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Journal of Sol-Gel Science and Technology

Erschienen in:

11.06.2020 | Original Paper: Sol-gel and hybrid materials for energy, environment and building applications

Synthesis of magnetically separable Bi₂O₂CO₃/carbon nanotube/ZnFe₂O₄ as Z-scheme heterojunction with enhanced photocatalytic activity for water purification

verfasst von: Aftab Aslam Parwaz Khan, Pardeep Singh, Pankaj Raizada, Abdullah M. Asiri

Erschienen in: Journal of Sol-Gel Science and Technology | Ausgabe 2/2020

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Abstract

To utilize Bi₂O₂CO₃ as an efficient photocatalyst, it is of utmost interest to design a system that not only promotes the broad range absorption but also facilitates recyclability and speedy separation of photocatalyst. In this work, magnetically separable Z-scheme Bi₂O₂CO₃/carbon nanotubes/ZnFe₂O₄ photocatalyst (BOC/CNT/ZF) was synthesized through a simplistic one-step hydrothermal approach investigated for 2,4-dimethyl phenol (DMP) degradation under visible light exposure. The structural and morphological features of photocatalyst were explored using XRD, FTIR, FESEM, HRTEM, and EDX mapping analysis. The UV-visible spectroscopy indicated extended visible light activity of prepared photocatalyst. The photocatalyst was magnetically separated from reaction solution in 20 s. The Z-scheme approach during photocatalysis process was validated using radical scavenging, electrochemical impedance and photoluminescence analysis. CNT mediated Z-scheme electron migration mechanism was proposed which explicate remarkable augmentation in photodegradation ability for DMP degradation. The hydroxyl radicals generated via Z-scheme mode were responsible for mineralization of DMP into CO₂ and H₂O. BOC/CNT/ZF photocatalyst displayed significant photocatalytic efficiency during the recycle experiment. In addition, significant activity for other phenolic compounds credited it as perspective for long-term practical use in environmental remediation.

Vorheriger Artikel Preparation and microstructure characterization of crack-free zirconium nitride microspheres by internal gelation combined with two-step nitridation

Nächster Artikel Effect of the reducing atmospheres on the photoluminescent and phosphorescent properties of Sr4Al14O25:Eu2+, Dy3+, Cr3+ phosphors

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Chandel N, Sharma K, Sudhaik A, Raizada P, Bandegharaei AH, Thakur VK, Singh P (2020) Magnetically separable ZnO/ZnFe₂O₄ and ZnO/CoFe₂O₄ photocatalysts supported onto nitrogen doped graphene for photocatalytic degradation of toxic dyes. Arab J Chem 13(2):4324–4340CrossRef

Kumar A, Raizada P, Singh P, Saini R, Saini A, Bandegharaei AH (2020) Perspective and status of polymeric graphitic carbon-nitride based Z-scheme photocatalytic systems for sustainable photocatalytic water purification. Chem Eng J 391:123496CrossRef

Hasija V, Raizada P, Sudhaik A, Sharma K, Kumar A, Singh P, Jonnalagadda SB, Thakur VK (2019) Recent advances in noble metal free doped graphitic carbon nitride based nanohybrids for photocatalysis of organic contaminants in water: a review. Appl Mater Today 15:494–524CrossRef

Singh P, Sharma K, Hasija V, Sharma V, Sharma S, Raizada P, Singh M, Saini AK, Bandegharaei AH, Thakur VK (2019) Systematic review on applicability of magnetic iron oxides–integrated photocatalysts for degradation of organic pollutants in water. Mater Today Chem 14:100186CrossRef

Singh P, Shandilya P, Raizada P, Sudhaik A, Sani AR, Bandegharaei AH (2020) Review on various strategies for enhancing photocatalytic activity of graphene-based nanocomposites for water purification. Arab J Chem 13(1):3498–3520CrossRef

Sharma S, Dutta V, Singh P, Raizada P, Sani AR, Bandegharaei AH, Thakur VK (2019) Carbon quantum dot supported semiconductor photocatalysts for efficient degradation of organic pollutants in water: A review. J Clean Prod 228:755–769CrossRef

Dutta V, Singh P, Shandilya P, Sharma S, Raizada P, Saini AK, Gupta VK, Bandegharaei AH, Agarwal S, Sani AR (2019) Review on advances in photocatalytic water disinfection utilizing graphene and graphene derivatives-based nanocomposites. J Environ Chem Eng 7:103132CrossRef

