Skip to main content

2020 | OriginalPaper | Buchkapitel

7. Utilization of Glycerol from Biodiesel Industry By-product into Several Higher Value Products

verfasst von : Zahrul Mufrodi, Erna Astuti, Arief Budiman, Supranto, Sutijan, Agus Prasetya, Rochmadi

Erschienen in: Valorisation of Agro-industrial Residues – Volume II: Non-Biological Approaches

Verlag: Springer International Publishing

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config
loading …

Abstract

Since the 1980s the energy demand has been increasing steadily, including diesel fuel. On the other hand the oil reserve in the world was increasingly limited because of being the product that could not be renewed. Therefore, effort was carried out to look for the alternative fuel that could be renewed and environment friendly. The alternative energy from new renewable energy is a solution to reduce the dependence of fossil energy. The renewable energy consists of the energy of water, wind, biomass or biofuels, solar energy, ocean energy, and geothermal energy. One of the biofuels is biodiesel. Biodiesel is diesel fuel which is made from vegetable oil by transesterification. The abundance of glycerol will result in declining sales value of glycerol as a by-product of the biodiesel plant. It should be anticipated to improve the usefulness of glycerol both in terms of quantity and its variants. The increasing usefulness of glycerol will result in the higher price of glycerol that will increase the profitability of biodiesel plants. Among the usefulness of glycerol investigated is as an ingredient in pharmaceutical products, polyether, emulsifiers, fabric softener, stabilizers, preservatives in bread, ice cream, cosmetic ingredients, a propellant binder, and others. This chapter explains the utilization of glycerol to produce triacetin as bioadditive and polyglycidyl nitrate (PGN) as a propellant binder. Triacetin is used to increase octane number of fuel and improve the biodiesel’s performance. Propellant binder consists of two kinds of non-energetic polymers and polymer energetic. The most energetic polymer is PGN. The focus of this chapter is to determine each step of reactions, operating conditions of process and the results of products.

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Literatur
Zurück zum Zitat Astuti E, Supranto, Rochmadi, Prasetya A (2014a) Determination of the temperature effect on glycerol nitration processes using the Hysys predictions and the laboratory experiment. Indo J Chem 14(1):57–62CrossRef Astuti E, Supranto, Rochmadi, Prasetya A (2014a) Determination of the temperature effect on glycerol nitration processes using the Hysys predictions and the laboratory experiment. Indo J Chem 14(1):57–62CrossRef
Zurück zum Zitat Astuti E, Supranto, Rochmadi, Prasetya A, Ström K, Andersson B (2014b) Kinetic modeling of nitration of glycerol. Mod Appl Sci 8(2):78–86CrossRef Astuti E, Supranto, Rochmadi, Prasetya A, Ström K, Andersson B (2014b) Kinetic modeling of nitration of glycerol. Mod Appl Sci 8(2):78–86CrossRef
