2007 | OriginalPaper | Buchkapitel
The Self-cooling Effect
Erschienen in: Thermal Decomposition of Solids and Melts
Verlag: Springer Netherlands
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The role of self-cooling in endothermic decompositions has been discussed in many works. However, only in a few studies [1–3] performed during the period 1930–1950 has this effect been taken into account in measurements of dehydration rates and of the corresponding Arrhenius parameters (
E
and
A
). Most of the other researchers assume (often implicitly) that the magnitude of self-cooling is insignificant and may be neglected. Much greater attention has been given to the problem of self-heating during the processes of pyrolysis, carbon gasification, and decomposition of high-energy materials.