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Erschienen in:
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2020 | OriginalPaper | Buchkapitel

5. The Template-Directed Synthesis of a Fully Conjugated 14-Porphyrin Nanoball

verfasst von : Jonathan Cremers

Erschienen in: Electronic Communication in Heterometallated Porphyrin Oligomers

Verlag: Springer International Publishing

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Abstract

The preparation of conjugated organic systems with strong π-orbital overlap between the molecular components is both challenging and laborious. This chapter describes the template-directed synthesis and characterisation of a π-conjugated 14-porphyrin nanoball. The bicyclic structure consists of a 6- and 10-porphyrin nanoring intersecting at two points. UV-Vis-NIR titrations were performed to investigate the binding behaviour of the templates inside the cavity of the ball. In addition, photoluminescence (PL) upconversion spectroscopy revealed strong coupling between the two rings. By removing the templates, the flexibility in the system increases which results in a decrease in the PL anisotropy. This indicates that excitations may migrate between the two ring components of the nanoball.

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Vorheriges Kapitel Synthesis of Ortho, Meta and Para Bis-Copper Porphyrin Nanorings
Nächstes Kapitel The Synthesis of a D4h Symmetric Porphyrin Nanoball Using Selective Demetallation
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Metadaten
Titel
The Template-Directed Synthesis of a Fully Conjugated 14-Porphyrin Nanoball
verfasst von
Jonathan Cremers
Copyright-Jahr
2020
Buch
Electronic Communication in Heterometallated Porphyrin Oligomers

Print ISBN: 978-3-030-39100-3

Electronic ISBN: 978-3-030-39101-0

Copyright-Jahr: 2020

DOI
https://doi.org/10.1007/978-3-030-39101-0_5

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