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Erschienen in:
1991 | OriginalPaper | Buchkapitel
The Equivalent Bond Orbital Model and the Interpretation of PE Spectra
verfasst von : Evi Honegger, Edgar Heilbronner
Erschienen in: Theoretical Models of Chemical Bonding
Verlag: Springer Berlin Heidelberg
Enthalten in: Professional Book Archive
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The low-energy part of the He(Iα) or He(IIα) PE spectrum of a hypothetical molecule M (shown in Fig. 1) consists of four bands, ① to ④, which — for simplicity — we assume not to overlap. The bands ① and ② exhibit resolved vibrational fine structure, whereas the fine structure of ③ and ④ cannot be resolved because of line broadening, of random noise and/or the resolution of the recording, the latter being typically of the order of 20 meV.