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Polymer Bulletin

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01.12.2013 | Original Paper

A facile synthesis of polyaniline/polyethylene glycol/polyaniline terpolymers: preparation of electrospun conducting nanofibers by blending of the terpolymers with polycaprolactone

verfasst von: Leyla Shadi, Mohammad Karimi, Ali Akbar Entezami, Kazem Dindar Safa

Erschienen in: Polymer Bulletin | Ausgabe 12/2013

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Abstract

The water-soluble terpolymers were synthesized in two steps, containing esterification of polyethylene glycol (PEG) and 4-amino benzoic acid without protection of its amino group, then copolymerization of aniline from both end of amine-terminated PEG via an interfacial polymerization method. The chemical structure of triblock copolymers was determined by FTIR and ¹HNMR. The thermal behavior, morphology and electroactivity of terpolymers were also investigated by thermogravimetric analysis, field emission microscope (FESEM) and cyclic voltammetry (CV), respectively. Uniform nanofibers consisting of blends of (PANI)_n-b-PEG-b-(PANI)_n terpolymers and polycaprolactone (PCL) were prepared using electrospinning technique. The FESEM was also used to investigate the electrospun nanofibers produced from different molecular weight of PANI/PEG/PANI terpolymers and PCL (30/70). The CV measurements of blends confirmed the preparation of electroactive nanofibers. The presence of terpolymers enhanced the spinnability of solution and significantly reduced the bead formation. This novel system opens up new and interesting opportunities for applications such as electroactive scaffold for tissue engineering.

Vorheriger Artikel Colorimetric chemosensor for ATP based on phthalimide-appended poly(2,5-dimethoxyaniline)

Nächster Artikel A novel twin-tailed hydrophobically associating copolymer: synthesis, characterization and solution properties

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Titel: A facile synthesis of polyaniline/polyethylene glycol/polyaniline terpolymers: preparation of electrospun conducting nanofibers by blending of the terpolymers with polycaprolactone
verfasst von: Leyla Shadi
Mohammad Karimi
Ali Akbar Entezami
Kazem Dindar Safa
Publikationsdatum: 01.12.2013
Verlag: Springer Berlin Heidelberg
Erschienen in: Polymer Bulletin / Ausgabe 12/2013
Print ISSN: 0170-0839
Elektronische ISSN: 1436-2449
DOI: https://doi.org/10.1007/s00289-013-1038-5

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