Raizada P, Sudhaik A, Singh P, Shandilya P, Saini AK, Gupta VK, Lim JH, Jung H, Bandegharaei AH (2019) Fabrication of Ag₃VO₄ decorated phosphorus and sulphur co-doped graphitic carbon nitride as a high-dispersed photocatalyst for phenol mineralization and E coli disinfection. Sep Purif Technol 212:887–900CrossRef

Dionysiou DD, Khodadoust AP, Kern AM, Suidan MT, Baudin I, Laîné JM (2000) Continuous-mode photocatalytic degradation of chlorinated phenols and pesticides in water using a bench-scale TiO₂ rotating disk reactor. Appl Catal B: Environ 24:139–155CrossRef

10.

Yu S, Yun HJ, Kim YH, Yi J (2014) Carbon-doped TiO₂ nanoparticles wrapped with nanographene as a high performance photocatalyst for phenol degradation under visible light irradiation. Appl Catal B: Environ 144:893–899CrossRef

11.

An G, Ma W, Sun Z, Liu Z, Han B, Miao S, Miao Z, Ding K (2001) Preparation of titania/carbon nanotube composites using supercritical ethanol and their photocatalytic activity for phenol degradation under visible light irradiation. Carbon 45:1795–1801CrossRef

12.

Long M, Cai W, Cai J, Zhou B, Chai X, Wu Y (2006) Efficient photocatalytic degradation of phenol over Co₃O₄/BiVO₄ composite under visible light irradiation. J Phy Chem B 110:20211–20216CrossRef

13.

Sharma K, Dutta V, Sharma S, Raizada P, Bandegharaei AH, Thakur P, Singh P (2019) Recent advances in enhanced photocatalytic activity of bismuth oxyhalides for efficient photocatalysis of organic pollutants in water: a review. J Ind Eng Chem 78:1–20CrossRef

14.

Singh P, Sudhaik A, Raizada P, Shandilya P, Sharma R, Bandegharaei AH (2019) Photocatalytic performance and quick recovery of BiOI/Fe₃O₄@ graphene oxide ternary photocatalyst for photodegradation of 2, 4-dintirophenol under visible light. Mater Today Chem 12:85–95CrossRef

15.

Sajjadi SA, Meknati A, Lima EC, Dotto GL, Castillo DIM, Anastopoulos I, Alakhras F, Unuabonah EI, Singh P, Bandegharaei AH (2019) A novel route for preparation of chemically activated carbon from pistachio wood for highly efficient Pb (II) sorption. J Environ Manag 236:34–44CrossRef

16.

Majhi D, Das K, Mishra A, Dhiman R, Mishra BG (2020) One pot synthesis of CdS/BiOBr/Bi₂O₂CO₃: a novel ternary double Z-scheme heterostructure photocatalyst for efficient degradation of atrazine. Appl Catal B: Environ 260:118222CrossRef

17.

Ye L, Liu J, Gong C, Tian L, Peng T, Zan L (2012) Two different roles of metallic Ag on Ag/AgX/BiOX (X = Cl, Br) visible light photocatalysts: surface plasmon resonance and Z-scheme bridge. ACS Catal 2:1677–1683CrossRef

18.

Liu Y, Ren H, Lv H, Guang J, Cao Y (2018) Synthesis of magnetic Bi₂O₂CO₃/ZnFe₂O₄ composite with improved photocatalytic activity and easy recyclability. Appl Surf Sci 433:610–616CrossRef

19.

Liang N, Wang M, Jin L, Huang S, Chen W, Xu M, He Q, Zai J, Fang N, Qian X (2014) Highly efficient Ag₂O/Bi₂O₂CO₃pn heterojunction photocatalysts with improved visible-light responsive activity. ACS Appl Mater Interface 6:11698–11705CrossRef

20.

Zhou Y, Zhao Z, Wang F, Cao K, Doronkin DE, Dong F, Grunwaldt JD (2016) Facile synthesis of surface N-doped Bi₂O₂CO₃: origin of visible light photocatalytic activity and in situ DRIFTS studies. J Hazard Mater 307:163–172CrossRef

21.

