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Erschienen in: Journal of Polymer Research 9/2020

01.09.2020 | Original paper

A novel multi-triggered natural rubber (NR)/beeswax (BW)/carbon nanotube (CNT) shape memory bio-nanocomposite

verfasst von: Sun-Mou Lai, Geng-Lun Guo, Yi-Cheng Xie, Jian-Ming Chen, Dun-Yu Xu, Yu-En Wei, Zhou-Rong Cao

Erschienen in: Journal of Polymer Research | Ausgabe 9/2020

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Abstract

The shape memory properties of sulfur crosslinked natural rubber/beeswax (NR/BW) bio-blends and nanocomposites at three blending compositions (8:2, 6:4, and 4:6) were investigated. The melting temperature of beeswax was used as the switching temperature in the one-way shape memory process. The addition of multi-walled carbon nanotube (CNT) into the NR/BW matrix was helpful in not only improving the beeswax dispersion but also serving the near-infrared absorber to remotely trigger the shape memory process. Most surprisingly, the crystal orientation of beeswax in the natural rubber matrix was parallel to the stretching direction. In addition, the NR/BW blends and nanocomposites demonstrated the THF and acetone solvent vapor-triggered reversible shape memory behavior, which was hardly achieved without applying external stress and pre-soaking treatment as seen in the literature. This simple blending approach offers tremendous possibilities to prepare bio-based blends and nanocomposites with reversible shape memory properties.

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Literatur
1.
Zurück zum Zitat Hager MD, Bode S, Weber C, Schubert US (2015) Shape memory polymers: past, present and future developments. Prog Polym Sci 49(50):3–33 Hager MD, Bode S, Weber C, Schubert US (2015) Shape memory polymers: past, present and future developments. Prog Polym Sci 49(50):3–33
2.
Zurück zum Zitat Ratna D, Karger-Kocsis J (2008) Recent advances in shape memory polymers and composites: a review. J Mater Sci 43(1):254–269 Ratna D, Karger-Kocsis J (2008) Recent advances in shape memory polymers and composites: a review. J Mater Sci 43(1):254–269
3.
Zurück zum Zitat Leng J, Lan X, Liu Y, Du S (2011) Shape-memory polymers and their composites: stimulus methods and applications. Prog Mater Sci 56(7):1077–1135 Leng J, Lan X, Liu Y, Du S (2011) Shape-memory polymers and their composites: stimulus methods and applications. Prog Mater Sci 56(7):1077–1135
4.
Zurück zum Zitat Meng H, Li G (2013) A review of stimuli-responsive shape memory polymer composites. Polymer 54(9):2199–2221 Meng H, Li G (2013) A review of stimuli-responsive shape memory polymer composites. Polymer 54(9):2199–2221
5.
Zurück zum Zitat Lu H, Lei M, Yao Y, Yu K, Fu YQ (2014) Shape memory polymer nanocomposites: nano-reinforcement and multifunctionalization. Nanosci Nanotechnol Lett 6(9):772–786 Lu H, Lei M, Yao Y, Yu K, Fu YQ (2014) Shape memory polymer nanocomposites: nano-reinforcement and multifunctionalization. Nanosci Nanotechnol Lett 6(9):772–786
6.
Zurück zum Zitat Mu T, Liu L, Lan X, Liu Y, Leng J (2018) Shape memory polymers for composites. Compos Sci Technol 160:169–198 Mu T, Liu L, Lan X, Liu Y, Leng J (2018) Shape memory polymers for composites. Compos Sci Technol 160:169–198
7.
Zurück zum Zitat Thomsen DL, Keller P, Naciri J, Pink R, Jeon H, Shenoy D, Ratna BR (2001) Liquid crystal elastomers with mechanical properties of a muscle. Macromolecules 34(17):5868–5875 Thomsen DL, Keller P, Naciri J, Pink R, Jeon H, Shenoy D, Ratna BR (2001) Liquid crystal elastomers with mechanical properties of a muscle. Macromolecules 34(17):5868–5875
8.
