Skip to main content
Erschienen in: Journal of Nanoparticle Research 6/2017

01.06.2017 | Research Paper

A comparative study of CO catalytic oxidation on Au/YPO4-prisms and Au/YPO4-rods

verfasst von: Huanhuan Yu, Jiuli Guo, Feng Dong, Baolin Zhu, Weiping Huang, Shoumin Zhang

Erschienen in: Journal of Nanoparticle Research | Ausgabe 6/2017

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config
loading …

Abstract

YPO4 nanoprisms and nanorods were synthesized by hydrothermal and co-precipitation processes. Au/YPO4 catalysts were obtained by a deposition-precipitation method. The as-prepared YPO4 and Au/YPO4 were characterized by N2 adsorption-desorption, XRD, TEM, XPS, ICP, UV-Vis DRS, and FT-IR. The XRD results revealed that YPO4 nanoprisms and nanorods were hexagonal phase. The TEM observations demonstrated that the gold nanoparticles with the size of <4 nm uniformly dispersed on the surface of the support. The XPS spectra revealed that gold was in the metallic state. The catalysis results demonstrated that Au/YPO4-rods performed higher catalytic activity than Au/YPO4-prisms for CO oxidation. 1.0% Au/YPO4-rods catalyst could achieve complete CO conversion at 20 °C. Au/YPO4-prisms exhibited higher sintering-resistant property than Au/YPO4-rods. After continuous operation for 10 h, Au/YPO4-rods showed better stability at low reaction temperature than Au/YPO4-prisms, and both of them showed good stability at the reaction temperature of 220 °C.

