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Journal of Nanoparticle Research
Erschienen in: Journal of Nanoparticle Research 8/2013

01.08.2013 | Research Paper

A novel thermally stable Eu(III) complex-modified acrylate nano-polymer and its luminescence properties

verfasst von: Lin Xu, Jun Hu, Lei Xu, Taiju Tsuboi, Wei Huang, Hongde Xie

Erschienen in: Journal of Nanoparticle Research | Ausgabe 8/2013

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Abstract

A Eu(III) complex-modified acrylate nano-polymer (Eu(III) complex-MA-np) is synthesized by semi-continuous emulsion polymerization. The organic–inorganic hybrid nanoparticles are characterized by transmission electron microscopy, laser particle size analysis, thermogravimetric analysis (TGA), and differential scanning calorimeter. The nanoparticle size is in a range of 70–170 nm. The optical properties of Eu(III) complex-MA-np are investigated by photoluminescence (PL) and PL excitation spectra, PL decay curve, and CIE chromaticity diagram. The Eu(III) complex-MA-np contains 1,3,5-trimethyltris(3,3,3-trifluoropyropyl)cyclotrisiloxane (D3F), where Eu3+ ions were surrounded by Si–O group through polymer complexation. TGA shows that the Eu(III) complex-MA-np was thermally stable up to 450 °C due to the high bond energy of CF3 units and Si–O bond. The Eu(III) complex-MA-np gives red emission with high color purity, which is excited at 350–450 nm effectively, indicating that the Eu(III) complex-MA-np is a potential red-emitting candidate for thermally stable white-LED nanodevices.
Vorheriger Artikel Mechanisms of nanoclay-enhanced plastic foaming processes: effects of nanoclay intercalation and exfoliation
Nächster Artikel Structural investigations on differently sized monodisperse iron oxide nanoparticles synthesized by remineralization of apoferritin molecules

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Metadaten
Titel
A novel thermally stable Eu(III) complex-modified acrylate nano-polymer and its luminescence properties
verfasst von
Lin Xu
Jun Hu
Lei Xu
Taiju Tsuboi
Wei Huang
Hongde Xie
Publikationsdatum
01.08.2013
Verlag
Springer Netherlands
Erschienen in
Journal of Nanoparticle Research / Ausgabe 8/2013
Print ISSN: 1388-0764
Elektronische ISSN: 1572-896X
DOI
https://doi.org/10.1007/s11051-013-1817-9

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