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Journal of Coatings Technology and Research
Erschienen in: Journal of Coatings Technology and Research 2/2015

01.03.2015

Tungstate and vanadate-doped polypyrrole/aluminum flake composite coatings for the corrosion protection of aluminum 2024-T3

verfasst von: Niteen Jadhav, Mark B. Jensen, Victoria Gelling

Erschienen in: Journal of Coatings Technology and Research | Ausgabe 2/2015

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Abstract

Polypyrrole (PPy) doped with either tungstate or vanadate as counter anions was synthesized by chemical oxidative polymerization on the surface of aluminum (Al) flakes. This resulted in the deposition of PPy on the surface of the Al flakes leading to the formation of doped PPy/Al flake composite pigments. These composite pigments were characterized by Fourier transform infrared spectroscopy, scanning electron microscopy, energy dispersive spectroscopy, conductive-atomic force microscopy, four-point probe conductivity, and X-ray photoelectron spectroscopy. Furthermore, these composites were incorporated in an epoxy-amide binder system in order to formulate a primer for an aluminum 2024-T3 substrate. The coatings were exposed to the Prohesion test conditions and corrosion resistance properties were monitored by electrochemical impedance spectroscopy, DC polarization, galvanic coupling, and scanning electrochemical microscopy measurements. It was found that the doped PPy/Al flake coatings provided sacrificial protection to the underlying aluminum 2024-T3 substrate. Additionally, the release of dopants from PPy backbone resulted in the passivation in the defect areas improving the corrosion protection ability.
Vorheriger Artikel Effect of addition of cellulose nanocrystals to wood coatings on color changes and surface roughness due to accelerated weathering
Nächster Artikel A study on the corrosion inhibition properties of silane-modified Fe2O3 nanoparticle on mild steel and its effect on the anticorrosion properties of the polyurethane coating

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Metadaten
Titel
Tungstate and vanadate-doped polypyrrole/aluminum flake composite coatings for the corrosion protection of aluminum 2024-T3
verfasst von
Niteen Jadhav
Mark B. Jensen
Victoria Gelling
Publikationsdatum
01.03.2015
Verlag
Springer US
Erschienen in
Journal of Coatings Technology and Research / Ausgabe 2/2015
Print ISSN: 1547-0091
Elektronische ISSN: 1935-3804
DOI
https://doi.org/10.1007/s11998-014-9633-4

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