nach oben

Journal of Sol-Gel Science and Technology

Erschienen in:

01.11.2012 | Original Paper

Synthesis and properties of Mo and W ions co-doped porous nano-structured VO₂ films by sol–gel process

verfasst von: Yuanjie Xu, Wanxia Huang, Qiwu Shi, Yang Zhang, Linwei Song, Yaxin Zhang

Erschienen in: Journal of Sol-Gel Science and Technology | Ausgabe 2/2012

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config

KI-gestützte Suche

Aus

Abstract

Porous nano-structured vanadium dioxide (VO₂) films doped with Mo and W ions had been synthesized by sol gel process by employing a sol containing ammonium molybdate and ammonium tungstate with the addition of cetyltrimethyl ammonium bromide (CTAB). The effects of molybdenum and tungsten co-doping and CTAB addition on the structure, morphologies, crystalline and optical properties of VO₂ films were investigated systematically in this study. The composition and microstructure were detected by X-ray diffraction, X-ray photoelectron spectroscopy and scanning electron microscopy. The Mo and W ions co-doped porous nano-structured VO₂ films showed excellent infrared transmittance (nearly 70 %), large transmittance difference (55 %) before and after the phase transition, low transition temperature (35 °C), wide hysteresis width (22 °C) and fast phase transition. The results suggest that such Mo and W ions co-doped porous nano-structured VO₂ film is an ideal fundamental material for optical data storage.

Vorheriger Artikel Synthesis of MnAl2O4 nanocrystallites by Pechini and sequential homogenous precipitation methods: characterization, product comparison, photocatalytic effect, and Taguchi optimization

Nächster Artikel Organic–inorganic tandem route to polymer nanocomposites: kinetic products versus thermodynamic products

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

über 67.000 Bücher
über 390 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Maschinenbau + Werkstoffe

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

über 102.000 Bücher
über 537 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Finance + Banking
Management + Führung
Marketing + Vertrieb
Maschinenbau + Werkstoffe
Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Feringa BL, Jager WF, Lange B (1993) Organic materials for reversible optical data storage. Tetrahedron 49:8267–8310CrossRef

Sbiaa R, Piramanayagam SN (2007) Patterned media towards nano-bit magnetic recording: fabrication and challenges. Recent Pat Nanotechnol 1:29–40CrossRef

Houbertz R, Domann G, Cronauer C, Schmitt A, Martin H (2003) Inorganic-organic hybrid materials for application in optical devices. Thin Solid Films 442:194–200CrossRef

Shi QW, Huang WX, Yan JZ et al (2011) Preparation and phase transition characterization of VO₂ thin film on single crystal Si (100) substrate by sol–gel process. J Sol–Gel Sci Technol 59:591–597CrossRef

Peng ZF, Wang Y, Du YY et al (2009) Phase transition and IR properties of tungsten-doped vanadium dioxide nanopowders. J Alloy Compd 480:537–540CrossRef

Lysenko S, Vikhnin V, Rua A et al (2011) Size-dependent phase transition of VO₂ nanostructures induced by light excitation. Phys Procedia 13:18–23CrossRef

Beteille F, Livage J (1998) Optical switching in VO₂ thin films. J Sol-Gel Sci Technol 13: 915–921

Hermann K, Chakrabarti A, Haras A, Witko M, Tepper B (2001) Electronic structure of vanadium dioxide: Ab initio density functional theory studies of periodic and local systems. Phys Status Solid A Appl Res 187:137–142CrossRef

Chen XQ, Lv Q, Yi XJ (2011) Smart window coating based on nanostructured VO₂ thin film. Optik 7:48–53

10.

Yan JZ, Zhang Y, Huang WX, Tu MJ (2008) Effect of Mo-W co-doping on semiconductor-metal phase transition temperature of vanadium dioxide film. Thin Solid Films 516:8554–8558CrossRef

11.

Cui J, Da D, Jiang W (1998) Structure characterization of vanadium oxide thin films prepared by magnetron sputtering methods. App Surf Sci 133:225–229CrossRef

12.