Zurück zum Zitat Tajbakhsh AR, Terentjev EM (2001) Spontaneous thermal expansion of nematic elastomers. Eur Phys J E 6(2):181–188 Tajbakhsh AR, Terentjev EM (2001) Spontaneous thermal expansion of nematic elastomers. Eur Phys J E 6(2):181–188
9.
Zurück zum Zitat Chung T, Rorno-Uribe A, Mather PT (2008) Two-way reversible shape memory in a semicrystalline network. Macromolecules 41(1):184–192 Chung T, Rorno-Uribe A, Mather PT (2008) Two-way reversible shape memory in a semicrystalline network. Macromolecules 41(1):184–192
10.
Zurück zum Zitat Zotzmann J, Behl M, Hofmann D, Lendlein A (2010) Reversible triple-shape effect of polymer networks containing polypentadecalactone-and poly(ε-caprolactone)-segments. Adv Mater 22(31):3424–3429PubMed Zotzmann J, Behl M, Hofmann D, Lendlein A (2010) Reversible triple-shape effect of polymer networks containing polypentadecalactone-and poly(ε-caprolactone)-segments. Adv Mater 22(31):3424–3429PubMed
11.
Zurück zum Zitat Bothe M, Pretsch T (2012) Two-way shape changes of a shape-memory poly(ester urethane). Macromol Chem Phys 213(22):2378–2385 Bothe M, Pretsch T (2012) Two-way shape changes of a shape-memory poly(ester urethane). Macromol Chem Phys 213(22):2378–2385
12.
Zurück zum Zitat Bothe M, Pretsch T (2013) Bidirectional actuation of a thermoplastic polyurethane elastomer. J Mater Chem A 1(46):14491–14497 Bothe M, Pretsch T (2013) Bidirectional actuation of a thermoplastic polyurethane elastomer. J Mater Chem A 1(46):14491–14497
13.
Zurück zum Zitat Behl M, Kratz K, Zotzmann J, Nöchel U, Lendlein A (2013) Reversible bidirectional shape-memory polymers. Adv Mater 25(32):4466–4469PubMed Behl M, Kratz K, Zotzmann J, Nöchel U, Lendlein A (2013) Reversible bidirectional shape-memory polymers. Adv Mater 25(32):4466–4469PubMed
14.
Zurück zum Zitat Qian C, Dong Y, Zhu Y, Fu Y (2016) Two-way shape memory behavior of semi-crystalline elastomer under stress-free condition. Smart Mater Struct 25(8):085023 Qian C, Dong Y, Zhu Y, Fu Y (2016) Two-way shape memory behavior of semi-crystalline elastomer under stress-free condition. Smart Mater Struct 25(8):085023
15.
Zurück zum Zitat Gao Y, Liu W, Zhu S (2017) Polyolefin thermoplastics for multiple shape and reversible shape memory. ACS Appl Mater Interfaces 9(5):4882–4889PubMed Gao Y, Liu W, Zhu S (2017) Polyolefin thermoplastics for multiple shape and reversible shape memory. ACS Appl Mater Interfaces 9(5):4882–4889PubMed
16.
Zurück zum Zitat Fan LF, Rong MZ, Zhang MQ, Chen XD (2017) A facile approach toward scalable fabrication of reversible shape-memory polymers with bonded elastomer microphases as internal stress provider. Macromol Rapid Commun 38(16):1700124 Fan LF, Rong MZ, Zhang MQ, Chen XD (2017) A facile approach toward scalable fabrication of reversible shape-memory polymers with bonded elastomer microphases as internal stress provider. Macromol Rapid Commun 38(16):1700124
17.
