Skip to main content
Fachgebiete
Automobil + Motoren Bauwesen + Immobilien Business IT + Informatik Elektrotechnik + Elektronik Energie + Nachhaltigkeit Finance + Banking Management + Führung Marketing + Vertrieb Maschinenbau + Werkstoffe Versicherung + Risiko
DE
EN
Bücher
Zeitschriften
Themenseiten
Organisationspsychologie Projektmanagement Marketing Smart Manufacturing
Weitere Formate
Podcasts Webinare Technik Webinare Wirtschaft Kongresse Veranstaltungskalender Awards
Jetzt Einzelzugang starten
Zugang für Unternehmen
Referenzkunden
SLX-Digitalkonferenz: Zukunftswerkstatt 2024

Mehr Umsatz mit Top-Kontakten

Am 7. Mai erfahren Sie, wie Vertriebsteams Leadgenerierung, Leadnurturing und Leadstrategien effizient steuern können.
Erweiterte Suche
Anmelden
nach oben
Journal of Materials Science
Erschienen in: Journal of Materials Science 13/2017

28.03.2017 | Energy materials

TiO2 crystalline structure and electrochemical performance in two-ply yarn CNT/TiO2 asymmetric supercapacitors

verfasst von: Ting Li, Yunlong Wu, Qiufan Wang, Daohong Zhang, Aiqing Zhang, Menghe Miao

Erschienen in: Journal of Materials Science | Ausgabe 13/2017

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config
loading …

Abstract

Solid-state flexible energy storage devices play a crucial role in the development of wearable electronic textiles. In this study, we fabricated flexible asymmetric two-ply yarn supercapacitors from carbon nanotube yarns and surface-oxidized titanium filament. The crystalline structure of the TiO2 surface layer can be adjusted to amorphous, anatase and rutile states by altering the annealing temperature. The titanium filament with a rutile TiO2 surface layer produced at high annealing temperature showed far superior electrochemical performance over the filaments with amorphous and anatase TiO2 surface layers. The as-prepared asymmetric two-ply yarn supercapacitors in aqueous gel electrolyte can achieve a durable operating voltage up to 1.4 V, with a maximum energy density of 11.7 Wh kg−1 and a maximum power density of 2060 W kg−1. The asymmetric two-ply yarn supercapacitors exhibited excellent flexibility and cycling stability over 1200 cycles at straight, twisted and bent states.
Vorheriger Artikel Rational design of graphene @ nitrogen and phosphorous dual-doped porous carbon sandwich-type layer for advanced lithium–sulfur batteries
Nächster Artikel Design and synthesis of H-TiO2/MnO2 core–shell nanotube arrays with high capacitance and cycling stability for supercapacitors