Zurück zum Zitat Astuti E, Supranto, Rochmadi, Prasetya A (2015) A thermodynamic study of parameters that affect the nitration of glycerol with nitric acid. Int J Chem Mol Nucl Mater Metall Eng 9(8):947–950 Astuti E, Supranto, Rochmadi, Prasetya A (2015) A thermodynamic study of parameters that affect the nitration of glycerol with nitric acid. Int J Chem Mol Nucl Mater Metall Eng 9(8):947–950
Zurück zum Zitat Astuti E, Supranto, Rochmadi, Prasetya A (2016a) Optimum operating conditions of glycerol nitration to produce 1,3-dinitroglycerin. ARPN J Eng Appl Sci 11(80):5203–5208 Astuti E, Supranto, Rochmadi, Prasetya A (2016a) Optimum operating conditions of glycerol nitration to produce 1,3-dinitroglycerin. ARPN J Eng Appl Sci 11(80):5203–5208
Zurück zum Zitat Ayoub M, Abdullah AZ (2012) Critical review on the current scenario and significance of crude glycerol resulting from biodiesel industry towards more sustainable renewable energy industry. Renew Sust Energ Rev 16:2671–2686CrossRef Ayoub M, Abdullah AZ (2012) Critical review on the current scenario and significance of crude glycerol resulting from biodiesel industry towards more sustainable renewable energy industry. Renew Sust Energ Rev 16:2671–2686CrossRef
Zurück zum Zitat Balaraju M, Nikhitha P, Jagadeeswaraiah K, Srilatha K, Prasad PSS, Lingaiah N (2010) Acetylation of glycerol to synthesize bioadditives over niobic acid supported tungstophosphoric acid catalysts. Fuel Process Technol 91:249–253CrossRef Balaraju M, Nikhitha P, Jagadeeswaraiah K, Srilatha K, Prasad PSS, Lingaiah N (2010) Acetylation of glycerol to synthesize bioadditives over niobic acid supported tungstophosphoric acid catalysts. Fuel Process Technol 91:249–253CrossRef
Zurück zum Zitat Bonet J, Costa J, Sire R, Reneaume JM, Plesu EA, Plesu V, Bozga G (2009) Revalorization of glycerol: comestible oil from biodiesel synthesis. Food Bioprod Process 87:171–178CrossRef Bonet J, Costa J, Sire R, Reneaume JM, Plesu EA, Plesu V, Bozga G (2009) Revalorization of glycerol: comestible oil from biodiesel synthesis. Food Bioprod Process 87:171–178CrossRef
Zurück zum Zitat Bremus N, Dieckelmann G, Jeromin L, Rupilius W, Schutt H (1983) Process for continuous production of triacetin. US Patent 4.381.407 Bremus N, Dieckelmann G, Jeromin L, Rupilius W, Schutt H (1983) Process for continuous production of triacetin. US Patent 4.381.407
Zurück zum Zitat Colclough ME, Desai H, Millar RW, Paul NC, Stewart MJ, Golding P (1993) Energetic polymers as binders in composite propellants and explosives. Polym Adv Technol 5:554–560CrossRef Colclough ME, Desai H, Millar RW, Paul NC, Stewart MJ, Golding P (1993) Energetic polymers as binders in composite propellants and explosives. Polym Adv Technol 5:554–560CrossRef
Zurück zum Zitat Coombes RG, Moodie RB, Schofield K (1968) Electrophilic aromatic substitution. Part I. The nitration of some reactive aromatic compounds in concentrated sulphuric and perchloric acids. J Chem Soc B:800–804 Coombes RG, Moodie RB, Schofield K (1968) Electrophilic aromatic substitution. Part I. The nitration of some reactive aromatic compounds in concentrated sulphuric and perchloric acids. J Chem Soc B:800–804
Zurück zum Zitat Danov SM, Kolesnikov VA, Esipovich AL (2010) Kinetics of benzene nitration by nitric acid. Russ J Appl Chem 83(1):168–170CrossRef Danov SM, Kolesnikov VA, Esipovich AL (2010) Kinetics of benzene nitration by nitric acid. Russ J Appl Chem 83(1):168–170CrossRef