Zurück zum Zitat Westbrook KK, Mather PT, Parakh V, Dunn ML, Ge Q, Lee BM, Qi HJ (2011) Two-way reversible shape memory effects in a free-standing polymer composite. Smart Mater Struct 20(6):065010 Westbrook KK, Mather PT, Parakh V, Dunn ML, Ge Q, Lee BM, Qi HJ (2011) Two-way reversible shape memory effects in a free-standing polymer composite. Smart Mater Struct 20(6):065010
18.
Zurück zum Zitat Chen S, Hu J, Zhuo H, Zhu Y (2008) Two-way shape memory effect in polymer laminates. Mater Lett 62(25):4088–4090 Chen S, Hu J, Zhuo H, Zhu Y (2008) Two-way shape memory effect in polymer laminates. Mater Lett 62(25):4088–4090
19.
Zurück zum Zitat Wu Y, Hu J, Han J, Zhu Y, Huang H, Li J, Tang B (2014) Two-way shape memory polymer with “switch-spring” composition by interpenetrating polymer network. J Mater Chem A 2(44):18816–18822 Wu Y, Hu J, Han J, Zhu Y, Huang H, Li J, Tang B (2014) Two-way shape memory polymer with “switch-spring” composition by interpenetrating polymer network. J Mater Chem A 2(44):18816–18822
20.
Zurück zum Zitat Li J, Rodgers WR, Xie T (2011) Semi-crystalline two-way shape memory elastomer. Polymer 52(23):5320–5325 Li J, Rodgers WR, Xie T (2011) Semi-crystalline two-way shape memory elastomer. Polymer 52(23):5320–5325
21.
Zurück zum Zitat Behl M, Kratz K, Noechel U, Sauter T, Lendlein A (2013) Temperature-memory polymer actuators. Proc Natl Acad Sci 110(31):12555–12559PubMed Behl M, Kratz K, Noechel U, Sauter T, Lendlein A (2013) Temperature-memory polymer actuators. Proc Natl Acad Sci 110(31):12555–12559PubMed
22.
Zurück zum Zitat Pandini S, Passera S, Messori M, Paderni K, Toselli M, Gianoncelli A, Bontempi E, Riccò T (2012) Two-way reversible shape memory behaviour of crosslinked poly(ε-caprolactone). Polymer 53(9):1915–1924 Pandini S, Passera S, Messori M, Paderni K, Toselli M, Gianoncelli A, Bontempi E, Riccò T (2012) Two-way reversible shape memory behaviour of crosslinked poly(ε-caprolactone). Polymer 53(9):1915–1924
23.
Zurück zum Zitat Pandini S, Baldi F, Paderni K, Messori M, Toselli M, Pilati F, Gianoncelli A, Brisotto M, Bontempi E, Riccò T (2013) One-way and two-way shape memory behaviour of semi-crystalline networks based on sol–gel cross-linked poly(ε-caprolactone). Polymer 54(16):4253–4265 Pandini S, Baldi F, Paderni K, Messori M, Toselli M, Pilati F, Gianoncelli A, Brisotto M, Bontempi E, Riccò T (2013) One-way and two-way shape memory behaviour of semi-crystalline networks based on sol–gel cross-linked poly(ε-caprolactone). Polymer 54(16):4253–4265
24.
Zurück zum Zitat Hou G, Wang F, Qu Z, Cheng Z, Zhang Y, Cai S, Xie T, Feng X (2018) Reversible semicrystalline polymer as actuators driven by organic solvent vapor. Macromol Rapid Commun 39(7):1700716 Hou G, Wang F, Qu Z, Cheng Z, Zhang Y, Cai S, Xie T, Feng X (2018) Reversible semicrystalline polymer as actuators driven by organic solvent vapor. Macromol Rapid Commun 39(7):1700716
25.
Zurück zum Zitat Gu L, Jiang Y, Hu J (2018) Bioinspired poly(vinyl alcohol)-silk hybrids: two-way water-sensitive shape-memory materials. Mater Today Communications 17:419–426 Gu L, Jiang Y, Hu J (2018) Bioinspired poly(vinyl alcohol)-silk hybrids: two-way water-sensitive shape-memory materials. Mater Today Communications 17:419–426
26.
