nach oben

Cellulose

Erschienen in:

18.09.2020 | Original Research

A synergistic flame retardant of glycosyl cross-linking boron acid and ammonium salt of phytic acid to enhance durable flame retardancy of cotton fabrics

verfasst von: Wenju Zhu, Shuaishuai Hao, Mingyang Yang, Bowen Cheng, Jimei Zhang

Erschienen in: Cellulose | Ausgabe 16/2020

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config

KI-gestützte Suche

Aus

Abstract

In the present research, a glycosyl cross-linking coordination chelate flame retardant was designed to enhance durable flame retardancy of cotton fabrics. It was a halogen-free, non-formaldehyde boron acid and phytic acid ammonium salt synergistic flame-retardant system. The flame retardancy and durability of flame retardants prepared by different saccharides were investigated. Results showed that raffinose was the best cross-linking reagent compared with the other monosaccharides and oligosaccharides. The raffinose as cross-linking reagent prepared glycosyl cross-linking boron acid and ammonium salt of phytic acid flame retardant (r-GBAP) (100 g/L) can obtain the shortest char length of 56 mm and the largest limiting oxygen index (LOI) value of 37.4%. A lower r-GBAP concentration can get good flame retardancy, due to adopt the three curing cycles process. FTIR, XPS, LOI, TG and SEM testing and characterization techniques were used to analyze and research the flame retardancy, durability, thermal oxidation stability and flame-retardant mechanisms of r-GBAP and the treated cotton fibers.

Graphic abstract

Vorheriger Artikel A theoretical model to investigate the performance of cellulose yarns constrained to lie on a moving solid cylinder

Nächster Artikel Bioactive emulsions with beneficial antimicrobial application in textile material production

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

über 67.000 Bücher
über 390 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Maschinenbau + Werkstoffe

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

über 102.000 Bücher
über 537 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Finance + Banking
Management + Führung
Marketing + Vertrieb
Maschinenbau + Werkstoffe
Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Alongi J, Carletto RA, Di Blasio A, Cuttica F, Carosio F, Bosco F, Malucelli G (2013) Intrinsic intumescent-like flame retardant properties of DNA-treated cotton fabrics. Carbohydr Polym 96(1):296–304. https://doi.org/10.1016/j.carbpol.2013.03.066CrossRefPubMed

Alongi J, Malucelli G (2015) Cotton flame retardancy: state of the art and future perspectives. RSC Adv 5:24239–24263. https://doi.org/10.1039/C5RA01176KCrossRef

Chan SY, Si L, Lee KI, Ng PF, Chen L, Yu B, Hu Y, Yuen RKK, Xin JH, Fei B (2018) A novel boron–nitrogen intumescent flame retardant coating on cotton with improved washing durability. Cellulose 25(1):843–857. https://doi.org/10.1007/s10570-017-1577-2CrossRef

Chirico AD, aArmanini M, Chini P, Cioccolo G,Provasoli F, Audisio G (2003) Flame retardants for polypropylene based on lignin. Polym Degrad Stab 79(1):139–145. https://doi.org/10.1016/S0141-3910(02)00266-5CrossRef

Choi K, Seo S, Kwon H, Kim D, Park YT (2018) Fire protection behavior of layer-by-layer assembled starch-clay multilayers on cotton fabric. J Mater Sci 53(16):11433–11443. https://doi.org/10.1007/s10853-018-2434-xCrossRef

Costes L, Laoutid F, Brohez S, Dubois P (2017) Bio-based flame retardants: when nature meets fire protection. Mater Sci Eng R 117:1–25. https://doi.org/10.1016/j.mser.2017.04.001CrossRef

Dorez G, Taguet A, Ferry L, Lopez-Cuesta JM (2013) Thermal and fire behavior of natural fibers/PBS biocomposites. Polym Degrad Stab 98(1):87–95. https://doi.org/10.1016/j.polymdegradstab.2012.10.026CrossRef

French AD (2017) Glucose, not cellobiose, is the repeating unit of cellulose and why that is important. Cellulose 24(11):4605–4609CrossRef

Guo D, Ding B, Hu X, Wang Y, Han F, Wu X (2018) Synthesis of boron and nitrogen codoped porous carbon foam for high performance supercapacitors. ACS Sustain Chem Eng 6(9):11441–11449CrossRef

Horrocks AR (2011) Flame retardant challenges for textiles and fibers: new chemistry versus innovatory solutions. Polym Degrad Stab 96(3):377–392. https://doi.org/10.1016/j.polymdegradstab.2010.03.036CrossRef

Hill V, Howell B, Daniel Y (2017) Oligomeric flame retardants for polymeric materials from itaconic acid. In: Abstracts of papers of the American chemical society, Washington, DC, USA

Himmel HJ (2015) Urea azines (bisguanidines): electronic structure, redox properties, and coordination chemistry. Eur J Inorg Chem 13:2345–2361

