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2016 | OriginalPaper | Buchkapitel

The Carbon Dioxide Molecule and the Effects of Its Interaction with Electrophiles and Nucleophiles

verfasst von : Michele Aresta, Antonella Angelini

Erschienen in: Carbon Dioxide and Organometallics

Verlag: Springer International Publishing

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Abstract

This chapter discusses the CO₂ molecule in its ground and excited states, correlating the energy to the molecular geometry. The effect of adding or taking out an electron is illustrated, opening the way to the coordination of CO₂ to metal centers. Several modes of bonding of CO₂ are presented and the IR and multinuclear NMR spectroscopic data of transition metal complexes or adducts with Lewis acids and bases are commented. The reactivity of the coordinated heterocumulene is presented through several examples. The use of IR and NMR techniques for determining the molecular behavior of transition metal complexes in solution is exemplified.

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Titel: The Carbon Dioxide Molecule and the Effects of Its Interaction with Electrophiles and Nucleophiles
verfasst von: Michele Aresta
Antonella Angelini
Verlag: Springer International Publishing
Buch: Carbon Dioxide and Organometallics
Print ISBN: 978-3-319-22077-2

Electronic ISBN: 978-3-319-22078-9

Copyright-Jahr: 2016
DOI: https://doi.org/10.1007/3418_2015_93

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