Zurück zum Zitat Lai S-M, Guo G-L (2019) Two-way shape memory effects of sulfur vulcanized natural rubber (NR) and NR/paraffin wax (PW)/carbon nanotube (CNT) nanocomposites. Polym Test 77:105892 Lai S-M, Guo G-L (2019) Two-way shape memory effects of sulfur vulcanized natural rubber (NR) and NR/paraffin wax (PW)/carbon nanotube (CNT) nanocomposites. Polym Test 77:105892
27.
Zurück zum Zitat Wee JS-H, Chai AB, Ho J-H (2017) Fabrication of shape memory natural rubber using palmitic acid. J King Saud Univ Sci 29(4):494–501 Wee JS-H, Chai AB, Ho J-H (2017) Fabrication of shape memory natural rubber using palmitic acid. J King Saud Univ Sci 29(4):494–501
28.
Zurück zum Zitat Lin GY, Liu SM, Dong FC (2014) Study on shape-memory mechanism and properties of NR/TPI blends. Appl Mech Mater 467:146–151 Lin GY, Liu SM, Dong FC (2014) Study on shape-memory mechanism and properties of NR/TPI blends. Appl Mech Mater 467:146–151
29.
Zurück zum Zitat Yuan D, Chen Z, Xu C, Chen K, Chen Y (2015) Fully biobased shape memory material based on novel cocontinuous structure in poly(lactic acid)/natural rubber TPVs fabricated via peroxide-induced dynamic vulcanization and in situ interfacial compatibilization. ACS Sustain Chem Eng 3(11):2856–2865 Yuan D, Chen Z, Xu C, Chen K, Chen Y (2015) Fully biobased shape memory material based on novel cocontinuous structure in poly(lactic acid)/natural rubber TPVs fabricated via peroxide-induced dynamic vulcanization and in situ interfacial compatibilization. ACS Sustain Chem Eng 3(11):2856–2865
30.
Zurück zum Zitat Brostowitz NR, Weiss RA, Cavicchi KA (2014) Facile fabrication of a shape memory polymer by swelling cross-linked natural rubber with stearic acid. ACS Macro Lett 3(4):374–377 Brostowitz NR, Weiss RA, Cavicchi KA (2014) Facile fabrication of a shape memory polymer by swelling cross-linked natural rubber with stearic acid. ACS Macro Lett 3(4):374–377
31.
Zurück zum Zitat Pantoja M, Lin Z, Cakmak M, Cavicchi KA (2018) Structure–property relationships of fatty acid swollen, crosslinked natural rubber shape memory polymers. J Polym Sci B Polym Phys 56(8):673–688 Pantoja M, Lin Z, Cakmak M, Cavicchi KA (2018) Structure–property relationships of fatty acid swollen, crosslinked natural rubber shape memory polymers. J Polym Sci B Polym Phys 56(8):673–688
32.
Zurück zum Zitat Lai S-M, Guo G-L, Han K-T, Huang P-S, Huang Z-L, Jiang M-J, Zou Y-R (2019) Properties and characterization of near infrared-triggered natural rubber (NR)/carnauba wax (CW)/carbon nanotube (CNT) shape memory bio-nanocomposites. J Polym Res 26:86 Lai S-M, Guo G-L, Han K-T, Huang P-S, Huang Z-L, Jiang M-J, Zou Y-R (2019) Properties and characterization of near infrared-triggered natural rubber (NR)/carnauba wax (CW)/carbon nanotube (CNT) shape memory bio-nanocomposites. J Polym Res 26:86
33.
Zurück zum Zitat Katzenberg F, Heuwers B, Tiller JC (2011) Superheated rubber for cold storage. Adv Mater 23(16):1909–1911PubMed Katzenberg F, Heuwers B, Tiller JC (2011) Superheated rubber for cold storage. Adv Mater 23(16):1909–1911PubMed
34.
