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Journal of Materials Science
Erschienen in: Journal of Materials Science 5/2017

04.11.2016 | Original Paper

Synthesis of polypyrrole/Fe-kanemite nanocomposite through in situ polymerization: effect of iron exchange, acid treatment, and CO2 adsorption properties

verfasst von: Bouhadjar Boukoussa, Fatiha Abidallah, Zakaria Abid, Zoulikha Talha, Nafissa Taybi, Hadjer Sid El Hadj, Rachid Ghezini, Rachida Hamacha, Abdelkader Bengueddach

Erschienen in: Journal of Materials Science | Ausgabe 5/2017

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Abstract

This paper focuses on the synthesis of polypyrrole/Fe-kanemite nanocomposites by in situ polymerization of pyrrole. Different percentages of PPy/Fe-kan have been prepared and tested for the CO2 adsorption. Fe-exchanged kanemite was prepared using various iron contents and used as an oxidant for the preparation of PPy/Fe-kan nanocomposite. The obtained materials were characterized using various techniques such as X-ray diffraction (XRD), Fourier transform infrared spectroscopy, ultraviolet–visible (UV–vis), thermogravimetric analysis TGA, energy dispersive X-ray analysis, scanning and transmission electronic microscopy (SEM, TEM). Based on the XRD and UV–vis analysis, the exchange process leads to the formation of various iron species on the external and internal surface. The thermal stability of PPy/Fe-kan was improved and increased in the following order PPy/Fe-kan (1%) > PPy/Fe-kan (3%) > PPy/Fe-kan (5%) > PPy/Fe-kan (10%) > PPy. SEM and TEM analysis show that the nanocomposite particles have spherical morphology with a high dispersion of the Fe-kanemite in the polymer matrix. CO2 adsorption at 0 and 15 °C was carried using a volumetric method, and the recorded isotherm indicated that the CO2 adsorption capacity of PPy/Fe-kan can be enhanced through modification by polypyrrole. The unmodified Na-kanemite has low CO2 adsorption capacity around 0.05 mmol g−1 at 15 °C, while the PPy/Fe-kan (5%) nanocomposite presented the best CO2 adsorption capacity around 1.7 mmol g−1 at 0 °C under low pressure that is mainly attributable to physical adsorption.
Vorheriger Artikel On polystyrene–block polyisoprene–block polystyrene filled with carbon-coated Ni nanoparticles
Nächster Artikel Design and fabrication of imidazolium ion-immobilized electrospun polyurethane membranes with antibacterial activity

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Metadaten
Titel
Synthesis of polypyrrole/Fe-kanemite nanocomposite through in situ polymerization: effect of iron exchange, acid treatment, and CO2 adsorption properties
verfasst von
Bouhadjar Boukoussa
Fatiha Abidallah
Zakaria Abid
Zoulikha Talha
Nafissa Taybi
Hadjer Sid El Hadj
Rachid Ghezini
Rachida Hamacha
Abdelkader Bengueddach
Publikationsdatum
04.11.2016
Verlag
Springer US
Erschienen in
Journal of Materials Science / Ausgabe 5/2017
Print ISSN: 0022-2461
Elektronische ISSN: 1573-4803
DOI
https://doi.org/10.1007/s10853-016-0541-0

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