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2021 | OriginalPaper | Buchkapitel

2. Thermodynamics, Kinetics and Desorption Studies of Heavy Metal Ions by Grafted Cross-Linked Chitosan Beads Composites

verfasst von : Ephraim Igberase, Peter Ogbemudia Osifo, Tumisang Seodigeng, Ikenna Emeji

Erschienen in: Enhanced Chitosan Material for Water Treatment

Verlag: Springer International Publishing

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Abstract

Functionalized grafted cross-linked chitosan bead (G/CR-CS), prepared from pure chitosan for the removal of scavenging metal ions from aqueous solutions, has been studied. The modified material was then characterized using FTIR, SEM, TGA, BET and XRD to assert successful modification. Parameters such as effect of contact time, pH and temperature were investigated to determine their physicochemical properties for the maximum removal of metal ions using batch applications. The results indicated that adsorption performance of the modified chitosan beads can be modelled efficiently using Langmuir isotherm and pseudo-second-order kinetic. Also, calculated thermodynamic parameters (ΔG⁰, ΔH⁰ and ΔS⁰) indicated that the adsorption of metal ions onto the grafted cross-linked chitosan is spontaneous and endothermic in nature.

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Titel: Thermodynamics, Kinetics and Desorption Studies of Heavy Metal Ions by Grafted Cross-Linked Chitosan Beads Composites
verfasst von: Ephraim Igberase
Peter Ogbemudia Osifo
Tumisang Seodigeng
Ikenna Emeji
Verlag: Springer International Publishing
Buch: Enhanced Chitosan Material for Water Treatment
Print ISBN: 978-3-030-71721-6

Electronic ISBN: 978-3-030-71722-3

Copyright-Jahr: 2021
DOI: https://doi.org/10.1007/978-3-030-71722-3_2

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