Madhusudan P, Ran J, Zhang J, Yu J, Liu G (2011) Novel urea assisted hydrothermal synthesis of hierarchical BiVO₄/Bi₂O₂CO₃ nanocomposites with enhanced visible-light photocatalytic activity. Appl Catal B: Environ 110:286–295CrossRef

22.

Lu H, Xu L, Wei B, Zhang M, Gao H, Sun W (2014) Enhanced photosensitization process induced by the p–n junction of Bi₂O₂CO₃/BiOCl heterojunctions on the degradation of rhodamine B. Appl Surf Sci 303:360–366CrossRef

23.

Wang Z, Wang J, Pan Y, Liu F, Lai Y, Li J, Jiang L (2020) Preparation and characterization of a novel and recyclable InVO₄/ZnFe₂O₄ composite for methylene blue removal by adsorption and visible-light photocatalytic degradation. Appl Surf Sci 501:144006CrossRef

24.

Zhu C, Zhang L, Jiang B, Zheng J, Hu P, Li S, Wu M, Wu W (2016) Fabrication of Z-scheme Ag₃PO₄/MoS₂ composites with enhanced photocatalytic activity and stability for organic pollutant degradation. Appl Surf Sci 377:99–108CrossRef

25.

Zhou P, Yu J, Jaroniec M (2014) All-solid-state Z-scheme photocatalytic systems. Adv Mater 26:4920–4935CrossRef

26.

Raizada P, Thakur P, Sudhaik A, Singh P, Thakur VK, Bandegharaei AH (2019) Fabrication of dual Z-scheme photocatalyst via coupling of BiOBr/Ag/AgCl heterojunction with P and S co-doped g-C₃N₄ for efficient phenol degradation. Arab J Chem https://doi.org/10.1016/j.arabjc.2019.10.001

27.

Chen Z, Wang W, Zhang Z, Fang X (2013) High-efficiency visible-light-driven Ag₃PO₄/AgI photocatalysts: Z-scheme photocatalytic mechanism for their enhanced photocatalytic activity. J Phy Chem C 117:19346–19352CrossRef

28.

Huang Y, Zhu D, Zhang Q, Zhang Y, Cao J, Shen Z, Ho W, Lee SC (2018) Synthesis of a Bi₂O₂CO₃/ZnFe₂O₄ heterojunction with enhanced photocatalytic activity for visible light irradiation-induced NO removal. Appl Catal B: Environ 234:70–78CrossRef

29.

Shi Q, Zhao W, Xie L, Chen J, Zhang M, Li Y (2016) Enhanced visible-light driven photocatalytic mineralization of indoor toluene via a BiVO₄/reduced graphene oxide/Bi₂O₃ all-solid-state Z-scheme system. J Alloy Compd 662:108–117CrossRef

30.

Shen H, Wang J, Jiang J, Luo B, Mao B, Shi W (2017) All-solid-state Z-scheme system of RGO-Cu₂O/Bi₂O₃ for tetracycline degradation under visible-light irradiation. Chem Eng J 313:508–517CrossRef

31.

Mohamed HH (2019) Rationally designed Fe₂O₃/GO/WO₃ Z-Scheme photocatalyst for enhanced solar light photocatalytic water remediation. J Photochem Photobio A: Chem 378:74–84CrossRef

32.

Di L, Yang H, Xian T, Chen X (2018) Construction of Z-scheme g-C₃N₄/CNT/Bi₂Fe₄O₉ composites with improved simulated-sunlight photocatalytic activity for the dye degradation. Micromachines 9:613CrossRef

33.

Ma D, Wu J, Gao M, Xin Y, Chai C (2017) Enhanced debromination and degradation of 2, 4-dibromophenol by Z-scheme Bi₂MoO₆/CNTs/g-C₃N₄ visible light photocatalyst. Chem Eng J 316:461–470CrossRef

34.

Gan J, Zhang J, Zhang B, Chen W, Niu D, Qin Y, Duan X, Zhou X (2020) Active sites engineering of Pt/CNT oxygen reduction catalysts by atomic layer deposition. J Energy Chem 45:59–66CrossRef

35.

Li F, Yin Y, Zhang C, Li W, Maliutina K, Zhang Q, Wu Q (2020) Enhancing oxygen reduction performance of oxide-CNT through in-situ generated nanoalloy bridging. Appl Catal B: Environ 263:118297CrossRef

36.

