nach oben

Journal of Sol-Gel Science and Technology

Erschienen in:

01.10.2014 | Original Paper

Template-directed synthesis of ordered iron pyrite (FeS₂) nanowires and nanotubes arrays

verfasst von: Yi Li, Zili Han, Liangxing Jiang, Zhenghua Su, Fangyang Liu, Yanqing Lai, Yexiang Liu

Erschienen in: Journal of Sol-Gel Science and Technology | Ausgabe 1/2014

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config

KI-gestützte Suche

Aus

Abstract

Highly ordered iron pyrite (FeS₂) nanowires and nanotubes arrays have been fabricated by using sol–gel method with AAO templates. The prepared nanowires and nanotubes have uniform lengths and 200 nm diameters. Their crystal phase was identified as cubic FeS₂ by using X-ray diffraction, Raman spectroscopy, high-resolution transmission electron microscopy and selected-area electron diffraction pattern. The direct optical band gaps of the as-prepared FeS₂ nanowires were 0.98 and 1.23 eV, respectively, indicating their suitability for photovoltaic application.

Vorheriger Artikel Synthesis of ZnO/Cu2S core/shell nanorods and their enhanced photoelectric performance

Nächster Artikel A novel pH-responsive controlled release system based on mesoporous silica coated with hydroxyapatite

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

über 67.000 Bücher
über 390 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Maschinenbau + Werkstoffe

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

über 102.000 Bücher
über 537 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Finance + Banking
Management + Führung
Marketing + Vertrieb
Maschinenbau + Werkstoffe
Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Wadia C, Alivisatos AP, Kammen DM (2009) Materials availability expands the opportunity for large-scale photovoltaics deployment. Environ Sci Technol 43(6):2072–2077. doi:10.1021/es8019534 CrossRef

Ennaoui A, Fiechter S, Pettenkofer C, Alonso-Vante N, Büker K, Bronold M, Höpfner C, Tributsch H (1993) Iron disulfide for solar energy conversion. Sol Energy Mater Sol Cells 29(4):289–370. doi:10.1016/0927-0248(93)90095-k CrossRef

Ennaoui A, Tributsch H (1986) Energetic characterization of the photoactive FeS₂ (pyrite) interface. Sol Energy Mater 14(6):461–474. doi:10.1016/0165-1633(86)90030-4 CrossRef

Ennaoui A, Fiechter S, Jaegermann W, Tributsch H (1986) Photoelectrochemistry of highly quantum efficient single-crystalline n-FeS₂ (pyrite). J Electrochem Soc 133(1):97–106. doi:10.1149/1.2108553 CrossRef

Ennaoui A, Tributsch H (1984) Iron sulphide solar cells. Sol Cells 13(2):197–200. doi:10.1016/0379-6787(84)90009-7 CrossRef

Antonucci V, Arico AS, Giordano N, Antonucci PL, Russo U, Cocke DL, Crea F (1991) Photoactive screen-printed pyrite anodes for electrochemical photovoltaic cells. Sol Cells 31(2):119–141. doi:10.1016/0379-6787(91)90016-i CrossRef

Ennaoui A, Fiechter S, Tributsch H, Giersig M, Vogel R, Weller H (1992) Photoelectrochemical energy conversion obtained with ultrathin organo-metallic-chemical-vapor-deposition layer of FeS₂ (pyrite) on TiO₂. J Electrochem Soc 139(9):2514–2518. doi:10.1149/1.2221255 CrossRef

Buker K, Alonso-Vante N, Tributsch H (1992) Photovoltaic output limitation of n-FeS₂ (pyrite) Schottky barriers: a temperature-dependent characterization. J Appl Phys 72(12):5721–5728. doi:10.1063/1.351925 CrossRef

Spagnoli D, Refson K, Wright K, Gale JD (2010) Density functional theory study of the relative stability of the iron disulfide polymorphs pyrite and marcasite. Phys Rev B 81(9):094106. doi:10.1103/PhysRevB.81.094106 CrossRef

10.

Alonso-Vante N, Chatzitheodorou G, Fiechter S, Mgoduka N, Poulios I, Tributsch H (1988) Interfacial behavior of hydrogen-treated sulphur deficient pyrite. Sol Energy Mater 18(1–2):9–21. doi:10.1016/0165-1633(88)90041-x CrossRef

11.

Wadia C, Wu Y, Gul S, Volkman SK, Guo J, Alivisatos AP (2009) Surfactant-assisted hydrothermal synthesis of single phase pyrite FeS₂ nanocrystals. Chem Mater 21(13):2568–2570. doi:10.1021/cm901273v CrossRef

12.

Birkholz M, Fiechter S, Hartmann A, Tributsch H (1991) Sulfur deficiency in iron pyrite FeS_2−x and its consequences for band-structure models. Phys Rev B 43(14):11926–11936. doi:10.1103/PhysRevB.43.11926 CrossRef

13.

von Oertzen GU, Skinner WM, Nesbitt HW (2005) Ab initio and X-ray photoemission spectroscopy study of the bulk and surface electronic structure of pyrite (100) with implications for reactivity. Phys Rev B 72(23):235427. doi:10.1103/PhysRevB.72.235427 CrossRef

14.

