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Erschienen in: Polymer Bulletin 7/2019

08.10.2018 | Original Research

A photochromic waterborne polyurethane-based dye with chemically fixed azobenzene groups

verfasst von: Xianhai Hu, Xiang Liu, Manli Liu, Gen Li, Congliang Cheng

Erschienen in: Polymer Bulletin | Ausgabe 7/2019

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Abstract

A photochromic waterborne polyurethane-based dye with azobenzene groups WPU-DDB-3BF was prepared by incorporating Disperse Diazo Black 3BF (DDB-3BF, CAS: 6232-57-1) into the polyurethane chain according to a modified acetone process. The expected structure of WPU-DDB-3BF was characterized by FT-IR, Raman and UV–Vis spectra. Containing the well-known dye of azobenzene groups, WPU-DDB-3BF exhibits a slow photochromic process. Compared with DDB-3BF, the isomerization time of WPU-DDB-3BF has obviously grown longer. The improved thermal stability of WPU-DDB-3BF is ascribed to the attachment of azobenzene units to polyurethane backbone chains. The polyester fibers dyed with WPU-DDB-3BF show high color yield (K/S), outstanding breaking strength retention, excellent breathability and strong wrinkle resistance. From the experimental results, WPU-DDB-3BF possesses outstanding photochromism and dyeing performance.

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Metadaten
Titel
A photochromic waterborne polyurethane-based dye with chemically fixed azobenzene groups
verfasst von
Xianhai Hu
Xiang Liu
Manli Liu
Gen Li
Congliang Cheng
Publikationsdatum
08.10.2018
Verlag
Springer Berlin Heidelberg
Erschienen in
Polymer Bulletin / Ausgabe 7/2019
Print ISSN: 0170-0839
Elektronische ISSN: 1436-2449
DOI
https://doi.org/10.1007/s00289-018-2552-2

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