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Anhänge
Nur mit Berechtigung zugänglich
Literatur
Zurück zum Zitat Chopade SS, Barve SA, Raman KHT, Chand N, Deo MN, Biswas A, Rai S, Lodha GS, Rao GM, Patil DS (2013) RF plasma MOCVD of Y2O3 thin films: effect of RF self-bias on the substrates during deposition. Appl Surf Sci 285P:524–531. doi:10.1016/j.apsusc.2013.08.087 CrossRef Chopade SS, Barve SA, Raman KHT, Chand N, Deo MN, Biswas A, Rai S, Lodha GS, Rao GM, Patil DS (2013) RF plasma MOCVD of Y2O3 thin films: effect of RF self-bias on the substrates during deposition. Appl Surf Sci 285P:524–531. doi:10.​1016/​j.​apsusc.​2013.​08.​087 CrossRef
Zurück zum Zitat Chimentão RJ, Cota I, Dafinov A, Medina F, Sueiras JE, Fuente JL, Fierro JLG, Cesteros Y, Salagre P (2006) Synthesis of silver-gold alloy nanoparticles by a phase-transfer system. J Mater Res 21:105–111. doi:10.1557/jmr.2006.0014 CrossRef Chimentão RJ, Cota I, Dafinov A, Medina F, Sueiras JE, Fuente JL, Fierro JLG, Cesteros Y, Salagre P (2006) Synthesis of silver-gold alloy nanoparticles by a phase-transfer system. J Mater Res 21:105–111. doi:10.​1557/​jmr.​2006.​0014 CrossRef
Zurück zum Zitat Carrot G, Valmalette JC, Plummer CJG, Scholz SM, Dutta J, Hofmann H, Hilborn JG (1998) Gold nanoparticle synthesis in graft copolymer micelles. Colloid Polym Sci 276:853–859. doi:10.1007/s003960050321 CrossRef Carrot G, Valmalette JC, Plummer CJG, Scholz SM, Dutta J, Hofmann H, Hilborn JG (1998) Gold nanoparticle synthesis in graft copolymer micelles. Colloid Polym Sci 276:853–859. doi:10.​1007/​s003960050321 CrossRef
Zurück zum Zitat Du GH, Guo WW, Al-zyadi JMK, Han YB, Liu P, Liu ZL (2013) Effect of Ce3+ dopant ions on the shape and luminescence of YPO4:Eu3+ and YPO4:Tb3+ nanocrystals. J Nanopart Res 15:1619. doi:10.1007/s11051-013-1619-0 CrossRef Du GH, Guo WW, Al-zyadi JMK, Han YB, Liu P, Liu ZL (2013) Effect of Ce3+ dopant ions on the shape and luminescence of YPO4:Eu3+ and YPO4:Tb3+ nanocrystals. J Nanopart Res 15:1619. doi:10.​1007/​s11051-013-1619-0 CrossRef
Zurück zum Zitat Fang YP, Xu AW, Song RQ, Zhang HX, You LP, Yu JC, Liu HQ (2003) Systematic synthesis and characterization of single-crystal lanthanide orthophosphate nanowires. J Am Chem Soc 125:16025–16034. doi:10.1021/ja037280d CrossRef Fang YP, Xu AW, Song RQ, Zhang HX, You LP, Yu JC, Liu HQ (2003) Systematic synthesis and characterization of single-crystal lanthanide orthophosphate nanowires. J Am Chem Soc 125:16025–16034. doi:10.​1021/​ja037280d CrossRef
Zurück zum Zitat Haruta M, Kobayashi T, Sano H, Yamada N (1987) Novel gold catalysts for the oxidation of carbon monoxide at a temperature far below 0 °C. Chem Lett 16(2):405–408. doi:10.1246/cl.1987.405 CrossRef Haruta M, Kobayashi T, Sano H, Yamada N (1987) Novel gold catalysts for the oxidation of carbon monoxide at a temperature far below 0 °C. Chem Lett 16(2):405–408. doi:10.​1246/​cl.​1987.​405 CrossRef
Zurück zum Zitat Li CX, Hou ZY, Zhang CM, Yang PP, Li GG, Xu ZH, Fan Y, Lin J (2009) Controlled synthesis of Ln3+ (Ln = Tb, Eu, Dy) and V5+ ion-doped YPO4 Nano−/microstructures with tunable luminescent colors. Chem Mater 21:4598–4607. doi:10.1021/cm901658k CrossRef Li CX, Hou ZY, Zhang CM, Yang PP, Li GG, Xu ZH, Fan Y, Lin J (2009) Controlled synthesis of Ln3+ (Ln = Tb, Eu, Dy) and V5+ ion-doped YPO4 Nano−/microstructures with tunable luminescent colors. Chem Mater 21:4598–4607. doi:10.​1021/​cm901658k CrossRef