Bronold M, Tomm Y, Jaegermann W (1994) Surface states on cubic d-band semiconductor pyrite (FeS₂). Surf Sci 314(3):L931–L936. doi:10.1016/0039-6028(94)90230-5 CrossRef

15.

Bronold M, Pettenkofer C, Jaegermann W (1994) Surface photovoltage measurements on pyrite (100) cleavage planes: evidence for electronic bulk defects. J Appl Phys 76(10):5800–5808. doi:10.1063/1.358393 CrossRef

16.

Sun R, Chan M, Ceder G (2011) First-principles electronic structure and relative stability of pyrite and marcasite: implications for photovoltaic performance. Phys Rev B 83(23):235311. doi:10.1103/PhysRevB.83.235311 CrossRef

17.

Ennaoui A, Schlichthorl G, Fiechter S, Tributsch H (1992) Vapor phase epitaxial growth of FeS₂ pyrite and evaluation of the carrier collection in liquid-junction solar cell. Sol Energy Mater Sol Cells 25(1–2):169–178. doi:10.1016/0927-0248(92)90025-k CrossRef

18.

Thomas B, Ellmer K, Müller M, Höpfner C, Fiechter S, Tributsch H (1997) Structural and photoelectrical properties of FeS₂ (pyrite) thin films grown by MOCVD. J Cryst Growth 170(1–4):808–812. doi:10.1016/s0022-0248(96)00600-8 CrossRef

19.

De las Heras C, Ferrer IJ, Sánchez C (1991) Comparison of pyrite thin films obtained from Fe and natural pyrite powder. Appl Surf Sci 50(1–4):505–509. doi:10.1016/0169-4332(91)90227-b CrossRef

20.

Ferrer IJ, Sánchez C (1991) Characterization of FeS₂ thin films prepared by thermal sulfidation of flash evaporated iron. J Appl Phys 70(5):2641. doi:10.1063/1.349377 CrossRef

21.

Huang L, Wang F, Luan Z, Meng L (2010) Pyrite (FeS₂) thin films deposited by sol–gel method. Mater Lett 64(23):2612–2615. doi:10.1016/j.matlet.2010.08.070 CrossRef

22.

Birkholz M, Lichtenberger D, Höpfner C, Fiechter S (1992) Sputtering of thin pyrite films. Sol Energy Mater Sol Cells 27(3):243–251. doi:10.1016/0927-0248(92)90086-5 CrossRef

23.

Yamamoto A, Nakamura M, Seki A, Li EL, Hashimoto A, Nakamura S (2003) Pyrite (FeS₂) thin films prepared by spray method using FeSO₄ and (NH₄)₂S_x. Sol Energy Mater Sol Cells 75(3–4):451–456. doi:10.1016/s0927-0248(02)00205-2 CrossRef

24.

Iijima S (1991) Helical microtubules of graphitic carbon. Nature 354(6348):56–58. doi:10.1038/354056a0 CrossRef

25.

Alivisatos AP (1996) Semiconductor clusters, nanocrystals, and quantum dots. Science 271(5251):933. doi:10.1126/science.271.5251.933 CrossRef

26.

Hu J, Ouyang M, Yang P, Lieber CM (1999) Controlled growth and electrical properties of heterojunctions of carbon nanotubes and silicon nanowires. Nature 399(6731):48–51. doi:10.1038/19941 CrossRef

27.

Wang X, Gao P, Li J, Summers CJ, Wang ZL (2002) Rectangular porous ZnO–ZnS nanocables and ZnS nanotubes. Adv Mater 14(23):1732–1735. doi:10.1002/1521-4095(20021203)14:23<1732:aid-adma1732>3.0.co;2-5 CrossRef

28.

Peng H, Schoen DT, Meister S, Zhang XF, Cui Y (2006) Synthesis and phase transformation of In₂Se₃ and CuInSe₂ nanowires. J Am Chem Soc 129(1):34–35. doi:10.1021/ja067436k CrossRef

29.

Tian B, Kempa TJ, Lieber CM (2009) Single nanowire photovoltaics. Chem Soc Rev 38(1):16–24. doi:10.1039/B718703N CrossRef

30.

Law M, Greene LE, Johnson JC, Saykally R, Yang P (2005) Nanowire dye-sensitized solar cells. Nat Mater 4(6):455–459. doi:10.1038/nmat1387 CrossRef

31.

Bi Y, Yuan Y, Exstrom CL, Darveau S, Huang J (2011) Air stable, photosensitive, phase pure iron pyrite nanocrystal thin films for photovoltaic application. Nano Lett. doi:10.1021/nl202902z

32.