Zurück zum Zitat Dasari MA et al (2005) Low-pressure hydrogenolysis of glycerol to propylene glycol. Appl Catal A Gen 281:225–231CrossRef Dasari MA et al (2005) Low-pressure hydrogenolysis of glycerol to propylene glycol. Appl Catal A Gen 281:225–231CrossRef
Zurück zum Zitat Delgado J (2002) SP Patent 2201.894.2002 Delgado J (2002) SP Patent 2201.894.2002
Zurück zum Zitat Desai HJ, Cunliffe AV, Lewis T, Millar RW, Paul NC, Stewart MJ, Amass AJ (1996) Synthesis of narrow molecular weight á,ù-hydroxy telechelic poly(glycidyl nitrate) and estimation of theoretical heat of explosion. Polymer 37(15):3471–3476CrossRef Desai HJ, Cunliffe AV, Lewis T, Millar RW, Paul NC, Stewart MJ, Amass AJ (1996) Synthesis of narrow molecular weight á,ù-hydroxy telechelic poly(glycidyl nitrate) and estimation of theoretical heat of explosion. Polymer 37(15):3471–3476CrossRef
Zurück zum Zitat Fogler HS (2006) Elements of chemical reaction engineering, 4th edn. Prentice Hall Professional Technical Reference, Upper Saddle River, NJ, pp 81–92 Fogler HS (2006) Elements of chemical reaction engineering, 4th edn. Prentice Hall Professional Technical Reference, Upper Saddle River, NJ, pp 81–92
Zurück zum Zitat Fukumura T, Toda T, Seki Y, Kubo M, Kitakawa NS, Yonemoto T (2009) Catalytic synthesis of glycerol monoacetate using a continuous expanded bed column reactor packed with cation-exchange resin. Ind Eng Chem Res 48:1816–1823CrossRef Fukumura T, Toda T, Seki Y, Kubo M, Kitakawa NS, Yonemoto T (2009) Catalytic synthesis of glycerol monoacetate using a continuous expanded bed column reactor packed with cation-exchange resin. Ind Eng Chem Res 48:1816–1823CrossRef
Zurück zum Zitat Galan MI, Bonet J, Sire R, Reneaume JM, Plesu AE (2009) From residual to use oil: revalorization of glycerine from the biodiesel synthesis. Bioresour Technol 100:3775–3778CrossRefPubMed Galan MI, Bonet J, Sire R, Reneaume JM, Plesu AE (2009) From residual to use oil: revalorization of glycerine from the biodiesel synthesis. Bioresour Technol 100:3775–3778CrossRefPubMed
Zurück zum Zitat Gelosa D, Ramaioli M, Valente G, Morbidelli M (2003) Chromatographic reactors: esterification of glycerol with acetic acid using acidic polymeric resins. Ind Eng Chem Res 42:6536–6544CrossRef Gelosa D, Ramaioli M, Valente G, Morbidelli M (2003) Chromatographic reactors: esterification of glycerol with acetic acid using acidic polymeric resins. Ind Eng Chem Res 42:6536–6544CrossRef
Zurück zum Zitat Gonsalves VLC, Pinto BP, Silva JC, Mota CJA (2008) Acetylation of glycerol catalyzed by different solid acid. Catal Today 133–135:673–677CrossRef Gonsalves VLC, Pinto BP, Silva JC, Mota CJA (2008) Acetylation of glycerol catalyzed by different solid acid. Catal Today 133–135:673–677CrossRef
Zurück zum Zitat Haryanto R, Budiman A (2005) Kinetika Reaksi Poliesterifikasi Gliserol-Asam Adipat. Teknisains 18(1) Haryanto R, Budiman A (2005) Kinetika Reaksi Poliesterifikasi Gliserol-Asam Adipat. Teknisains 18(1)
Zurück zum Zitat Highsmith TK, Johnston HE (2005) Continuous process and system for production of glycidyl nitrate from glycerin, nitric acid and caustic and conversion of glycidyl nitrate to poly(glycidyl nitrate). US Patent 6.870.061 Highsmith TK, Johnston HE (2005) Continuous process and system for production of glycidyl nitrate from glycerin, nitric acid and caustic and conversion of glycidyl nitrate to poly(glycidyl nitrate). US Patent 6.870.061
