Skip to main content
Fachgebiete
Automobil + Motoren Bauwesen + Immobilien Business IT + Informatik Elektrotechnik + Elektronik Energie + Nachhaltigkeit Finance + Banking Management + Führung Marketing + Vertrieb Maschinenbau + Werkstoffe Versicherung + Risiko
DE
EN
Themenseiten
Organisationspsychologie Projektmanagement Marketing Smart Manufacturing
Bücher
Zeitschriften
Weitere Formate
Podcasts Webinare Technik Webinare Wirtschaft Kongresse Veranstaltungskalender Awards
Jetzt Einzelzugang starten
Zugang für Unternehmen
Referenzkunden
MTZ-Fachkongress

Antriebe und Energiesysteme von morgen


Austausch von Automobil- und Energiewirtschaft

Am 14./15. Mai geht es in Chemnitz um die Mobilitätswende durch Elektro- und Wasserstofffahrzeuge.
Erweiterte Suche
Anmelden
nach oben
Journal of Sol-Gel Science and Technology
Erschienen in: Journal of Sol-Gel Science and Technology 2/2015

01.08.2015 | Original Paper

A new method for elaborating mesoporous SiO2/montmorillonite composite materials

verfasst von: Tesnime Abou Khalil, Semy Ben Chaabene, Souhir Boujday, Juliette Blanchard, Latifa Bergaoui

Erschienen in: Journal of Sol-Gel Science and Technology | Ausgabe 2/2015

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config
loading …

Abstract

We report the sol–gel preparation of SiO2/montmorillonite composite materials and the investigation of the effect of the amount of clay and the TEOS concentration on the textural and structural properties of the composites. Pre-swelling of the clay with cetyltrimethyl ammonium results in solids with a larger mesoporous surface area. A decrease in the gel time and an increase in the surface area were observed upon increasing the amount of clay in the reaction medium. These porous solids showed acidic properties, and their acidities were correlated with the amount of the clay mineral. The obtained composites were functionalized by adding manganese, and their catalytic properties were evaluated in the cyclohexene oxidation reaction.

Graphical Abstract

Vorheriger Artikel Synthesis of visible light-responsive cobalt-doped TiO2 nanoparticles with tunable optical band gap
Nächster Artikel Development of an aqueous TiO2 paste in terms of morphological manipulation of nanostructured photoanode electrode of dye-sensitized solar cells