Zurück zum Zitat Quitmann D, Dibolik M, Katzenberg F, Tiller JC (2014) Altering the trigger behavior of programmed shape memory natural rubber (SMNR) by solvent vapor. Macromol Mater Eng 300(1):25–30 Quitmann D, Dibolik M, Katzenberg F, Tiller JC (2014) Altering the trigger behavior of programmed shape memory natural rubber (SMNR) by solvent vapor. Macromol Mater Eng 300(1):25–30
35.
Zurück zum Zitat Quitmann D, Reinders FM, Heuwers B, Katzenberg F, Tiller JC (2015) Programming of shape memory natural rubber for near-discrete shape transitions. ACS Appl Mater Interfaces 7(3):1486–1490PubMed Quitmann D, Reinders FM, Heuwers B, Katzenberg F, Tiller JC (2015) Programming of shape memory natural rubber for near-discrete shape transitions. ACS Appl Mater Interfaces 7(3):1486–1490PubMed
36.
Zurück zum Zitat Quitmann D, Gushterov N, Sadowski G, Katzenberg F, Tiller JC (2013) Solvent-sensitive reversible stress-response of shape memory natural rubber. ACS Appl Mater Interfaces 5(9):3504–3507PubMed Quitmann D, Gushterov N, Sadowski G, Katzenberg F, Tiller JC (2013) Solvent-sensitive reversible stress-response of shape memory natural rubber. ACS Appl Mater Interfaces 5(9):3504–3507PubMed
37.
Zurück zum Zitat Heuwers B, Quitmann D, Katzenberg F, Tiller JC (2012) Stress-induced melting of crystals in natural rubber: a new way to tailor the transition temperature of shape memory polymers. Macromol Rapid Commun 33(18):1517–1522PubMed Heuwers B, Quitmann D, Katzenberg F, Tiller JC (2012) Stress-induced melting of crystals in natural rubber: a new way to tailor the transition temperature of shape memory polymers. Macromol Rapid Commun 33(18):1517–1522PubMed
38.
Zurück zum Zitat Heuwers B, Beckel A, Krieger A, Katzenberg F, Tiller JC (2013) Shape-memory natural rubber: an exceptional material for strain and energy storage. Macromol Chem Phys 214(8):912–923 Heuwers B, Beckel A, Krieger A, Katzenberg F, Tiller JC (2013) Shape-memory natural rubber: an exceptional material for strain and energy storage. Macromol Chem Phys 214(8):912–923
39.
Zurück zum Zitat Heuwers B, Quitmann D, Hoeher R, Reinders FM, Tiemeyer S, Sternemann C, Tolan M, Katzenberg F, Tiller JC (2013) Stress-induced stabilization of crystals in shape memory natural rubber. Macromol Rapid Commun 34(2):180–184PubMed Heuwers B, Quitmann D, Hoeher R, Reinders FM, Tiemeyer S, Sternemann C, Tolan M, Katzenberg F, Tiller JC (2013) Stress-induced stabilization of crystals in shape memory natural rubber. Macromol Rapid Commun 34(2):180–184PubMed
40.
Zurück zum Zitat Li G, Zhang H, Fortin D, Fan W, Xia H, Zhao Y (2016) A composite material with room temperature shape processability and optical repair. J Mater Chem C 4(25):5932–5939 Li G, Zhang H, Fortin D, Fan W, Xia H, Zhao Y (2016) A composite material with room temperature shape processability and optical repair. J Mater Chem C 4(25):5932–5939
41.
Zurück zum Zitat Chen S, Zhan Q, Feng J (2017) 3D printing of tunable shape memory polymer blends. J Mater Chem 5(33):8361–8365 Chen S, Zhan Q, Feng J (2017) 3D printing of tunable shape memory polymer blends. J Mater Chem 5(33):8361–8365
42.