Krishna MG, Debauge Y, Bhattacharya AK (1998) X-ray photoelectron spectroscopy and spectral study of stoichiometry in sputtered vanadium oxide films. Thin Solid Films 312:116–122CrossRef

13.

Ye JW, Zhou L, Liu FJ et al (2011) Preparation, characterization and properties of thermochromic tungsten-doped vanadium dioxide by thermal reduction and annealing. J Alloy Compd 504:503–507CrossRef

14.

Kang LT, Gao YF, Luo HJ, Chen Z, Du J, Zhang ZT (2011) Effects of annealing parameters on optical properties of thermochromic VO₂ films prepared in aqueous solution. ACS Appl Mater Interfaces 3:135–138CrossRef

15.

Feng CQ, Wang SY, Zeng R, Guo ZP et al (2008) Synthesis of spherical porous vanadium pentoxide and its electrochemical properties. J Power Sour 184:485–488CrossRef

16.

Scherer GW (1997) Sintering of sol–gel films. J Sol–Gel Sci Technol 8:353–363

17.

Kong FY, Li M, Pan SS, Zhang YX, Li GH (2010) Synthesis and thermal stability of W-doped VO₂ nanocrystals. Mater Res Bull 46:2100–2104CrossRef

18.

Klimov VA, Timofeeva IO, Khanin SD, Shadrin EB et al (2003) Hysteresis loop construction for the metal-semiconductor phase transition in vanadium dioxide films. Semiconductors 37:370–374CrossRef

19.

Kang LT, Gao YF, Zhang ZT, Du J et al (2010) Effects of annealing parameters on optical properties of thermochromic VO₂ films prepared in aqueous solution. J Phys Chem C 114:1901–1911CrossRef

20.

Guinneton F, Sauques L, Valmalette JC et al (2004) Optimized infrared switching properties in thermochromic vanadium dioxide thin films. Thin Solid Films 446:287–295CrossRef

21.

Ramirez JG, Sharoni A, Dubi Y, Gomez ME, Schuller IK (2009) First-order reversal curve measurements of the metal-insulator transition in VO₂: signatures of persistent metallic domains. Phys Rev B 79:235110CrossRef

Titel: Synthesis and properties of Mo and W ions co-doped porous nano-structured VO2 films by sol–gel process
verfasst von: Yuanjie Xu
Wanxia Huang
Qiwu Shi
Yang Zhang
Linwei Song
Yaxin Zhang
Publikationsdatum: 01.11.2012
Verlag: Springer US
Erschienen in: Journal of Sol-Gel Science and Technology / Ausgabe 2/2012
Print ISSN: 0928-0707
Elektronische ISSN: 1573-4846
DOI: https://doi.org/10.1007/s10971-012-2881-9

Premium Partner

Marktübersichten

Die im Laufe eines Jahres in der „adhäsion“ veröffentlichten Marktübersichten helfen Anwendern verschiedenster Branchen, sich einen gezielten Überblick über Lieferantenangebote zu verschaffen.

Zur Marktübersicht

Springer Professional

Abstract

Bitte loggen Sie sich ein, um Zugang zu Ihrer Lizenz zu erhalten.

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Technik"

Springer Professional "Wirtschaft+Technik"

Weitere Artikel der Ausgabe 2/2012

A sol–gel methodology for the preparation of lanthanide-oxide aerogels: preparation and characterization

Preparation of new photosensitive Nb2O5 gel films modified with benzoylacetone and properties of heat-treated films

Crucial factors affecting the physicochemical properties of sol–gel produced Fe3O4@SiO2–NH2 core–shell nanomaterials

Modified nanoporous silicas for oral delivery of the water insoluble organotin compound: loading and release of methylphenyltin dichloride as an anti-tumor drug model

Synthesis of silica nanoparticles using oil-in-water emulsion and the porosity analysis

Preparation and characterization of Ce-doped and Zr-doped sol–gel inks of titanium alkoxide

Premium Partner

Marktübersichten