Zurück zum Zitat Highsmith TK, Sanderson AJ, Cannizzo LF, Hajik RM (2001) Polymerization of poly(glycidyl nitrate) from high purity glycidyl nitrate synthesized from glycerol. WO/2001/029111 Highsmith TK, Sanderson AJ, Cannizzo LF, Hajik RM (2001) Polymerization of poly(glycidyl nitrate) from high purity glycidyl nitrate synthesized from glycerol. WO/2001/029111
Zurück zum Zitat Highsmith TK, Sanderson AJ, Cannizzo LF, Hajik RM (2002) Polymerization of poly(glycidyl nitrate) from high purity glycidyl nitrate synthesized from glycerol. US Patent 6.362.311 Highsmith TK, Sanderson AJ, Cannizzo LF, Hajik RM (2002) Polymerization of poly(glycidyl nitrate) from high purity glycidyl nitrate synthesized from glycerol. US Patent 6.362.311
Zurück zum Zitat Hou J, Zhang Q, Shi W, Li Y (1998) New process for synthesis of triacetin. Henan Huagon 15(6):18–19 Hou J, Zhang Q, Shi W, Li Y (1998) New process for synthesis of triacetin. Henan Huagon 15(6):18–19
Zurück zum Zitat Kazakov AI, Rubstov YI, Zabelin LV, Manelis GB, Marchenko GN (1987a) Mechanism and kinetics of the nitration of methanol. Communication 1. Kinetics of the nitration reaction, vol 6. Plenum Publishing Corporation, pp 1137–1141. (translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 6, 1236–1240) Kazakov AI, Rubstov YI, Zabelin LV, Manelis GB, Marchenko GN (1987a) Mechanism and kinetics of the nitration of methanol. Communication 1. Kinetics of the nitration reaction, vol 6. Plenum Publishing Corporation, pp 1137–1141. (translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 6, 1236–1240)
Zurück zum Zitat Kazakov AI, Rubstov YI, Zabelin LV, Manelis GB, Marchenko GN (1987b) Mechanism and kinetics of the nitration of methanol. Communication 2. Mechanics of the nitration reaction, vol 6. Plenum Publishing Corporation, pp 1142–1145. (translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 6, 1241–1244) Kazakov AI, Rubstov YI, Zabelin LV, Manelis GB, Marchenko GN (1987b) Mechanism and kinetics of the nitration of methanol. Communication 2. Mechanics of the nitration reaction, vol 6. Plenum Publishing Corporation, pp 1142–1145. (translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 6, 1241–1244)
Zurück zum Zitat Kazakov AI, Lagodzinskaya GV, Andrienku LP, Yunda NG, Korolev AM, Rubtsov YI, Manelis GB, Eremenko LT (1990a) Study of nitration equilibrium in the glycerin—aqueous nitric acid system. 1. Dependence of the equilibrium constants of nitration reactions on the temperature, acidity of the medium, and structure of the nitrated compound. Russ Chem Bull 39(8):1560–1565CrossRef Kazakov AI, Lagodzinskaya GV, Andrienku LP, Yunda NG, Korolev AM, Rubtsov YI, Manelis GB, Eremenko LT (1990a) Study of nitration equilibrium in the glycerin—aqueous nitric acid system. 1. Dependence of the equilibrium constants of nitration reactions on the temperature, acidity of the medium, and structure of the nitrated compound. Russ Chem Bull 39(8):1560–1565CrossRef