Dhiman M, Sharma R, Kumar V, Singhal S (2016) Morphology controlled hydrothermal synthesis and photocatalytic properties of ZnFe₂O₄ nanostructures. Ceram Int 42(11):12605CrossRef

37.

Pare B, Singh P, Jonnalgadda SB (2009) Degradation and mineralization of victoria blue B dye in a slurry photoreactor using advanced oxidation process. J Sci Ind Res 68:724–729

38.

APHA (1985) Standard methods for examination of water and wastewater, 6th edn. American Public Health Association, American Water Works Association, Water Environment Federation, New York, NY, pp 535–543

39.

Pare B, Singh P, Jonnalagadda SB (2008) Visible light induced heterogeneous advanced oxidation process to degrade pararosanilin dye in aqueous suspension of ZnO. Indian J Chem 47:830–835

40.

Maiti SK (2011) Handbook of methods in environmental studies: Water and waste water analysis. Oxford Book Company, Jaipur, India, pp 110–121

41.

Fu Y, Wang X (2011) Magnetically separable ZnFe₂O₄–graphene catalyst and its high photocatalytic performance under visible light irradiation. Ind Eng Chem Res 50:7210–7218CrossRef

42.

Majhi D, Bhoi YP, Samal PK, Mishra BG (2018) Morphology controlled synthesis and photocatalytic study of novel CuS-Bi₂O₂CO₃ heterojunction system for chlorpyrifos degradation under visible light illumination. Appl Surf Sci 455:891–902CrossRef

43.

Chandel N, Sharma K, Sudhaik A, Raizada P, Bandegharaei AH, Thakur VK, Singh P (2019) Magnetically separable ZnO/ZnFe₂O₄ and ZnO/CoFe₂O₄ photocatalysts supported onto nitrogen doped graphene for photocatalytic degradation of toxic dyes. Arab J Chem. https://doi.org/10.1016/j.arabjc.2019.08.005

44.

Eren O, Ucar N, Onen A, Kizildag N, Karacan I (2016) Synergistic effect of polyaniline, nanosilver, and carbon nanotube mixtures on the structure and properties of polyacrylonitrile composite nanofiber. J Compos Mater 50:2073–2086CrossRef

45.

Xu Q, Feng J, Li L, Xiao Q, Wang J (2015) Hollow ZnFe₂O₄/TiO₂ composites: high-performance and recyclable visible-light photocatalyst. J Alloy Compd 641:110–118CrossRef

46.

Raizada P, Sudhaik A, Singh P, Bandegharaei AH, Thakur P (2019) Converting type II AgBr/VO into ternary Z scheme photocatalyst via coupling with phosphorus doped g-C₃N₄ for enhanced photocatalytic activity. Sep Purif Technol 227:115692CrossRef

47.

Shandilya P, Mittal D, Sudhaik A, Soni M, Raizada P, Saini AK, Singh P (2019) GdVO₄ modified fluorine doped graphene nanosheets as dispersed photocatalyst for mitigation of phenolic compounds in aqueous environment and bacterial disinfection. Sep Purif Technol 210:804–816CrossRef

48.

Zhao Z, Zhou Y, Wang F, Zhang K, Yu S, Cao K (2015) Polyaniline-Decorated {001} facets of Bi₂O₂CO₃ Nanosheets: In situ oxygen vacancy formation and enhanced visible light photocatalytic activity. ACS Appl Mater Inter 7:730–737CrossRef

49.

Boumaza S, Boudjemaa A, Bouguelia A, Bouarab R, Trari M (2010) Visible light induced hydrogen evolution on new hetero-system ZnFe₂O₄/SrTiO₃. Appl Energ 87:2230–2236CrossRef

50.

Sudhaik A, Raizada P, Shandilya P, Singh P (2018) Magnetically recoverable graphitic carbon nitride and NiFe₂O₄ based magnetic photocatalyst for degradation of oxytetracycline antibiotic in simulated wastewater under solar light. J Environ Chem Eng 6:3874–3883CrossRef

51.

Dang H, Qiu Y, Cheng Z, Yang W, Wu H, Hongbo F, Xinfa D (2016) Hydrothermal preparation and characterization of nanostructured CNTs/ZnFe₂O₄ composites for solar water splitting application. Ceram Int 42(8):10520–10525CrossRef

52.