James TD, Phillips MD, Shinkai S (2006) Boronic acids in saccharide recognition, vol 9. Royal Society of Chemistry, Cambridge

Jia Y, Lu Y, Zhang G, Liang Y, Zhang F (2017) Facile synthesis of an eco-friendly nitrogen–phosphorus ammonium salt to enhance the durability and flame retardancy of cotton. J Mater Chem A 5(20):9970–9981. https://doi.org/10.1039/C7TA01106GCrossRef

Kayser H, Rodríguez-Ropero F, Leitner W, Fioroni M, de María PD (2013) Mechanistic comparison of saccharide depolymerization catalyzed by dicarboxylic acids and glycosidases. RSC Adv 3:9273–9278. https://doi.org/10.1039/C3RA41307ACrossRef

Kundu CK, Wang X, Song L, Hu Y (2018) Borate cross-linked layer-by-layer assembly of green polyelectrolytes on polyamide 66 fabrics for flame-retardant treatment. Prog Org Coat 121:173–181. https://doi.org/10.1016/j.porgcoat.2018.04.031CrossRef

Laufer G, Kirkland C, Morgan AB, Grunlan JC (2012) Intumescent multilayer nanocoating, made with renewable polyelectrolytes, for flame-retardant cotton. Biomacromolecules 13(9):2843–2848. https://doi.org/10.1021/bm300873bCrossRefPubMed

Li P, Wang B, Xu Y-J, Jiang Z, Dong C, Liu Y, Zhu P (2019) Ecofriendly flame-retardant cotton fabrics: preparation, flame retardancy, thermal degradation properties, and mechanism. ACS Sustain Chem Eng 7:19246–19256. https://doi.org/10.1021/acssuschemeng.9b05523CrossRef

Li YC et al (2010) Flame retardant behavior of polyelectrolyte-clay thin film assemblies on cotton fabric. ACS Nano 4(6):3325–3337. https://doi.org/10.1021/nn100467eCrossRefPubMed

Liu L, Pan Y, Wang Z, Hou Y, Gui Z, Hu Y (2017) Layer-by-layer assembly of hypophosphorous acid-modified chitosan based coating for flame-retardant polyester-cotton blends. Ind Eng Chem Res 56(34):9429–9436. https://doi.org/10.1021/acs.iecr.7b02303CrossRef

Liu X-H, Zhang Q-Y, Cheng B-W, Ren Y-L, Zhang Y-G, Ding C (2018) Durable flame retardant cellulosic fibers modified with novel, facile and efficient phytic acid-based finishing agent. Cellulose 25(15):799–811. https://doi.org/10.1007/s10570-017-1550-0CrossRef

Luo C, Zuo J, Wang F, Lin F, Xu Z (2018) Click chemistry-assisted preparation and properties of phosphorus and nitrogen synergistic flame retardant optical resin with a high refractive index. J Appl Polym Sci 135(38):46648. https://doi.org/10.1002/app.46648CrossRef

Maleki M, Beitollahi A, Leeb J, Shokouhimehrc M, Javadpoura J, Parkd EJ, Chunb J, Hwang J (2015) One pot synthesis of mesoporous boron nitride using polystyrene-b-poly (ethylene oxide) block copolymer. RSC Adv 5(9):6528–6535. https://doi.org/10.1039/c4ra11431kCrossRef

Ortelli S, Malucelli G, Blosi M, Zanoni I, Costa AL (2019) NanoTiO2@ DNA complex: a novel eco, durable, fire retardant design strategy for cotton textiles. J Colloid Interface Sci 546:174–183. https://doi.org/10.1016/j.jcis.2019.03.055CrossRefPubMed

Pan H, Song L, Ma L, Pan Y, Liew KM, Hu Y (2014) Layer-by-layer assembled thin films based on fully biobased polysaccharides: chitosan and phosphorylated cellulose for flame-retardant cotton fabric. Cellulose 21(4):2995–3006. https://doi.org/10.1007/s10570-014-0276-5CrossRef

Pandimurugan R, Thambidurai S (2017) UV protection and antibacterial properties of seaweed capped ZnO nanoparticles coated cotton fabrics. Int J Biol Macromol 105:788–795. https://doi.org/10.1016/j.ijbiomac.2017.07.097CrossRefPubMed

Rosace G, Castellano A, Trovato V, Iacono G, Malucelli G (2018) Thermal and flame retardant behaviour of cotton fabrics treated with a novel nitrogen-containing carboxyl-functionalized organophosphorus system. Carbohydr Polym 196(15):348–358. https://doi.org/10.1016/j.carbpol.2018.05.012CrossRefPubMed

Rovira J, Domingo JL (2019) Human health risks due to exposure to inorganic and organic chemicals from textiles: a review. Environ Res 168:62–69. https://doi.org/10.1016/j.envres.2018.09.027CrossRefPubMed