Zurück zum Zitat Kazakov AI, Kirpichev EP, Lagodzinskaya GV, Andrienku LP, Yunda NG, Korolev AM, Rubtsov YI, Manelis GB, Eremenko LT (1990b) Study of nitration equilibrium in the glycerin—aqueous nitric acid system. 2. Change in ΔH and ΔS in the nitration reactions. Russ Chem Bull 39(8):1565–1570CrossRef Kazakov AI, Kirpichev EP, Lagodzinskaya GV, Andrienku LP, Yunda NG, Korolev AM, Rubtsov YI, Manelis GB, Eremenko LT (1990b) Study of nitration equilibrium in the glycerin—aqueous nitric acid system. 2. Change in ΔH and ΔS in the nitration reactions. Russ Chem Bull 39(8):1565–1570CrossRef
Zurück zum Zitat Khayoon MS, Hameed BH (2011) Acetylation of glycerol to biofuel additives over sulfated activated carbon catalyst. Bioresour Technol 102:9229–9235CrossRefPubMed Khayoon MS, Hameed BH (2011) Acetylation of glycerol to biofuel additives over sulfated activated carbon catalyst. Bioresour Technol 102:9229–9235CrossRefPubMed
Zurück zum Zitat Kirk RE, Othmer DF (1980) Encyclopedia of chemical technology, vol 5. Interscience Incyclopedia, New York, pp 781–790 Kirk RE, Othmer DF (1980) Encyclopedia of chemical technology, vol 5. Interscience Incyclopedia, New York, pp 781–790
Zurück zum Zitat Kiss AA, Ignat RM (2012) Enhanced methanol recovery and glycerol separation in biodiesel production – DWC makes it happen. Appl Energy 99:146–153CrossRef Kiss AA, Ignat RM (2012) Enhanced methanol recovery and glycerol separation in biodiesel production – DWC makes it happen. Appl Energy 99:146–153CrossRef
Zurück zum Zitat Kurosaka T, Maruyama H, Naribayashi I, Sasaki Y (2008) Production of 1,3 propanediol by hydrogenolysis of glycerol catalyzed by Pt/WO3/ZrO2. Catal Commun 9:1360–1363CrossRef Kurosaka T, Maruyama H, Naribayashi I, Sasaki Y (2008) Production of 1,3 propanediol by hydrogenolysis of glycerol catalyzed by Pt/WO3/ZrO2. Catal Commun 9:1360–1363CrossRef
Zurück zum Zitat Liao X, Zhu Y, Wang SG, Li Y (2009) Producing triacetylglycerol with glycerol by two steps: esterification and acetylation. J Fuel Process Tech 90:988–993CrossRef Liao X, Zhu Y, Wang SG, Li Y (2009) Producing triacetylglycerol with glycerol by two steps: esterification and acetylation. J Fuel Process Tech 90:988–993CrossRef
Zurück zum Zitat Liu H, Lu Y, Gong S (2007) Study on synthesis of glycerol triacetate using acidic functional ionic liquid as catalyst. Hebei Gongye Keji 24(1):21–23 Liu H, Lu Y, Gong S (2007) Study on synthesis of glycerol triacetate using acidic functional ionic liquid as catalyst. Hebei Gongye Keji 24(1):21–23
Zurück zum Zitat Lu KT, Luo KM, Yeh T, Lin PC (2008) The kinetic parameters and safe operating conditions of nitroglycerine manufacture in the CSTR of biazzi process. Process Saf Environ Prot 86:37–47CrossRef Lu KT, Luo KM, Yeh T, Lin PC (2008) The kinetic parameters and safe operating conditions of nitroglycerine manufacture in the CSTR of biazzi process. Process Saf Environ Prot 86:37–47CrossRef
Zurück zum Zitat Luque R, Budarin V, Clark JH, Macquarrie DJ (2008) Glycerol transformations on polysaccharide derived mesoporous material. Appl Catal B Environ 82:157–162CrossRef Luque R, Budarin V, Clark JH, Macquarrie DJ (2008) Glycerol transformations on polysaccharide derived mesoporous material. Appl Catal B Environ 82:157–162CrossRef