Zurück zum Zitat Liu XY, Liu MH, Luo YC, Mou CY, Lin SD, Cheng HK, Chen JM, Lee JF, Lin TS (2012) Strong metal-support interactions between gold nanoparticles and ZnO nanorods in CO oxidation. J Am Chem Soc 134:10251–10258. doi:10.1021/ja3033235 CrossRef Liu XY, Liu MH, Luo YC, Mou CY, Lin SD, Cheng HK, Chen JM, Lee JF, Lin TS (2012) Strong metal-support interactions between gold nanoparticles and ZnO nanorods in CO oxidation. J Am Chem Soc 134:10251–10258. doi:10.​1021/​ja3033235 CrossRef
Zurück zum Zitat Luwang MN, Ningthoujam RS, Jagannath SSK, Vastsa RK (2010) Effects of Ce3+ codoping and annealing on phase transformation and luminescence of Eu3+-doped YPO4 nanorods: D2O solvent effect. J Am Chem Soc 132:2759–2768. doi:10.1021/ja909578s CrossRef Luwang MN, Ningthoujam RS, Jagannath SSK, Vastsa RK (2010) Effects of Ce3+ codoping and annealing on phase transformation and luminescence of Eu3+-doped YPO4 nanorods: D2O solvent effect. J Am Chem Soc 132:2759–2768. doi:10.​1021/​ja909578s CrossRef
Zurück zum Zitat Luwang MN, Ningthoujam RS, Srivastava SK, Vatsa RK (2011) Disappearance and recovery of luminescence in Bi3+, Eu3+ codoped YPO4 nanoparticles due to the presence of water molecules up to 800°C. J Am Chem Soc 133:2998–3004. doi:10.1021/ja1092437 CrossRef Luwang MN, Ningthoujam RS, Srivastava SK, Vatsa RK (2011) Disappearance and recovery of luminescence in Bi3+, Eu3+ codoped YPO4 nanoparticles due to the presence of water molecules up to 800°C. J Am Chem Soc 133:2998–3004. doi:10.​1021/​ja1092437 CrossRef
Zurück zum Zitat Majeed S, Bashir M, Shivashankar SA (2015) Dispersible crystalline nanobundles of YPO4 and Ln (Eu, Tb)-doped YPO4: rapid synthesis, optical properties and bio-probe applications. J Nanopart Res 17:309. doi:10.1007/s11051-015-3113-3 CrossRef Majeed S, Bashir M, Shivashankar SA (2015) Dispersible crystalline nanobundles of YPO4 and Ln (Eu, Tb)-doped YPO4: rapid synthesis, optical properties and bio-probe applications. J Nanopart Res 17:309. doi:10.​1007/​s11051-015-3113-3 CrossRef
Zurück zum Zitat Moriya T, Kugai J, Seino S, Ohkubo Y, Nakagawa TN, Nitani H, Yamamoto TA (2013) CuO role in γ-Fe2O3-supported Pt-Cu bimetallic nanoparticles synthesized by radiation-induced reduction as catalysts for preferential CO oxidation. J Nanopart Res 15:1451. doi:10.1007/s11051-013-1451-6 CrossRef Moriya T, Kugai J, Seino S, Ohkubo Y, Nakagawa TN, Nitani H, Yamamoto TA (2013) CuO role in γ-Fe2O3-supported Pt-Cu bimetallic nanoparticles synthesized by radiation-induced reduction as catalysts for preferential CO oxidation. J Nanopart Res 15:1451. doi:10.​1007/​s11051-013-1451-6 CrossRef
Zurück zum Zitat Najafishirtari S, Guardia P, Scarpellini A, Prato M, Marras S, Manna L, Colombo M (2016) The effect of Au domain size on the CO oxidation catalytic activity of colloidal Au-FeOx dumbbell-like heterodimers. J Catal 338:115–123. doi:10.1016/j.jcat.2016.03.002 CrossRef Najafishirtari S, Guardia P, Scarpellini A, Prato M, Marras S, Manna L, Colombo M (2016) The effect of Au domain size on the CO oxidation catalytic activity of colloidal Au-FeOx dumbbell-like heterodimers. J Catal 338:115–123. doi:10.​1016/​j.​jcat.​2016.​03.​002 CrossRef
