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Journal of Materials Science
Erschienen in: Journal of Materials Science 22/2020

30.04.2020 | Energy materials

Template-assisted synthesis of LiNi0.8Co0.15Al0.05O2 hollow nanospheres as cathode material for lithium ion batteries

verfasst von: Xiaoyu Wu, Junjie Lu, Yue Han, Huayu Wu, Lingli Bu, Ju Xie, Chen Qian, Haibo Li, Guowang Diao, Ming Chen

Erschienen in: Journal of Materials Science | Ausgabe 22/2020

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Abstract

Based on hydrothermal synthesis and solid-phase thermal reaction, LiNi0.8Co0.15Al0.05O2 hollow nanospheres (LNCA HNSs) were synthesized by using SiO2 hollow nanospheres as hard template. Firstly, the SiO2 HNSs were prepared. Then, (Ni0.8Co0.15Al0.05)CO3 nanosheets grew on the surface of SiO2 HNSs to form SiO2@(Ni0.8Co0.15Al0.05)CO3 hollow nanospheres with double shells by hydrothermal method. Finally, the above precursors and lithium source were calcined at high temperature, and then SiO2 template was etched to obtain hollow LNCA HNSs. The characterization results showed that the LNCA HNSs are hollow spheres with a diameter of about 1.8 μm. The shell thickness of LNCA HNSs is about 300 nm. Compared with LNCA nanoparticles and LNCA microparticles, LNCA HNSs showed excellent stability, high capacity, and good rate performance as cathode materials for lithium ion batteries. The LNCA HNSs exhibited a reversible capacity of 202.4 mA h g−1 at 0.1 C and good stability of 179.1 mA h g−1 at 1 C after 80 cycles.
Vorheriger Artikel Structural and electronic properties of BaSi2(100) thin film on Si(111) substrate
Nächster Artikel A novel SiO2 nanofiber-supported organic–inorganic gel polymer electrolyte for dendrite-free lithium metal batteries

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Metadaten
Titel
Template-assisted synthesis of LiNi0.8Co0.15Al0.05O2 hollow nanospheres as cathode material for lithium ion batteries
verfasst von
Xiaoyu Wu
Junjie Lu
Yue Han
Huayu Wu
Lingli Bu
Ju Xie
Chen Qian
Haibo Li
Guowang Diao
Ming Chen
Publikationsdatum
30.04.2020
Verlag
Springer US
Erschienen in
Journal of Materials Science / Ausgabe 22/2020
Print ISSN: 0022-2461
Elektronische ISSN: 1573-4803
DOI
https://doi.org/10.1007/s10853-020-04627-1

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