Zurück zum Zitat Marris EP, Ketchie WC, Murayama M, Davis RJ (2007) Glycerol hydrogenolysis on carbon supported PtRu and AuRu bimetallic catalysts. J Catal 251:281–294CrossRef Marris EP, Ketchie WC, Murayama M, Davis RJ (2007) Glycerol hydrogenolysis on carbon supported PtRu and AuRu bimetallic catalysts. J Catal 251:281–294CrossRef
Zurück zum Zitat Melero JA, Grieken RV, Morales G, Paniagua M (2007) Acidic mesoporous silica for the acetylation of glycerol: synthesis of bioadditives to petrol fuel. Energy Fuel 21:1782–1791CrossRef Melero JA, Grieken RV, Morales G, Paniagua M (2007) Acidic mesoporous silica for the acetylation of glycerol: synthesis of bioadditives to petrol fuel. Energy Fuel 21:1782–1791CrossRef
Zurück zum Zitat Millar RW, Paul NC, Golding P (1992) Preparation of epoxy nitrate. US Patent 5.136.062 Millar RW, Paul NC, Golding P (1992) Preparation of epoxy nitrate. US Patent 5.136.062
Zurück zum Zitat Missen RW, Mims CA, Saville BA (1999) Introduction to chemical reaction engineering and kinetics. Wiley, New York, pp 36–145 Missen RW, Mims CA, Saville BA (1999) Introduction to chemical reaction engineering and kinetics. Wiley, New York, pp 36–145
Zurück zum Zitat Moodie RB, Schofield K, Tobin GD (1977) Electrophilic aromatic substitution. Part 17. Products, kinetics, and mechanism of nitration in trifluoroacetic acid. JCS Perkin II:1688–1693 Moodie RB, Schofield K, Tobin GD (1977) Electrophilic aromatic substitution. Part 17. Products, kinetics, and mechanism of nitration in trifluoroacetic acid. JCS Perkin II:1688–1693
Zurück zum Zitat Moodie RB, Schofield K, Tobin GD (1978) Electrophilic aromatic substitution. Part 19. The nitration of some aromatic compounds in perchloric acid. JCS Perkin II 318–323 Moodie RB, Schofield K, Tobin GD (1978) Electrophilic aromatic substitution. Part 19. The nitration of some aromatic compounds in perchloric acid. JCS Perkin II 318–323
Zurück zum Zitat Mufrodi Z, Rochmadi S, Budiman A (2012) Chemical kinetics for synthesis of triacetin from biodiesel byproduct. Int J Chem 4(2):101–107CrossRef Mufrodi Z, Rochmadi S, Budiman A (2012) Chemical kinetics for synthesis of triacetin from biodiesel byproduct. Int J Chem 4(2):101–107CrossRef
Zurück zum Zitat Mufrodi Z, Astuti E, Aktawan A, Purwono S (2018a) The effect of recycle stream on the selectivity and yield of the formation of triacetin from glycerol. IOP Conf Ser Earth Environ Sci 175:1–6CrossRef Mufrodi Z, Astuti E, Aktawan A, Purwono S (2018a) The effect of recycle stream on the selectivity and yield of the formation of triacetin from glycerol. IOP Conf Ser Earth Environ Sci 175:1–6CrossRef
Zurück zum Zitat Mufrodi Z, Budiman A, Purwono S (2018b) Operation conditions in synthesize of bioadditive from glycerol as by-product biodiesel: a review. Energy Procedia 145:434–439CrossRef Mufrodi Z, Budiman A, Purwono S (2018b) Operation conditions in synthesize of bioadditive from glycerol as by-product biodiesel: a review. Energy Procedia 145:434–439CrossRef
Zurück zum Zitat Pagliaro M, Rossi M (2008) The future of glycerol: new usage of a versatile raw material. RSC Publishing, Cambridge Pagliaro M, Rossi M (2008) The future of glycerol: new usage of a versatile raw material. RSC Publishing, Cambridge