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Jetzt informieren
Literatur
1.
Murray HH (2000) Traditional and new application for kaolin, smectite, and palygorskite: a general over view. Appl Clay Sci 17:207–221CrossRef
2.
Pinnavaia TJ, Tzou M-S, Landau SD, Raythatha RH (1984) On the pillared and delamination of smectite clay catalysis by polyoxo cations of aluminium. J Mol Catal 27:195–212CrossRef
3.
Lambert JF, Poncelet G (1997) Acidity in pillared clays: origin and catalytic manifestations. Top Catal 4:43–56CrossRef
4.
Vaccari A (1999) Clays and catalysis: a promising future. Appl Clay Sci 14:161–198CrossRef
5.
Ben Chaabene S, Bergaoui L, Ghorbel A, Lambert JF, Grange P (2003) Acidic properties of a clay prepared from the reaction of zirconyl chloride solution containing sulfate ions with montmorillonite. Appl Catal A-Gen 252:411–419CrossRef
6.
Sadek OM, Reda SM, Al-Bilali RK (2013) Preparation and characterization of silica and clay–silica core-shell nanoparticles using sol–gel method. Adv Nanoparticles 2:165–175CrossRef
7.
Dudarko OA, Gunathilake C, Sliesarenko VV, Zub YL, Jaroniec M (2014) Microwave-assisted and conventional hydrothermal synthesis of ordered mesoporous silicas with P-containing functionalities. Colloids Surf A 459:4–10CrossRef
8.
Zhao D, Huo Q, Feng J, Chmelka BF, Stucky GD (1998) Nonionic triblock and star diblock copolymer and oligomeric surfactant syntheses of highly ordered, hydrothermally stable, mesoporous silica structures. J Am Chem Soc 120:6024–6036CrossRef
9.
El-Toni AM, Habila MA, Ibrahim MA, Labis JP, Al Othman ZA (2014) Simple and facile synthesis of amino functionalized hollow core–mesoporous shell silica spheres using anionic surfactant for Pb(II), Cd(II), and Zn(II) adsorption and recovery. Chem Eng J 251:441–451CrossRef
10.
Rahman MS, Ambati J, Joshi S, Rankin SE (2014) Incorporation of isolated Ti sites into mesoporous silica thin films by sugar surfactant complexation. Micro Meso Mater 190:74–83CrossRef
11.
Ganguly SC (2001) Book review: polymer–clay nanocomposites in polymer science. In Pinnavaia TJ, Beall GW (eds) John Wiley & Sons Ltd., Chichester, West Sussex 370 pp. J Inorg Organomet Polym 11: 247–251
12.
Galarneau A, Barodawalla A, Pinnavaia TJ (1994) Porous clay heterostructures formed by gallery-templated synthesis. Nature 374:529–531CrossRef
13.
Mercier L, Pinnavaia TJ (1998) A functionalized porous clay heterostructure for heavy metal ion (Hg2+) trapping. Micro Meso Mater 20:101–106CrossRef
14.
Zhu HY, Ding Z, Lu CQ, Lu GQ (2002) Molecular engineered porous clays using surfactants. Appl Clay Sci 20:165–175CrossRef
15.
Lagaly G, Dékany I (2005) Adsorption on hydrophobized surfaces: clusters and self-organization. Adv Colloid Interface 114–115:189–204CrossRef
16.
Zhu JX, He HP, Guo JG, Yang D, Xie XD (2003) Arrangement models of alkylammonium cations in the interlayer of HDTMA+ pillared montmorillonites. Chin Sci Bull 48:368–372
17.
Aliouane N, Hammouche A, De Doncker RW, Telli L, Boutahala M, Brahimi B (2002) Investigation of hydration and protonic conductivity of H-montmorillonite. Solid State Ionics 148:103–110CrossRef
18.
Bérend I, Cases JM, Francois M, Uriot JP, Michot L, Masion A, Thomas F (1995) Mechanism of adsorption and desorption of water vapor by homoionic montmorillonites: 2. The Li+, Na+, K+, Rb+, and Cs+-exchanged forms. Clay Clay Miner 43:324–336CrossRef
19.
Monnier A, Schüth F, Huo Q, Kumar D, Margolese D, Maxwell RS, Stucky GD, Krishnamurthy M, Petroff P, Firouzi A, Janicke M, Chmelka BF (1993) Cooperative Formation of inorganic–organic interfaces in the synthesis of silicate mesostructures. Science 261:1299–1303CrossRef
20.
Chen CY, Burkett SL, Li HX, Davis ME (1993) Studies on mesoporous materials II. Synthesis mechanism of MCM-41. Microporous Mater 2:27–34CrossRef
21.
Livage J, Henry M, Sanchez C (1988) Sol–gel chemistry of transition metal oxides. Prog Solid State Chem 18:259–341CrossRef
22.
Zhou CH, Li XN, Ge ZH, Li QW, Tong DS (2004) Synthesis and acid catalysis of nanoporous silica/alumina-clay composites. Catal Today 93–95:607–613CrossRef
23.
Zapata PA, Belver C, Quijada R, Aranda P, Ruiz-Hitzky E (2013) Silica/clay organo-heterostructures to promote polyethylene-clay nanocomposites by in situ polymerization. Appl Catal A 453:142–150CrossRef
24.
Li B, Mao H, Li X, Ma W, Liu Z (2009) Synthesis of mesoporous silica-pillared clay by intragallery ammonia-catalyzed hydrolysis of tetraethoxysilane using quaternary ammonium surfactants as gallery templates. J Colloid Interface Sci 336:244–249CrossRef
25.
Fatimah I, Huda T (2013) Preparation of cetyltrimethylammonium intercalated Indonesian montmorillonite for adsorption of toluene. Appl Clay Sci 74:115–120CrossRef