Zurück zum Zitat Rodriguez JA, Si R, Evans J, Xu WQ, Hanson JC, Tao J, Zhu YM (2015) Active gold-ceria and gold-ceria/titania catalysts for CO oxidation: from single-crystal model catalysts to powder catalysts. Catal Today 240:229–235. doi:10.1016/j.cattod.2014.06.033 CrossRef Rodriguez JA, Si R, Evans J, Xu WQ, Hanson JC, Tao J, Zhu YM (2015) Active gold-ceria and gold-ceria/titania catalysts for CO oxidation: from single-crystal model catalysts to powder catalysts. Catal Today 240:229–235. doi:10.​1016/​j.​cattod.​2014.​06.​033 CrossRef
Zurück zum Zitat Tian CC, Chai SH, Zhu X, Wu ZL, Binder A, Bauer JC, Brown S, Chi MF, Veith GM, Guo YL, Dai S (2012) In situ growth synthesis of heterostructured LnPO4–SiO2 (Ln= La, Ce, and Eu) mesoporous materials as supports for small gold particles used in catalytic CO oxidation. J Mater Chem 22:25227–25235. doi:10.1039/c2jm35416k CrossRef Tian CC, Chai SH, Zhu X, Wu ZL, Binder A, Bauer JC, Brown S, Chi MF, Veith GM, Guo YL, Dai S (2012) In situ growth synthesis of heterostructured LnPO4–SiO2 (Ln= La, Ce, and Eu) mesoporous materials as supports for small gold particles used in catalytic CO oxidation. J Mater Chem 22:25227–25235. doi:10.​1039/​c2jm35416k CrossRef
Zurück zum Zitat Venkov T, Fajerwerg K, Delannoy L, Klimev H, Hadjiivanov K, Louis C (2006) Effect of the activation temperature on the state of gold supported on titania: an FT-IR spectroscopic study. Appl Catal a 301:106–114. doi:10.1016/j.apcata.2005.11.019 CrossRef Venkov T, Fajerwerg K, Delannoy L, Klimev H, Hadjiivanov K, Louis C (2006) Effect of the activation temperature on the state of gold supported on titania: an FT-IR spectroscopic study. Appl Catal a 301:106–114. doi:10.​1016/​j.​apcata.​2005.​11.​019 CrossRef
Zurück zum Zitat Wang ZH, Fu HF, Tian ZW, Han DM, Gu FB (2016) Strong metal–support interaction in novel core–shell Au–CeO2 nanostructures induced by different pretreatment atmospheres and its influence on CO oxidation. Nano 8:5865–5872. doi:10.1039/c5nr06929g Wang ZH, Fu HF, Tian ZW, Han DM, Gu FB (2016) Strong metal–support interaction in novel core–shell Au–CeO2 nanostructures induced by different pretreatment atmospheres and its influence on CO oxidation. Nano 8:5865–5872. doi:10.​1039/​c5nr06929g
Zurück zum Zitat Westcott SL, Oldenburg SJ, Lee TR, Halas NJ (1998) Formation and adsorption of clusters of gold nanoparticles onto functionalized silica nanoparticle surfaces. Langmuir 14:5396–5401. doi:10.1021/la980380q CrossRef Westcott SL, Oldenburg SJ, Lee TR, Halas NJ (1998) Formation and adsorption of clusters of gold nanoparticles onto functionalized silica nanoparticle surfaces. Langmuir 14:5396–5401. doi:10.​1021/​la980380q CrossRef
Zurück zum Zitat Yan WF, Brown S, Pan ZW, Mahurin SM, Overbury SH, Dai S (2006) Ultrastable gold nanocatalyst supported by nanosized non-oxide substrate. Angew Chem Int Ed 45:3614–3618. doi:10.1002/anie.200503808 CrossRef Yan WF, Brown S, Pan ZW, Mahurin SM, Overbury SH, Dai S (2006) Ultrastable gold nanocatalyst supported by nanosized non-oxide substrate. Angew Chem Int Ed 45:3614–3618. doi:10.​1002/​anie.​200503808 CrossRef
Zurück zum Zitat Zanella R, Giorgio S, Shin CH, Henry CR, Louis C (2004) Characterization and reactivity in CO oxidation of gold nanoparticles supported on TiO2 prepared by deposition-precipitation with NaOH and urea. J Catal 222:357–367. doi:10.1016/j.jcat.2003.11.005 CrossRef Zanella R, Giorgio S, Shin CH, Henry CR, Louis C (2004) Characterization and reactivity in CO oxidation of gold nanoparticles supported on TiO2 prepared by deposition-precipitation with NaOH and urea. J Catal 222:357–367. doi:10.​1016/​j.​jcat.​2003.​11.​005 CrossRef