Zurück zum Zitat Zhang Q, Feng J (2013) Difunctional olefin block copolymer/paraffin form-stable phase change materials with simultaneous shape memory property. Sol Energy Mater Sol Cells 117:259–266 Zhang Q, Feng J (2013) Difunctional olefin block copolymer/paraffin form-stable phase change materials with simultaneous shape memory property. Sol Energy Mater Sol Cells 117:259–266
43.
Zurück zum Zitat Zhang Q, Hua W, Feng J (2016) A facile strategy to fabricate multishape memory polymers with controllable mechanical properties. Macromol Rapid Commun 37(15):1262–1267PubMed Zhang Q, Hua W, Feng J (2016) A facile strategy to fabricate multishape memory polymers with controllable mechanical properties. Macromol Rapid Commun 37(15):1262–1267PubMed
44.
Zurück zum Zitat Gaillard Y, Mija A, Burr A, Darque-Ceretti E, Felder E, Sbirrazzuoli N (2011) Green material composites from renewable resources: polymorphic transitions, and phase diagram of beeswax/rosin resin. Thermochim Acta 521(1–2):90–97 Gaillard Y, Mija A, Burr A, Darque-Ceretti E, Felder E, Sbirrazzuoli N (2011) Green material composites from renewable resources: polymorphic transitions, and phase diagram of beeswax/rosin resin. Thermochim Acta 521(1–2):90–97
45.
Zurück zum Zitat Kameda T, Tamada Y (2009) Variable-temperature 13 C solid-state NMR study of the molecular structure of honeybee wax and silk. Int J Biol Macromol 44(1):64–69PubMed Kameda T, Tamada Y (2009) Variable-temperature 13 C solid-state NMR study of the molecular structure of honeybee wax and silk. Int J Biol Macromol 44(1):64–69PubMed
46.
Zurück zum Zitat Lee EJ, Park JK, Lee Y-S, Lim K-H (2010) Comparison of thermal properties of crude by-product polyolefin wax, fractionated paraffin wax and their blend. Korean J Chem Eng 27(2):524–530 Lee EJ, Park JK, Lee Y-S, Lim K-H (2010) Comparison of thermal properties of crude by-product polyolefin wax, fractionated paraffin wax and their blend. Korean J Chem Eng 27(2):524–530
47.
Zurück zum Zitat Yang Z, Chen Y, Wang Q, Wang T (2016) High performance multiple-shape memory behaviors of poly(benzoxazole-co-imide)s. Polymer 88:19–28 Yang Z, Chen Y, Wang Q, Wang T (2016) High performance multiple-shape memory behaviors of poly(benzoxazole-co-imide)s. Polymer 88:19–28
48.
Zurück zum Zitat Mohamed MG, Lin R-C, Kuo S-W (2017) In: Ishida H, Froimowicz P (eds) Advanced and emerging polybenzoxazine science and technology1st edn. Esevier Mohamed MG, Lin R-C, Kuo S-W (2017) In: Ishida H, Froimowicz P (eds) Advanced and emerging polybenzoxazine science and technology1st edn. Esevier
49.
Zurück zum Zitat Shih H-K, Hsieh C-C, Mohamed MG, Zhu C-Y, Kuo S-W (2016) Ternary polybenzoxazine/POSS/SWCNT hybrid nanocomposites stabilized through supramolecular interactions. Soft Matter 12(6):1847–1858PubMed Shih H-K, Hsieh C-C, Mohamed MG, Zhu C-Y, Kuo S-W (2016) Ternary polybenzoxazine/POSS/SWCNT hybrid nanocomposites stabilized through supramolecular interactions. Soft Matter 12(6):1847–1858PubMed
50.
