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Journal of Materials Science
Erschienen in: Journal of Materials Science 3/2019

19.10.2018 | Chemical routes to materials

Synthesis of two novel H4TCPBDA-based metal–organic frameworks and their application in lead ion adsorption

verfasst von: Yanzi Wu, Yujie Ma, Guanhong Xu, Tianyi Xia, Wenxuan Liu, Zezhong Dong, Qing Yuan, Cong Zhang, Qin Hu

Erschienen in: Journal of Materials Science | Ausgabe 3/2019

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Abstract

Two novel porous metal–organic frameworks (MOFs) Cu(TCPBDA) and Cd(TCPBDA) based on a new ligand, namely N,N,N′,N′-tetrakis(4-carboxyphenyl)biphenyl-4,4′-diamine (H4TCPBDA), were synthesized by solvent thermal method and characterized with scanning electron microscopy, powder X-ray diffraction, BET analysis and spectrofluorometry. The static adsorption of the two MOFs for lead ions (Pb2+) was investigated. Cu(TCPBDA) showed a higher adsorption capacity for Pb2+ compared with Cd(TCPBDA), and its maximum adsorption capacity was 300 mg/g. The adsorption performance of Cu(TCPBDA) was then further studied. It was found that the adsorption of Cu(TCPBDA) for Pb2+ fitted the Freundlich model and pseudo-second-order equation very well. The adsorption ability of Cu(TCPBDA) was applied to fast and efficient adsorption for Pb2+ in toner. The results indicates that Cu(TCPBDA) is a promising material in adsorption and removal of heavy metal ions.
Vorheriger Artikel Robust fabrication of superhydrophobic and photocatalytic self-cleaning cotton textile based on TiO2 and fluoroalkylsilane
Nächster Artikel Influence of hygrothermal aging on the durability and interfacial performance of pultruded glass fiber-reinforced polymer composites

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Metadaten
Titel
Synthesis of two novel H4TCPBDA-based metal–organic frameworks and their application in lead ion adsorption
verfasst von
Yanzi Wu
Yujie Ma
Guanhong Xu
Tianyi Xia
Wenxuan Liu
Zezhong Dong
Qing Yuan
Cong Zhang
Qin Hu
Publikationsdatum
19.10.2018
Verlag
Springer US
Erschienen in
Journal of Materials Science / Ausgabe 3/2019
Print ISSN: 0022-2461
Elektronische ISSN: 1573-4803
DOI
https://doi.org/10.1007/s10853-018-3008-7

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