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Metallurgical and Materials Transactions B
Erschienen in: Metallurgical and Materials Transactions B 1/2021

27.10.2020

A Sustainable Approach for Producing Ti and TiS2 from TiC

verfasst von: Eltefat Ahmadi, Ryosuke o. Suzuki, Takumi Kaneko, Tatsuya Kikuchi

Erschienen in: Metallurgical and Materials Transactions B | Ausgabe 1/2021

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Abstract

TiC was examined as a starting material for Ti metal production by sulfidation and electrochemical reduction in molten salt. The sulfur evaporation temperature, sulfidation temperature, and time were optimized in a dual-zone furnace for the efficient and sustainable formation of TiS2 as well as carbon removal from TiC by S2 gas sulfidation. A mixture of TiS2 and Ti2.45S4 powders was synthesized from TiC at 1200 °C, and a perfect carbon removal was achieved to a very clean level as low as 0.025 mass pct C. The sulfides derived from TiC were then electrochemically reduced in molten CaCl2-0.5 mol pct CaS salt. The spherical shape Ti powder consisting of high-purity Ti sheets was obtained from TiS2 without the carbon contamination. This method might be applied for sustainable recycling of waste carbides and for production of low-cost Ti powders via TiC or TiOxCyNz from the titanium ore.
Vorheriger Artikel Effect of Ternary Basicity of Iron Ore-Fluxed Pellets on Melting and Softening Properties in a Blast Furnace
Nächster Artikel Changes of Effective Binary Diffusivity of Silica and Viscosity of Silicomanganese Slag in the Process of Reduction of MnO and SiO2

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Fußnoten
1
JEOL is a trademark of Japan Electron Optics Ltd., Tokyo.
 
2
LECO is a trademark of LECO Corporation, St. Joseph, MI.
 
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Metadaten
Titel
A Sustainable Approach for Producing Ti and TiS2 from TiC
verfasst von
Eltefat Ahmadi
Ryosuke o. Suzuki
Takumi Kaneko
Tatsuya Kikuchi
Publikationsdatum
27.10.2020
Verlag
Springer US
Erschienen in
Metallurgical and Materials Transactions B / Ausgabe 1/2021
Print ISSN: 1073-5615
Elektronische ISSN: 1543-1916
DOI
https://doi.org/10.1007/s11663-020-01988-5

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