Zurück zum Zitat Le HH, Hait S, Das A, Wießner S, Stöckelhuber KW, Böhme F, Reuter U, Naskar K, Heinrich G, H-j R (2017) Self-healing properties of carbon nanotube filled natural rubber/bromobutyl rubber blends. Express Polym Lett 11(3):230–242 Le HH, Hait S, Das A, Wießner S, Stöckelhuber KW, Böhme F, Reuter U, Naskar K, Heinrich G, H-j R (2017) Self-healing properties of carbon nanotube filled natural rubber/bromobutyl rubber blends. Express Polym Lett 11(3):230–242
51.
Zurück zum Zitat Cardinaud R, McNally T (2013) Localization of MWCNTs in PET/LDPE blends. Eur Polym J 49(6):1287–1297 Cardinaud R, McNally T (2013) Localization of MWCNTs in PET/LDPE blends. Eur Polym J 49(6):1287–1297
52.
Zurück zum Zitat Zhang W, Lu P, Qian L, Xiao H (2014) Fabrication of superhydrophobic paper surface via wax mixture coating. Chem Eng J 250:431–436 Zhang W, Lu P, Qian L, Xiao H (2014) Fabrication of superhydrophobic paper surface via wax mixture coating. Chem Eng J 250:431–436
53.
Zurück zum Zitat Zhao P, Li L, Luo Y, Lv Z, Xu K, Li S, Zhong J, Wang Z, Peng Z (2016) Effect of blend ratio on the morphology and electromagnetic properties of nanoparticles incorporated natural rubber blends. Composites Part B 99:216–223 Zhao P, Li L, Luo Y, Lv Z, Xu K, Li S, Zhong J, Wang Z, Peng Z (2016) Effect of blend ratio on the morphology and electromagnetic properties of nanoparticles incorporated natural rubber blends. Composites Part B 99:216–223
54.
Zurück zum Zitat Xiao Y, Zhou S, Wang L, Gong T (2010) Electro-active shape memory properties of poly(ε-caprolactone)/functionalized multiwalled carbon nanotube nanocomposite. ACS Symp Ser 2(12):3506–3514 Xiao Y, Zhou S, Wang L, Gong T (2010) Electro-active shape memory properties of poly(ε-caprolactone)/functionalized multiwalled carbon nanotube nanocomposite. ACS Symp Ser 2(12):3506–3514
55.
Zurück zum Zitat Anthamatten M, Roddecha S, Li J (2013) Energy storage capacity of shape-memory polymers. Macromolecules 46(10):4230–4234 Anthamatten M, Roddecha S, Li J (2013) Energy storage capacity of shape-memory polymers. Macromolecules 46(10):4230–4234
56.
Zurück zum Zitat Birdwell BF, Jessen FW (1966) Crystallization of petroleum waxes. Nature 209:366–368 Birdwell BF, Jessen FW (1966) Crystallization of petroleum waxes. Nature 209:366–368
57.
Zurück zum Zitat Du J, Liu D, Zhang Z, Liu L, Yao X, Wan D, Pu H, Lu Z (2017) Dual-responsive triple-shape memory polyolefin elastomer/stearic acid composite. Polymer 126:206–210 Du J, Liu D, Zhang Z, Liu L, Yao X, Wan D, Pu H, Lu Z (2017) Dual-responsive triple-shape memory polyolefin elastomer/stearic acid composite. Polymer 126:206–210
Metadaten
Titel
A novel multi-triggered natural rubber (NR)/beeswax (BW)/carbon nanotube (CNT) shape memory bio-nanocomposite
verfasst von
Sun-Mou Lai
Geng-Lun Guo
Yi-Cheng Xie
Jian-Ming Chen
Dun-Yu Xu
Yu-En Wei
Zhou-Rong Cao
Publikationsdatum
01.09.2020
Verlag
Springer Netherlands
Erschienen in
Journal of Polymer Research / Ausgabe 9/2020
Print ISSN: 1022-9760
Elektronische ISSN: 1572-8935
DOI
https://doi.org/10.1007/s10965-020-02256-5

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