Raizada P, Sudhaik A, Singh P, Shandilya P, Thakur P, Jung H (2018) Visible light assisted photodegradation of 2, 4-dinitrophenol using Ag₂CO₃ loaded phosphorus and sulphur co-doped graphitic carbon nitride nanosheets in simulated wastewater. Arab J Chem. https://doi.org/10.1016/j.arabjc.2018.10.004

53.

Hasija V, Sudhaik A, Raizada P, Bandegharaei AH, Singh P (2019) Carbon quantum dots supported AgI/ZnO/phosphorus doped graphitic carbon nitride as Z-scheme photocatalyst for efficient photodegradation of 2, 4-dinitrophenol. J Environ Chem Eng 7:103272CrossRef

54.

Hu J, Zhang P, An W, Liu L, Liang Y, Cui W (2019) In-situ Fe-doped g-C₃N₄ heterogeneous catalyst via photocatalysis-Fenton reaction with enriched photocatalytic performance for removal of complex wastewater. Appl Catal B: Environ 245:130–142CrossRef

55.

Pare B, Singh P, Jonnalgadda SB (2009) Artificial light assisted photocatalytic degradation of lissamine fast yellow dye in ZnO suspension in a slurry batch reactor. Indian J Chem 48A:1364–1369

56.

Priya B, Shandilya P, Raizada P, Thakur P, Singh N, Singh P (2016) Photocatalytic mineralization and degradation kinetics of ampicillin and oxytetracycline antibiotics using graphene sand composite and chitosan supported BiOCl. J Mol Catal A: Chem 423:400–413CrossRef

57.

Singh P, Raizada P, Sudhaik A, Shandilya P, Thakur P, Agarwal S, Gupta VK (2019) Enhanced photocatalytic activity and stability of AgBr/BiOBr/graphene heterojunction for phenol degradation under visible light. J Saudi Chem Soc 23:586–599CrossRef

58.

Lee H, Kannan P, Al Shoaib A, Srinivasakannan C (2019) Phenol degradation catalysed by metal oxide supported porous carbon matrix under UV irradiation. J Water. Process Eng 31:100869

59.

Raizada P, Singh S (2017) Hybrid metal oxide semiconductors for waste water treatment. Environ Sci Eng 4:187–206

60.

Singh P, Priya B, Shandilya P, Raizada P, Singh N, Pare B, Jonnalagadda SB (2016) Photocatalytic mineralization of antibiotics using 60% WO₃/BiOCl stacked to graphene sand composite and chitosan. Arab J Chem. https://doi.org/10.1016/j.arabjc.2016.08.005

61.

Cai C, Zhang Z, Liu J, Shan N, Zhang H, Dionysiou DD (2016) Visible light-assisted heterogeneous Fenton with ZnFe₂O₄ for the degradation of Orange II in water. Appl Catal B: Environ 182:456–468CrossRef

62.

Li J, Liu Z, Zhu Z (2014) Magnetically separable ternary hybrid of ZnFe₂O₄–Fe₂O₃–Bi₂WO₆ hollow nanospheres with enhanced visible photocatalytic property. Appl Surf Sci 320:146–153CrossRef

63.

Li Y, Li Y, Yin Y, Xia D, Ding H, Ding C, Wu J (2018) Facile synthesis of highly efficient ZnO/ZnFe₂O₄ photocatalyst using earth-abundant sphalerite and its visible light photocatalytic activity. Appl Catal B: Environ 226:324–336CrossRef

64.

Andrade LS, Laurindo EA, Oliveira RVD, Rocha-Filho RC (2006) QB Cass Development of a HPLC method to follow the degradation of phenol by electrochemical or photoelectrochemical treatment. J Braz Chem Soc 17:369–373CrossRef

Titel: Synthesis of magnetically separable Bi2O2CO3/carbon nanotube/ZnFe2O4 as Z-scheme heterojunction with enhanced photocatalytic activity for water purification
verfasst von: Aftab Aslam Parwaz Khan
Pardeep Singh
Pankaj Raizada
Abdullah M. Asiri
Publikationsdatum: 11.06.2020
Verlag: Springer US
Erschienen in: Journal of Sol-Gel Science and Technology / Ausgabe 2/2020
Print ISSN: 0928-0707
Elektronische ISSN: 1573-4846
DOI: https://doi.org/10.1007/s10971-020-05336-6

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