Zurück zum Zitat Paraskos AJ, Sanderson AJ, Cannizzo LZ (2004) Polymerization of glycidyl nitrate via catalysis BF3.THF: compatibility with the activated monomer mechanism. 2004 IM/EM Technical Symposium, San Francisco Paraskos AJ, Sanderson AJ, Cannizzo LZ (2004) Polymerization of glycidyl nitrate via catalysis BF3.THF: compatibility with the activated monomer mechanism. 2004 IM/EM Technical Symposium, San Francisco
Zurück zum Zitat Pardi (2005) Optimasi Proses Produksi Gliserol Monooleat dari Gliserol Hasil Samping Pembuatan Biodiesel. USU Digital Library Pardi (2005) Optimasi Proses Produksi Gliserol Monooleat dari Gliserol Hasil Samping Pembuatan Biodiesel. USU Digital Library
Zurück zum Zitat Paul NC, Millar RW, Golding P (1992) Preparation of nitroalkyl-substituted cyclic esters. US Patent 5.145.974 Paul NC, Millar RW, Golding P (1992) Preparation of nitroalkyl-substituted cyclic esters. US Patent 5.145.974
Zurück zum Zitat Provatas A (2000) Energetic polymers and plasticisers for explosive formulations. A review of recent advances. DSTO Aeronautical and Maritime Research Laboratory, Melbourne Provatas A (2000) Energetic polymers and plasticisers for explosive formulations. A review of recent advances. DSTO Aeronautical and Maritime Research Laboratory, Melbourne
Zurück zum Zitat Rao PV, Rao BVA (2011) Effect of adding triacetin additive with coconut oil methyl ester (COME) in performance and emission characteristics of DI diesel engine. Int J Therm Technol 1:100–106 Rao PV, Rao BVA (2011) Effect of adding triacetin additive with coconut oil methyl ester (COME) in performance and emission characteristics of DI diesel engine. Int J Therm Technol 1:100–106
Zurück zum Zitat Reddy PS, Sudarsanam P, Raju G, Reddy BM (2010) Synthesis of bio-additives: acetylation of glycerol over zirconia-based solid acid catalysts. Catal Commun 11:1224–1228CrossRef Reddy PS, Sudarsanam P, Raju G, Reddy BM (2010) Synthesis of bio-additives: acetylation of glycerol over zirconia-based solid acid catalysts. Catal Commun 11:1224–1228CrossRef
Zurück zum Zitat Rubtsov YL, Kazakov AI (1997) Equilibrium constants of nitration of alcohols and thermal stability of their nitrates. Russ Chem Bull 46(10):1707–1709CrossRef Rubtsov YL, Kazakov AI (1997) Equilibrium constants of nitration of alcohols and thermal stability of their nitrates. Russ Chem Bull 46(10):1707–1709CrossRef
Zurück zum Zitat Sailah I (2007) Kajian Awal Proses Polimerisasi Gliserol pada Produksi Poligliserol dari Hasil Samping Industri Biodiesel. LPPM IPB, Bogor Sailah I (2007) Kajian Awal Proses Polimerisasi Gliserol pada Produksi Poligliserol dari Hasil Samping Industri Biodiesel. LPPM IPB, Bogor
Zurück zum Zitat Sanderson JS, Martins LJ (2004) Process for making stable cured poly(glycidyl nitrate). US Patent 6.730.181 Sanderson JS, Martins LJ (2004) Process for making stable cured poly(glycidyl nitrate). US Patent 6.730.181
Zurück zum Zitat Sanderson JS, Martins LJ, Dewey MA (2005) Process for making stable cured poly(glycidyl nitrate) and energetic compositions comprising same. US Patent 6.861.501 Sanderson JS, Martins LJ, Dewey MA (2005) Process for making stable cured poly(glycidyl nitrate) and energetic compositions comprising same. US Patent 6.861.501
