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Erschienen in: Journal of Sol-Gel Science and Technology 2/2010

01.02.2010 | Original Paper

Synthesis of a low-density tantalum oxide tile-like aerogel monolithic

verfasst von: Hongbo Ren, Lin Zhang, Chengwei Shang, Xian Wang, Yutie Bi

Erschienen in: Journal of Sol-Gel Science and Technology | Ausgabe 2/2010

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Abstract

A tile-like Ta2O5 aerogel monolithic was prepared by sol–gel method. Tantalum ethoxide and tantalum pentachloride were used as precursors, ethanol as the solvent, and propylene oxide as the gelation agent. Field emission scanning electron microscopy (FESEM), high-resolution transmission electron microscopy (HRTEM), and Brunauer–Emmett–Teller (BET) and Barrett–Joyner–Halenda (BJH) methods were used to characterize the as-prepared aerogel. The combined results of these techniques indicated the presence of tantalum pentachloride and propylene oxide leading to the high porosity, high surface area, and low density of the Ta2O5 aerogel monolithic.

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Literatur
1.
Zurück zum Zitat Mccusker LB, Liebau F, Engelhardt G (2001) Nomenclature of structural and compositional characteristics of ordered microporous and mesoporous materials with inorganic hosts. Pure Appl Chem 73(2):381–394CrossRef Mccusker LB, Liebau F, Engelhardt G (2001) Nomenclature of structural and compositional characteristics of ordered microporous and mesoporous materials with inorganic hosts. Pure Appl Chem 73(2):381–394CrossRef
2.
Zurück zum Zitat Jenekhe SA, Chen XL (1999) Self-assembly of ordered microporous materials from rod-coil block copolymers. Science 283(5400):372–375CrossRefPubMedADS Jenekhe SA, Chen XL (1999) Self-assembly of ordered microporous materials from rod-coil block copolymers. Science 283(5400):372–375CrossRefPubMedADS
3.
Zurück zum Zitat Beyer HK, Mihályi RM, Minchev Ch, Neinska Y, Kanazirev V (1996) Study of the reductive solid-state ion exchange of indium into NH4NaY zeolite. Microporous Mater 7(6):333–341CrossRef Beyer HK, Mihályi RM, Minchev Ch, Neinska Y, Kanazirev V (1996) Study of the reductive solid-state ion exchange of indium into NH4NaY zeolite. Microporous Mater 7(6):333–341CrossRef
4.
Zurück zum Zitat Reid CR, Thomas KM (1999) Adsorption of gases on a carbon molecular sieve used for air separation: linear adsorptives as probes for kinetic selectivity. Langmuir 15(9):3206–3218CrossRef Reid CR, Thomas KM (1999) Adsorption of gases on a carbon molecular sieve used for air separation: linear adsorptives as probes for kinetic selectivity. Langmuir 15(9):3206–3218CrossRef
5.
Zurück zum Zitat Shu H-T, Li D, Scala AA, Ma YH (1997) Adsorption of small organic pollutants from aqueous streams by aluminosilicate-based microporous materials. Sep Purif Technol 11(1):27–36CrossRef Shu H-T, Li D, Scala AA, Ma YH (1997) Adsorption of small organic pollutants from aqueous streams by aluminosilicate-based microporous materials. Sep Purif Technol 11(1):27–36CrossRef
6.
Zurück zum Zitat Zhang Z, Han Y, Xiao F-S, Qiu S, Zhu L, Wang R, Yu Y, Zhang Z, Zou B, Wang Y, Sun H, Zhao D, Wei Y (2001) Mesoporous aluminosilicates with ordered hexagonal structure, strong acidity, and extraordinary hydrothermal stability at high temperatures. J Am Chem Soc 123(21):5014–5021CrossRefPubMed Zhang Z, Han Y, Xiao F-S, Qiu S, Zhu L, Wang R, Yu Y, Zhang Z, Zou B, Wang Y, Sun H, Zhao D, Wei Y (2001) Mesoporous aluminosilicates with ordered hexagonal structure, strong acidity, and extraordinary hydrothermal stability at high temperatures. J Am Chem Soc 123(21):5014–5021CrossRefPubMed