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Jetzt informieren
Literatur
1.
Rogers JA, Huang Y (2009) A curvy, stretchy future for electronics. Proc Natl Acad Sci 106:10875–10876CrossRef
2.
Nyholm L, Nystrom G, Mihranyan A, Stromme M (2011) Toward flexible polymer and paper-based energy storage devices. Adv Mater 23:3751–3769
3.
Hu L, Wu H, La Mantia F, Yang Y, Cui Y (2010) Thin, flexible secondary Li-ion paper batteries. ACS Nano 4:5843–5848CrossRef
4.
El-Kady MF, Kaner RB (2013) Scalable fabrication of high-power graphene micro-supercapacitors for flexible and on-chip energy storage. Nat Commun 4:1475CrossRef
5.
Simon P, Gogotsi Y (2008) Materials for electrochemical capacitors. Nat Mater 7:845–854CrossRef
6.
Miller JR, Simon P (2008) Materials science. Electrochemical capacitors for energy management. Science 321:651–652CrossRef
7.
Simon P, Gogotsi Y, Dunn B (2014) Materials science. Where do batteries end and supercapacitors begin? Science 343:1210–1211CrossRef
8.
Lu X, Yu M, Wang G, Tong Y, Li Y (2014) Flexible solid-state supercapacitors: design, fabrication and applications. Energy Environ Sci 7:2160–2181CrossRef
9.
Le VT, Kim H, Ghosh A, Kim J, Chang J, Vu QA, Pham DT, Lee JH, Kim SW, Lee YH (2013) Coaxial fiber supercapacitor using all-carbon material electrodes. ACS Nano 7:5940–5947CrossRef
10.
Li Y, Sheng K, Yuan W, Shi G (2012) A high-performance flexible fibre-shaped electrochemical capacitor based on electrochemically reduced graphene oxide. Chem Commun 49:291–293CrossRef
11.
Lee JA, Shin MK, Kim SH, Cho HU, Spinks GM, Wallace GG, Lima MD, Lepro X, Kozlov ME, Baughman RH, Kim SJ (2013) Ultrafast charge and discharge biscrolled yarn supercapacitors for textiles and microdevices. Nat Commun 4:1970
12.
Ren J, Bai W, Guan G, Zhang Y, Peng H (2013) Flexible and weaveable capacitor wire based on a carbon nanocomposite fiber. Adv Mater 25:5965–5970CrossRef
13.
Yang Z, Deng J, Chen X, Ren J, Peng H (2013) A highly stretchable, fiber-shaped supercapacitor. Angew Chem Int Edit 52:13453–13457CrossRef
14.
Wang K, Meng Q, Zhang Y, Wei Z, Miao M (2013) High-performance two-ply yarn supercapacitors based on carbon nanotubes and polyaniline nanowire arrays. Adv Mater 25:1494–1498CrossRef
15.
Zhang D, Miao M, Niu H, Wei Z (2014) Core-spun carbon nanotube yarn supercapacitors for wearable electronic textiles. ACS Nano 8:4571–4579CrossRef
16.
Zhang D, Wu Y, Li T, Huang Y, Zhang A, Miao M (2015) High performance carbon nanotube yarn supercapacitors with a surface-oxidized copper current collector. ACS Appl Mater Interfaces 7:25835–25842CrossRef
17.
Wang Q, Wu Y, Li T, Zhang D, Miao M, Zhang A (2016) High performance two-ply carbon nanocomposite yarn supercapacitors enhanced with a platinum filament and in situ polymerized polyaniline nanowires. J Mater Chem A 4:3828–3834CrossRef
18.
Su F, Lv X, Miao M (2015) High-performance two-ply yarn supercapacitors based on carbon nanotube yarns dotted with Co3O4 and NiO nanoparticles. Small 11:854–861CrossRef
19.
Su F, Miao M (2014) Flexible, high performance two-ply yarn supercapacitors based on irradiated carbon nanotube yarn and PEDOT/PSS. Electrochim Acta 127:433–438CrossRef
20.
Wang K, Wu H, Meng Y, Wei Z (2014) Conducting polymer nanowire arrays for high performance supercapacitors. Small 10:14–31CrossRef
21.
Su F, Miao M (2014) Asymmetric carbon nanotube-MnO2 two-ply yarn supercapacitors for wearable electronics. Nanotechnology 25:13
22.
Su F, Miao M, Niu H, Wei Z (2014) Gamma-irradiated carbon nanotube yarn as substrate for high-performance fiber supercapacitors. ACS Appl Mater Interfaces 6:2553–2560CrossRef
23.
Su F, Lyu X, Liu C, Miao M (2016) Flexible two-ply yarn supercapacitors based on carbon nanotube/stainless steel core spun yarns decorated with Co3O4 nanoparticles and MnOx composites. Electrochim Acta 215:535–542CrossRef
24.
Choi C, Sim HJ, Spinks GM, Lepró X, Baughman RH, Kim SJ (2016) Elastomeric and dynamic MnO2/CNT core–shell structure coiled yarn supercapacitor. Adv Energy Mater 6:1502119CrossRef
25.
Sun J, Huang Y, Fu C, Wang Z, Huang Y, Zhu M, Zhi C, Hu H (2016) High-performance stretchable yarn supercapacitor based on PPy@ CNTs@urethane elastic fiber core spun yarn. Nano Energy 27:230–237CrossRef
26.
Chuang C, Huang C, Teng H, Ting J (2012) Hydrothermally synthesized RuO2/Carbon nanofibers composites for use in high-rate supercapacitor electrodes. Compos Sci Technol 72:1524–1529CrossRef
27.
Fang H, Liu M, Wang D, Ren X, Sun X (2013) Fabrication and supercapacitive properties of a thick electrode of carbon nanotube-RuO2 core-shell hybrid material with a high RuO2 loading. Nano Energy 2:1232–1241CrossRef
28.