Zurück zum Zitat Silva LN, Gonçalves VLC, Mota CJA (2010) Catalytic acetylation of glycerol with acetic anhydride. Catal Commun 11:1036–1039CrossRef Silva LN, Gonçalves VLC, Mota CJA (2010) Catalytic acetylation of glycerol with acetic anhydride. Catal Commun 11:1036–1039CrossRef
Zurück zum Zitat Swaddle TM (1997) Inorganic chemistry: an industrial and environmental perspective. Academic, San Diego, pp 16–38 Swaddle TM (1997) Inorganic chemistry: an industrial and environmental perspective. Academic, San Diego, pp 16–38
Zurück zum Zitat Testa ML, Parola VL, Liotta LF, Venezia AM (2013) Screening of different solid acid catalysts for glycerol acetylation. J Molec Catal A Chem 367:69–76CrossRef Testa ML, Parola VL, Liotta LF, Venezia AM (2013) Screening of different solid acid catalysts for glycerol acetylation. J Molec Catal A Chem 367:69–76CrossRef
Zurück zum Zitat Trevoy LW, Tegg D (1963) Purification of triacetin. US Patent 3.108.133 Trevoy LW, Tegg D (1963) Purification of triacetin. US Patent 3.108.133
Zurück zum Zitat Willer RL, Day RS, Stern AG (1992a) Process for producing improved poly(glycidyl nitrate). US Patent 5.120.827 Willer RL, Day RS, Stern AG (1992a) Process for producing improved poly(glycidyl nitrate). US Patent 5.120.827
Zurück zum Zitat Willer RL, Day RS, Stern AG (1992b) Isotactic poly(glycidyl nitrate) and synthesis thereof. US Patent 5.162.494 Willer RL, Day RS, Stern AG (1992b) Isotactic poly(glycidyl nitrate) and synthesis thereof. US Patent 5.162.494
Zurück zum Zitat Willer RL, Day RS, Stern AG (1993) Isotactic poly(glycidyl nitrate) and synthesis thereof. US Patent 5.264.596 Willer RL, Day RS, Stern AG (1993) Isotactic poly(glycidyl nitrate) and synthesis thereof. US Patent 5.264.596
Zurück zum Zitat Windriyanto IKH, Satriadi H (2012) Produksi Triasetin dengan Proses Esterifikasi Gliserol dan Asam Asetat Menggunakan Katalis Asam Sulfat. Jurnal Teknologi Kimia dan Industri 1(1):508–512 Windriyanto IKH, Satriadi H (2012) Produksi Triasetin dengan Proses Esterifikasi Gliserol dan Asam Asetat Menggunakan Katalis Asam Sulfat. Jurnal Teknologi Kimia dan Industri 1(1):508–512
Zurück zum Zitat Yang S, Lu B (1996) Application of SO42-/ZrO2-TiO2 in synthesis of glicerin triacetate. Xibei Shifan Daxue Xuebao Ziran Kexueban 32(2):43–45 Yang S, Lu B (1996) Application of SO42-/ZrO2-TiO2 in synthesis of glicerin triacetate. Xibei Shifan Daxue Xuebao Ziran Kexueban 32(2):43–45
Zurück zum Zitat Zaldivar JM, Molga E, Alos MA, Hernandez H, Westerterp KR (1995) Aromatic nitrations by mixed acid. slow liquid-liquid reaction regime. Chem Eng Process 34:543–559CrossRef Zaldivar JM, Molga E, Alos MA, Hernandez H, Westerterp KR (1995) Aromatic nitrations by mixed acid. slow liquid-liquid reaction regime. Chem Eng Process 34:543–559CrossRef
Zurück zum Zitat Zang M, Yuan X (2001) Synthesis of glycerol triacetate catalized by phosphotungstic acid. Hecheng Huaxue 9(5):469–472 Zang M, Yuan X (2001) Synthesis of glycerol triacetate catalized by phosphotungstic acid. Hecheng Huaxue 9(5):469–472
Metadaten
Titel
Utilization of Glycerol from Biodiesel Industry By-product into Several Higher Value Products
verfasst von
Zahrul Mufrodi
Erna Astuti
Arief Budiman
Supranto
Sutijan
Agus Prasetya
Rochmadi
Copyright-Jahr
2020
DOI
https://doi.org/10.1007/978-3-030-39208-6_7