7.
Zurück zum Zitat Berlini C, Guidotti M, Moretti G, Psaro R, Ravasio N (2000) Catalytic epoxidation of unsaturated alcohols on Ti-MCM-41. Catal Today 60(3–4):219–225CrossRef Berlini C, Guidotti M, Moretti G, Psaro R, Ravasio N (2000) Catalytic epoxidation of unsaturated alcohols on Ti-MCM-41. Catal Today 60(3–4):219–225CrossRef
8.
Zurück zum Zitat Doadrio AL, Sousa EMB, Doadrio JC, Pérez Pariente J, Izquierdo-Barba I, Vallet-Regi M (2004) Mesoporous SBA-15 HPLC evaluation for controlled gentamicin drug delivery. J Control Release 97(1):125–132CrossRefPubMed Doadrio AL, Sousa EMB, Doadrio JC, Pérez Pariente J, Izquierdo-Barba I, Vallet-Regi M (2004) Mesoporous SBA-15 HPLC evaluation for controlled gentamicin drug delivery. J Control Release 97(1):125–132CrossRefPubMed
9.
Zurück zum Zitat Selvam P, Bhatia SK, Sonwane CG (2001) Recent advances in processing and characterization of periodic mesoporous MCM-41 silicate molecular sieves. Ind Eng Chem Res 40(15):3237–3261CrossRef Selvam P, Bhatia SK, Sonwane CG (2001) Recent advances in processing and characterization of periodic mesoporous MCM-41 silicate molecular sieves. Ind Eng Chem Res 40(15):3237–3261CrossRef
10.
Zurück zum Zitat Aricò AS, Bruce P, Scrosati B, Tarascon J-M, van Schalkwijk W (2005) Nanostructured materials for advanced energy conversion and storage devices. Nat Mater 4(5):366–377CrossRefPubMedADS Aricò AS, Bruce P, Scrosati B, Tarascon J-M, van Schalkwijk W (2005) Nanostructured materials for advanced energy conversion and storage devices. Nat Mater 4(5):366–377CrossRefPubMedADS
11.
Zurück zum Zitat Yamada T, Zhou HS, Uchida H, Tomita M, Ueno Y, Honma I, Asai K, Katsube T (2002) Application of a cubic-like mesoporous silica film to a surface photovoltage gas sensing system. Microporous Mesoporous Mater 54(3):269–276CrossRef Yamada T, Zhou HS, Uchida H, Tomita M, Ueno Y, Honma I, Asai K, Katsube T (2002) Application of a cubic-like mesoporous silica film to a surface photovoltage gas sensing system. Microporous Mesoporous Mater 54(3):269–276CrossRef
12.
Zurück zum Zitat Gao F, Lu Q, Liu I, Yan Y, Zhao D (2001) Controlled synthesis of semiconductor PbS nanocrystals and nanowires inside mesoporous silica SBA-15 phase. Nano Lett 1(12):743–748CrossRefADS Gao F, Lu Q, Liu I, Yan Y, Zhao D (2001) Controlled synthesis of semiconductor PbS nanocrystals and nanowires inside mesoporous silica SBA-15 phase. Nano Lett 1(12):743–748CrossRefADS
13.
Zurück zum Zitat Kato H, Kudo A (1998) New tantalate photocatalysts for water decomposition into H2 and O2. Chem Phys Lett 295(5–6):487–492CrossRefADS Kato H, Kudo A (1998) New tantalate photocatalysts for water decomposition into H2 and O2. Chem Phys Lett 295(5–6):487–492CrossRefADS
14.
Zurück zum Zitat Kim KY, Ahn WS, Park DW, Oh JH, Lee CM, Tai WP (2004) Microwave synthesis of titanium silicalite-1 using solid phase precursors. Bull Korean Chem Soc 25(5):634–638CrossRef Kim KY, Ahn WS, Park DW, Oh JH, Lee CM, Tai WP (2004) Microwave synthesis of titanium silicalite-1 using solid phase precursors. Bull Korean Chem Soc 25(5):634–638CrossRef
15.
Zurück zum Zitat Takahara Y, Kondo JN, Takata T, Lu D, Domen K (2001) Mesoporous tantalum oxide. 1. Characterization and photocatalytic activity for the overall water decomposition. Chem Mater 13(4):1194–1199CrossRef Takahara Y, Kondo JN, Takata T, Lu D, Domen K (2001) Mesoporous tantalum oxide. 1. Characterization and photocatalytic activity for the overall water decomposition. Chem Mater 13(4):1194–1199CrossRef