Zurück zum Zitat Zhang P, Guo JL, Zhao P, Zhu BL, Huang WP, Zhang SM (2015) Promoting effects of lanthanum on the catalytic activity of Au/TiO2 nanotubes for CO oxidation. RSC Adv 5:11989–11995. doi:10.1039/c4ra14133d CrossRef Zhang P, Guo JL, Zhao P, Zhu BL, Huang WP, Zhang SM (2015) Promoting effects of lanthanum on the catalytic activity of Au/TiO2 nanotubes for CO oxidation. RSC Adv 5:11989–11995. doi:10.​1039/​c4ra14133d CrossRef
Zurück zum Zitat Zheng YL, Mao DS, Sun SS, Fu GY (2015) CO oxidation on CuO/CeO2 catalyst prepared by solvothermal synthesis: influence of catalyst activation temperature. J Nanopart Res 17:471. doi:10.1007/s11051-015-3282-0 CrossRef Zheng YL, Mao DS, Sun SS, Fu GY (2015) CO oxidation on CuO/CeO2 catalyst prepared by solvothermal synthesis: influence of catalyst activation temperature. J Nanopart Res 17:471. doi:10.​1007/​s11051-015-3282-0 CrossRef
Zurück zum Zitat Zhu W, Xiao SN, Zhang DQ, Liu PJ, Zhou HJ, Dai WR, Liu FF, Li HX (2015) Highly efficient and stable Au/CeO2-TiO2 photocatalyst for nitric oxide abatement: potential application in flue gas treatment. Langmuir 31:10822–10830. doi:10.1021/acs.langmuir.5b02232 CrossRef Zhu W, Xiao SN, Zhang DQ, Liu PJ, Zhou HJ, Dai WR, Liu FF, Li HX (2015) Highly efficient and stable Au/CeO2-TiO2 photocatalyst for nitric oxide abatement: potential application in flue gas treatment. Langmuir 31:10822–10830. doi:10.​1021/​acs.​langmuir.​5b02232 CrossRef
Zurück zum Zitat Zhang TY, Wang SP, Yu Y, Su Y, Guo XZ, Wang SR, Zhang SM, Wu SH (2008) Synthesis, characterization of CuO/Ce0.8Sn0.2O2 catalysts for low-temperature CO oxidation. Catal. Commun 9:1259–1264. doi:10.1016/j.catcom.2007.11.013 Zhang TY, Wang SP, Yu Y, Su Y, Guo XZ, Wang SR, Zhang SM, Wu SH (2008) Synthesis, characterization of CuO/Ce0.8Sn0.2O2 catalysts for low-temperature CO oxidation. Catal. Commun 9:1259–1264. doi:10.​1016/​j.​catcom.​2007.​11.​013
Zurück zum Zitat Zhao H, Zhang P, Wang YD, Huang WP, Zhang SM (2014) Au/TiO2 nanotube catalysts prepared by combining sol–gel method with hydrothermal treatment and their catalytic properties for CO oxidation. J Sol-Gel Sci Technol 71:406–412. doi:10.1007/s10971-014-3390-9 CrossRef Zhao H, Zhang P, Wang YD, Huang WP, Zhang SM (2014) Au/TiO2 nanotube catalysts prepared by combining sol–gel method with hydrothermal treatment and their catalytic properties for CO oxidation. J Sol-Gel Sci Technol 71:406–412. doi:10.​1007/​s10971-014-3390-9 CrossRef
Metadaten
Titel
A comparative study of CO catalytic oxidation on Au/YPO4-prisms and Au/YPO4-rods
verfasst von
Huanhuan Yu
Jiuli Guo
Feng Dong
Baolin Zhu
Weiping Huang
Shoumin Zhang
Publikationsdatum
01.06.2017
Verlag
Springer Netherlands
Erschienen in
Journal of Nanoparticle Research / Ausgabe 6/2017
Print ISSN: 1388-0764
Elektronische ISSN: 1572-896X
DOI
https://doi.org/10.1007/s11051-017-3891-x

Weitere Artikel der Ausgabe 6/2017

Journal of Nanoparticle Research 6/2017 Zur Ausgabe

    Marktübersichten

    Die im Laufe eines Jahres in der „adhäsion“ veröffentlichten Marktübersichten helfen Anwendern verschiedenster Branchen, sich einen gezielten Überblick über Lieferantenangebote zu verschaffen.