26.
Li F, Jiang Y, Xia M, Sun M, Xue B, Ren XA (2010) Novel mesoporous silica–clay composite and its thermal and hydrothermal stabilities. J Porous Mater 17:217–223CrossRef
27.
Tayade KN, Mishra M (2014) Catalytic activity of MCM-41 and Al grafted MCM-41 for oxidative self and cross coupling of amines. J Mol Catal A Chem 382:114–125CrossRef
28.
Arzoumanian H, Blanc A, Hartig U, Metzger J (1974) Homogeneous bimetallic catalysis. The selective autoxidation of cyclohexene. Tetrahedron Lett 12:1011–1014CrossRef
29.
Sakthivel A, Dapurkar SE, Selvam P (2003) Allylic oxidation of cyclohexene over chromium containing mesoporous molecular sieves. Appl Catal A 246:283–293CrossRef
30.
Mukherjee S, Samanta S, Bhaumik A, Ray BC (2006) Mechanistic study of cyclohexene oxidation and its use in modification of industrial waste organics. Appl Catal B Environ 68:12–20CrossRef
31.
Jermy BR, Kim SY, Bineesh KV, Selvaraj M, Park DW (2009) Easy route for the synthesis of Fe–SBA-16 at weak acidity and its catalytic activity in the oxidation of cyclohexene. Micro Meso Mater 121:103–113CrossRef
32.
Tong J, Zhang Y, Li Z, Xia C (2006) Highly effective catalysts of natural polymer supported Salophen Mn(III) complexes for aerobic oxidation of cyclohexene. J Mol Catal A Chem 249:47–52CrossRef
33.
Ameur N, Bedrane S, Bachir R, Choukchou-Braham A (2013) Influence of nanoparticles oxidation state in gold based catalysts on the product selectivity in liquid phase oxidation of cyclohexene. J Mol Catal A Chem 374–375:1–6CrossRef
34.
Salavati Niassari M, Farzaneh F, Ghandi M, Turkian L (2000) Oxidation of cyclohexene with tert-butylhydroperoxide catalyzed by manganese(II) complexes included in zeolite Y. J Mol Catal A Chem 157:183–188CrossRef
35.
Salavati-Niasari M, Salemi P, Davar F (2005) Oxidation of cyclohexene with Tert-butylhydroperoxide and hydrogen peroxide catalysted by Cu(II), Ni(II), Co(II) and Mn(II) complexes of N,N′-bis-(α-methylsalicylidene)-2,2-dimethylpropane-1,3-diamine, supported on alumina. J Mol Catal A Chem 238:215–222CrossRef
36.
Habibi D, Faraji AR, Arshadi M, Fierro JLG (2013) Characterization and catalytic activity of a novel Fe nano-catalyst as efficient heterogeneous catalyst for selective oxidation of ethylbenzene, cyclohexene, and benzylalcohol. J Mol Catal A Chem 372:90–99CrossRef
37.
Sheldon RA, Kochi JK (1981) Metal-catalyzed oxidations of organic compounds. Academic Press, New York
38.
Modén B, Zhan BZ, Dakka J, Santiesteban JG, Iglesia E (2006) Kinetics and mechanism of cyclohexane oxidation on MnAPO-5 catalysts. J Catal 239:390–401CrossRef
39.
Salavati-Niasari M (2008) Host (nanopores of zeolite-Y)/guest [manganese(II) with 12-membered tetradentate N2O2, N2S2 and N4 donor macrocyclic ligands] nanocatalysts: flexible ligand synthesis, characterization and catalytic activity. Transit Metal Chem 33:443–452CrossRef
40.
Gemeay AH, Salem MA, Salem IA (1996) Activity of silica–alumina surface modified with some transition metal ions. Colloids Surf A 117:245–252CrossRef
Metadaten
Titel
A new method for elaborating mesoporous SiO2/montmorillonite composite materials
verfasst von
Tesnime Abou Khalil
Semy Ben Chaabene
Souhir Boujday
Juliette Blanchard
Latifa Bergaoui
Publikationsdatum
01.08.2015
Verlag
Springer US
Erschienen in
Journal of Sol-Gel Science and Technology / Ausgabe 2/2015
Print ISSN: 0928-0707
Elektronische ISSN: 1573-4846
DOI
https://doi.org/10.1007/s10971-015-3716-2

Weitere Artikel der Ausgabe 2/2015

Journal of Sol-Gel Science and Technology 2/2015 Zur Ausgabe

Original Paper

Synthesis and characterization of mesoporous materials containing cerium, lanthanum and praseodymium by nonhydrothermal method

Original Paper

Effect of heat treatment on the size, structural and catalytic properties of Al2O3–CeO2 nanocomposite powder prepared by microemulsion method

Original Paper

Synthesis and spectroscopic properties of silica nanoparticles as scatter centers in random gain porous media

Original Paper

Entrapment of phenol red (PR) pH indicator into sol–gel matrix in presence of some surfactants

Original Paper

Synthesis of ultra-fine and controllable size distribution nanocrystalline MgAl2O4 powders and ascertainment of aluminum loss by introducing inert atmosphere pre-calcination during combustion

Original Paper

Synthesis and physicochemical characterization of LaCr1−xCuxO3

Premium Partner

    Marktübersichten

    Die im Laufe eines Jahres in der „adhäsion“ veröffentlichten Marktübersichten helfen Anwendern verschiedenster Branchen, sich einen gezielten Überblick über Lieferantenangebote zu verschaffen. 

    Zur Marktübersicht
    Bildnachweise