Puthussery J, Seefeld S, Berry N, Gibbs M, Law M (2011) Colloidal iron pyrite (FeS₂) nanocrystal inks for thin-film photovoltaics. J Am Chem Soc 133(4):716–719. doi:10.1021/ja1096368 CrossRef

33.

Steinhagen C, Harvey TB, Stolle CJ, Harris J, Korgel BA (2012) Pyrite nanocrystal solar cells: promising, or fool’s gold? J Phys Chem Lett 3:2352–2356. doi:10.1021/jz301023c CrossRef

34.

Kar S, Chaudhuri S (2005) Synthesis of highly oriented iron sulfide nanowires through solvothermal process. Mater Lett 59(2–3):289–292. doi:10.1016/j.matlet.2004.10.005 CrossRef

35.

Wan D, Wang Y, Zhou Z, Yang G, Wang B, Wei L (2005) Fabrication of the ordered FeS₂ (pyrite) nanowire arrays in anodic aluminum oxide. Mater Sci Eng B 122(2):156–159. doi:10.1016/j.mseb.2005.05.003 CrossRef

36.

Cabán-Acevedo M, Faber MS, Tan Y, Hamers RJ, Jin S (2012) Synthesis and properties of semiconducting iron pyrite (FeS₂) nanowires. Nano Lett 12(4):1977–1982. doi:10.1021/nl2045364 CrossRef

37.

Hulteen JC, Martin CR (1997) A general template-based method for the preparation of nanomaterials. J Mater Chem 7(7):1075–1087. doi:10.1039/a700027h CrossRef

38.

Limmer SJ, Seraji S, Wu Y, Chou TP, Nguyen C, Cao GZ (2002) Template-based growth of various oxide nanorods by sol–gel electrophoresis. Adv Funct Mater 12(1):59–64. doi:10.1002/1616-3028(20020101)12:1<59:AID-ADFM59>3.0.CO;2-B CrossRef

39.

Vogt H, Chattopadhyay T, Stolz HJ (1983) Complete first-order Raman spectra of the pyrite structure compounds FeS₂, MnS₂ and SiP₂. J Phys Chem Solids 44(9):869–873. doi:10.1016/0022-3697(83)90124-5 CrossRef

40.

Kleppe AK, Jephcoat AP (2004) High-pressure Raman spectroscopic studies of FeS₂ pyrite. Mineral Mag 68(3):433–441. doi:10.1180/0026461046830196 CrossRef

41.

Lutz HD, Müller B (1991) Lattice vibration spectra. LXVIII. Single-crystal Raman spectra of marcasite-type iron chalcogenides and pnictides, FeX₂ (X = S, Se, Te; P, As, Sb). Phys Chem Miner 18(4):265–268. doi:10.1007/bf00202579 CrossRef

42.

Smestad G, Da Silva A, Tributsch H, Fiechter S, Kunst M, Meziani N, Birkholz M (1989) Formation of semiconducting iron pyrite by spray pyrolysis. Sol Energy Mater 18(5):299–313. doi:10.1016/0165-1633(89)90044-0 CrossRef

43.

Ferrer IJ, Nevskaia DM, de las Heras C, Sánchez C (1990) About the band gap nature of FeS₂ as determined from optical and photoelectrochemical measurements. Solid State Commun 74(9):913–916. doi:10.1016/0038-1098(90)90455-k CrossRef

Titel: Template-directed synthesis of ordered iron pyrite (FeS2) nanowires and nanotubes arrays
verfasst von: Yi Li
Zili Han
Liangxing Jiang
Zhenghua Su
Fangyang Liu
Yanqing Lai
Yexiang Liu
Publikationsdatum: 01.10.2014
Verlag: Springer US
Erschienen in: Journal of Sol-Gel Science and Technology / Ausgabe 1/2014
Print ISSN: 0928-0707
Elektronische ISSN: 1573-4846
DOI: https://doi.org/10.1007/s10971-014-3425-2

Premium Partner

Marktübersichten

Die im Laufe eines Jahres in der „adhäsion“ veröffentlichten Marktübersichten helfen Anwendern verschiedenster Branchen, sich einen gezielten Überblick über Lieferantenangebote zu verschaffen.

Zur Marktübersicht

Springer Professional

Abstract

Bitte loggen Sie sich ein, um Zugang zu Ihrer Lizenz zu erhalten.

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Technik"

Springer Professional "Wirtschaft+Technik"

Weitere Artikel der Ausgabe 1/2014

Rice husk ash nanosilica to inhibit human breast cancer cell line (3T3)

A novel pH-responsive controlled release system based on mesoporous silica coated with hydroxyapatite

Effects of Cu addition on the structure and magnetic properties of L10-FePt nanoparticles prepared by sol–gel method

Investigation of visible light active Ag sensitized mixed phase TiO2 photocatalyst for solar energy application

Photovoltaic properties of Pt/BiFeO3 thin film/fluorine-doped tin oxide capacitor

Preparation, characterization, catalytic performance and antibacterial activity of Ag photodeposited on monodisperse ZnO submicron spheres

Premium Partner

Marktübersichten