16.
Zurück zum Zitat Miller JE (2007) High-pressure equation-of-state of porous-Ta2O5. University of Rochester, Dissertation Miller JE (2007) High-pressure equation-of-state of porous-Ta2O5. University of Rochester, Dissertation
17.
Zurück zum Zitat Huo Q, Margolese DI, Ciesla U, Feng P, Gier TE, Sieger P, Leon R, Petroff PM, Schüth F, Stucky GD (1994) Generalized synthesis of periodic surfactant/inorganic composite materials. Nature 368(6469):317–321CrossRefADS Huo Q, Margolese DI, Ciesla U, Feng P, Gier TE, Sieger P, Leon R, Petroff PM, Schüth F, Stucky GD (1994) Generalized synthesis of periodic surfactant/inorganic composite materials. Nature 368(6469):317–321CrossRefADS
18.
Zurück zum Zitat Ying JY, Mehnert CP, Wong MS (1999) Synthesis and applications of supramolecular-templated mesoporous materials. Angew Chem Int Ed 38(1–2):56–77CrossRef Ying JY, Mehnert CP, Wong MS (1999) Synthesis and applications of supramolecular-templated mesoporous materials. Angew Chem Int Ed 38(1–2):56–77CrossRef
19.
Zurück zum Zitat Antonelli DM, Ying JY (1996) Synthesis and characterization of hexagonally packed mesoporous tantalum oxide molecular sieves. Chem Mater 8(4):874–881CrossRef Antonelli DM, Ying JY (1996) Synthesis and characterization of hexagonally packed mesoporous tantalum oxide molecular sieves. Chem Mater 8(4):874–881CrossRef
20.
Zurück zum Zitat Kondo JN, Takahara Y, Lu D, Domen K (2001) Mesoporous Ta oxide. 2. Improvement of the synthetic method and observation of mesostructure formation. Chem Mater 13(4):1200–1206CrossRef Kondo JN, Takahara Y, Lu D, Domen K (2001) Mesoporous Ta oxide. 2. Improvement of the synthetic method and observation of mesostructure formation. Chem Mater 13(4):1200–1206CrossRef
21.
Zurück zum Zitat Droege MW, Coronado PR, Hair LM (1995) Method for making monolithic metal oxide aerogels. US Patent 5,395,805 Droege MW, Coronado PR, Hair LM (1995) Method for making monolithic metal oxide aerogels. US Patent 5,395,805
22.
Zurück zum Zitat Rouquerol J, Avnir D, Fairbridge CW, Everett DH, Haynes JH, Pernicone N, Ramsay JDF, Sing KSW, Unger KK (1994) Recommendations for the characterization of porous solids. Pure Appl Chem 66(8):1739–1758CrossRef Rouquerol J, Avnir D, Fairbridge CW, Everett DH, Haynes JH, Pernicone N, Ramsay JDF, Sing KSW, Unger KK (1994) Recommendations for the characterization of porous solids. Pure Appl Chem 66(8):1739–1758CrossRef
23.
Zurück zum Zitat Livage J, Henry M, Sanchez C (1988) Sol–gel chemistry of transition metal oxides. Prog Solid State Chem 18(5):259–341CrossRef Livage J, Henry M, Sanchez C (1988) Sol–gel chemistry of transition metal oxides. Prog Solid State Chem 18(5):259–341CrossRef
24.
Zurück zum Zitat Duraes L, Costa BFO, Vasques J, Campos J, Portugal A (2005) Phase investigation of as-prepared iron oxide/hydroxide produced by sol–gel synthesis. Mater Lett 59(7):859–863CrossRef Duraes L, Costa BFO, Vasques J, Campos J, Portugal A (2005) Phase investigation of as-prepared iron oxide/hydroxide produced by sol–gel synthesis. Mater Lett 59(7):859–863CrossRef
Metadaten
Titel
Synthesis of a low-density tantalum oxide tile-like aerogel monolithic
verfasst von
Hongbo Ren
Lin Zhang
Chengwei Shang
Xian Wang
Yutie Bi
Publikationsdatum
01.02.2010
Verlag
Springer US
Erschienen in
Journal of Sol-Gel Science and Technology / Ausgabe 2/2010
Print ISSN: 0928-0707
Elektronische ISSN: 1573-4846
DOI
https://doi.org/10.1007/s10971-009-2092-1

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