:589–593. doi:10.1016/j.jmmm.2008.04.034 CrossRef

27.

Mani MK, Viola G, Reece MJ, Hall JP, Evans SL (2014) Fabrication of carbon nanotube reinforced iron based magnetic alloy composites by spark plasma sintering. J Alloy Compd 601:146–153. doi:10.1016/j.jallcom.2014.02.169 CrossRef

28.

Clegg DW, Buckley RA (1973) The disorder → order transformation in iron–cobalt-based alloys. Met Sci 7:48–54CrossRef

29.

Sahoo PK, Panigrahy B, Li D, Bahadur D (2013) Magnetic behavior of reduced graphene oxide/metal nanocomposites. J Appl Phys 113:17B525. doi:10.1063/1.4799150

30.

Yuan BQ, Yu LM, Sheng LM, An K, Zhao XL (2012) Comparison of electromagnetic interference shielding properties between single-wall carbon nanotube and graphene sheet/polyaniline composites. J Phys D Appl Phys 45(23):1–6. doi:10.1088/0022-3727/45/23/235108 CrossRef

31.

Enoki T, Kobayashi Y (2005) Magnetic nanographite: an approach to molecular magnetism. J Mater Chem 15:3999–4002. doi:10.1039/b500274p CrossRef

32.

Hug E, Hubert O, Guillot I (2000) Effect of strengthening on the magnetic behaviour of ordered intermetallic 2 % V-CoFe alloys. J Magn Magn Mater 215:197–200CrossRef

33.

Herzer G (1990) Grain size dependence of coercivity and permeability in nanocrystalline ferromagnets. IEEE Trans Magn 26:1397–1402CrossRef

34.

Wu HQ, Xu DM, Wang Q, Yao YZ, Wang QY, Su GQ (2008) Effect of heat treatment on structure and magnetic properties of FeCoNi/CNTs nanocomposites. Bull Mater Sci 31:801–806CrossRef

35.

Rao CN, Sood AK, Subrahmanyam KS, Govindaraj A (2009) Graphene: the new two-dimensional nanomaterial. Angew Chem Int Ed Engl 48(42):7752–7777. doi:10.1002/anie.200901678 CrossRef

36.

Bastwros M, Kim GY, Zhu C, Zhang K, Wang S, Tang X, Wang X (2014) Effect of ball milling on graphene reinforced Al6061 composite fabricated by semi-solid sintering. Compos Part B Eng 60:111–118. doi:10.1016/j.compositesb.2013.12.043 CrossRef

37.

Ferrari AC, Meyer JC, Scardaci V, Casiraghi C, Lazzeri M, Mauri F, Piscanec S, Jiang D, Novoselov KS, Roth S, Geim AK (2006) Raman spectrum of graphene and graphene layers. Phys Rev Lett 97(1–4):187401. doi:10.1103/PhysRevLett.97.187401 CrossRef

38.

Inam F, Yan H, Reece MJ, Peijs T (2010) Structural and chemical stability of multiwall carbon nanotubes in sintered ceramic nanocomposite. Adv Appl Ceram 109(4):240–247CrossRef

Titel: Synthesis and properties of graphene and graphene/carbon nanotube-reinforced soft magnetic FeCo alloy composites by spark plasma sintering
verfasst von: Amar J. Albaaji
Elinor G. Castle
Mike J. Reece
Jeremy P. Hall
Sam L. Evans
Publikationsdatum: 11.05.2016
Verlag: Springer US
Erschienen in: Journal of Materials Science / Ausgabe 16/2016
Print ISSN: 0022-2461
Elektronische ISSN: 1573-4803
DOI: https://doi.org/10.1007/s10853-016-0041-2

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