Reddy ALM, Shaijumon MM, Gowda SR, Ajayan PM (2009) Multisegmented Au-MnO2/carbon nanotube hybrid coaxial arrays for high-power supercapacitor applications. J Phys Chem C 117:658–663
29.
Li P, Wei J, Wang K, Zhu H, Yang Y, Shi E, Shen Q, Shang Y, Wu S, Yuan Q (2014) Core-double-shell, carbon nanotube@Polypyrrole@MnO2 sponge as freestanding, compressible supercapacitor electrode. ACS Appl Mater Interfaces 6:5228–5234CrossRef
30.
Tang Q, Chen M, Yang C, Wang W, Bao H, Wang G (2015) Enhancing the energy density of asymmetric stretchable supercapacitor based on wrinkled CNT@MnO2 cathode and CNT@Polypyrrole anode. ACS Appl Mater Interfaces 7:15303–15313CrossRef
31.
Bai Y, Du M, Chang J, Sun J, Gao L (2014) Supercapacitors with high capacitance based on reduced graphene oxide/carbon nanotubes/NiO composite electrodes. J Mater Chem A 2:3834–3840CrossRef
32.
Yi H, Wang H, Jing Y, Peng T, Wang X (2015) Asymmetric supercapacitors based on carbon nanotubes@NiO ultrathin nanosheets core-shell composites and MOF-derived porous carbon polyhedrons with super-long cycle life. J Power Source 285:281–290CrossRef
33.
Wang Q, Wen Z, Li J (2006) A hybrid supercapacitor fabricated with a carbon nanotube cathode and a TiO2-B nanowire anode. Adv Funct Mater 16:2141–2146CrossRef
34.
Su L, Zhang X, Yuan C, Bo G (2008) Symmetric self-hybrid supercapacitor consisting of multiwall carbon nanotubes and Co–Al layered double hydroxides. J Electrochem Soc 155:A110–A114CrossRef
35.
Lu X, Wang G, Zhai T, Yu M, Gan J, Tong Y, Li Y (2012) Hydrogenated TiO2 nanotube arrays for supercapacitors. Nano Lett 12:1690–1696CrossRef
36.
Cao X, Xing X, Zhang N, Gao H, Zhang M, Shang Y, Zhang X (2015) Quantitative investigation on the effect of hydrogenation on the performance of MnO2/H-TiO2 composite electrodes for supercapacitors. J Mater Chem A 3:3785–3793CrossRef
37.
Huynh CP, Hawkins SC (2010) Understanding the synthesis of directly spinnable carbon nanotube forests. Carbon 48:1105–1115CrossRef
38.
Miao M, McDonnell J, Vuckovic L, Hawkins SC (2010) Poisson’s ratio and porosity of carbon nanotube dry-spun yarns. Carbon 48:2802–2811CrossRef
39.
Chen X, Liu L, Yu P, Mao S (2011) Increasing solar absorption for photocatalysis with black hydrogenated titanium dioxide nanocrystals. Science 331:746–750CrossRef
40.
Pei Z, Weng S, Liu P (2016) Enhanced photocatalytic activity by bulk trapping and spatial separation of charge carriers: a case study of defect and facet mediated TiO2. Appl Catal B Env 180:463–470CrossRef
41.
Pei Z, Zhu M, Huang Y, Huang Y, Xue Q, Geng H, Zhi C (2016) Dramatically improved energy conversion and storage efficiencies by simultaneously enhancing charge transfer and creating active sites in MnOx/TiO2 nanotube composite electrodes. Nano Energy 20:254–263CrossRef
42.
Chen X, Qiu L, Ren J, Guan G, Lin H, Zhang Z, Chen P, Wang Y, Peng H (2013) Novel electric double-layer capacitor with a coaxial fiber structure. Adv Mater 25:6436–6441CrossRef
43.
Yang Z, Deng J, Chen X, Ren J, Peng H (2013) A highly stretchable, fiber-shaped supercapacitor. Angew Chem Int Edit 52:13453–13457CrossRef
Metadaten
Titel
TiO2 crystalline structure and electrochemical performance in two-ply yarn CNT/TiO2 asymmetric supercapacitors
verfasst von
Ting Li
Yunlong Wu
Qiufan Wang
Daohong Zhang
Aiqing Zhang
Menghe Miao
Publikationsdatum
28.03.2017
Verlag
Springer US
Erschienen in
Journal of Materials Science / Ausgabe 13/2017
Print ISSN: 0022-2461
Elektronische ISSN: 1573-4803
DOI
https://doi.org/10.1007/s10853-017-1033-6

Weitere Artikel der Ausgabe 13/2017

Journal of Materials Science 13/2017 Zur Ausgabe

Energy materials

MOF-derived carbon coating on self-supported ZnCo2O4–ZnO nanorod arrays as high-performance anode for lithium-ion batteries

Original Paper

A novel hierarchical graphene/polyaniline hollow microsphere as electrode material for supercapacitor applications

Energy materials

Electrocatalytic applications of platinum-decorated TiO2 nanotubes prepared by a fully wet-chemical synthesis

Original Paper

Viscosity and liquidus temperature of quaternary glasses close to an eutectic composition in the CaO–MgO–Al2O3–SiO2 system

Energy materials

Bamboo-like, oxygen-doped carbon tubes with hierarchical pore structure derived from polymer tubes for supercapacitor applications

Metals

Effects of martensitic transformability and dynamic strain age hardenability on plasticity in metastable austenitic steels containing carbon

Premium Partner

    Marktübersichten

    Die im Laufe eines Jahres in der „adhäsion“ veröffentlichten Marktübersichten helfen Anwendern verschiedenster Branchen, sich einen gezielten Überblick über Lieferantenangebote zu verschaffen. 

    Zur Marktübersicht
    Bildnachweise