Sanjay M, Arpitha G, Naik LL, Gopalakrishna K, Yogesha B (2016) Applications of natural fibers and its composites: an overview. Nat Resour 7(3):108–114. https://doi.org/10.4236/nr.2016.73011CrossRef

Shao Z-B, Deng C, Tan Y, Chen M-J, Chen L, Wang Y-Z (2014) An efficient mono-component polymeric intumescent flame retardant for polypropylene: preparation and application. ACS Appl Mater Interfaces 6(10):7363–7370. https://doi.org/10.1021/am500789qCrossRefPubMed

Silva-Santos MC, Oliveira MS, Giacomin AM, Laktim MC, Baruque-Ramos J (2017) Flammability on textile of business uniforms: use of natural fibers. Procedia Eng 200:148–154. https://doi.org/10.1016/j.proeng.2017.07.022CrossRef

Veerappagounder S, Nalankilli G, Shanmugasundaram O (2016) Study on properties of cotton fabric incorporated with diammonium phosphate flame retardant through cyclodextrin and 1,2,3,4-butane tetracarboxylic acid binding system. J Ind Text 45(6):1204–1220. https://doi.org/10.1177/1528083714555780CrossRef

Wang L, Sánchez-Soto M, Fan J, Xia Ze, Liu Y (2019) Boron/nitrogen flame retardant additives cross-linked cellulose nanofibril/montmorillonite aerogels toward super-low flammability and improved mechanical properties. Polym Adv Technol 30(7):1807–1817. https://doi.org/10.1002/pat.4613CrossRef

Wang N, Liu YS, Xu CG, Liu Y, Wang Q (2017) Acid-base synergistic flame retardant wood pulp paper with high thermal stability. Carbohydr Polym 178:123–130. https://doi.org/10.1016/j.carbpol.2017.08.099CrossRefPubMed

Wu W, Yang CQ (2006) Comparison of different reactive organophosphorus flame retardant agents for cotton: part I. The bonding of the flame retardant agents to cotton. Polym Degrad Stab 91(11):2541–2548. https://doi.org/10.1016/j.polymdegradstab.2006.05.010CrossRef

Xu F, Zhong L, Zhang C, Wang P, Zhang F, Zhang G (2019) Novel high-efficiency casein-based P–N-containing flame retardants with multiple reactive groups for cotton fabrics. ACS Sustain Chem Eng 7(16):13999–14008. https://doi.org/10.1021/acssuschemeng.9b02474CrossRef

Yang CQ, Wu W, Xu Y (2005) The combination of a hydroxy-functional organophosphorus oligomer and melamine-formaldehyde as a flame retarding finishing system for cotton. Fire Mater 29(2):109–120. https://doi.org/10.1002/fam.877CrossRef

Yang H, Yang CQ (2016) Nonformaldehyde flame retardant finishing of the nomex/cotton blend fabric using a hydroxy-functional organophosphorus oligomer. J Fire Sci 25:425–446. https://doi.org/10.1177/0734904107078069CrossRef

Yang S, Hu Y, Zhang Q (2019) Synthesis of a phosphorus–nitrogen-containing flame retardant and its application in epoxy resin. High Perform Polym 31(2):186–196. https://doi.org/10.1177/0954008318756496CrossRef

Zhang S, Horrocks AR (2003) Substantive intumescence from phosphorylated 1,3-propanediol derivatives substituted on to cellulose. J Appl Polym Sci 90(12):3165–3172. https://doi.org/10.1002/app.12733CrossRef

Zhang X, Sühring R, Serodio D, Bonnell M, Sundin N, Diamond ML (2016) Novel flame retardants: estimating the physical–chemical properties and environmental fate of 94 halogenated and organophosphate PBDE replacements. Chemosphere 144:2401–2407. https://doi.org/10.1016/j.chemosphere.2015.11.017CrossRefPubMed

Zheng D, Zhou J, Zhong L, Zhang F, Zhang G (2016) A novel durable and high-phosphorous-containing flame retardant for cotton fabrics. Cellulose 23:2211–2220. https://doi.org/10.1007/s10570-016-0949-3CrossRef

Zhu WJ, Yang MY, Huang H, Dai Z, Cheng BW, Hao SS (2020) A phytic acid-based chelating coordination embedding structure of phosphorus–boron–nitride synergistic flame retardant to enhance durability and flame retardancy of cotton. Cellulose 27:4817–4829. https://doi.org/10.1007/s10570-020-03063-3CrossRef

Titel: A synergistic flame retardant of glycosyl cross-linking boron acid and ammonium salt of phytic acid to enhance durable flame retardancy of cotton fabrics
verfasst von: Wenju Zhu
Shuaishuai Hao
Mingyang Yang
Bowen Cheng
Jimei Zhang
Publikationsdatum: 18.09.2020
Verlag: Springer Netherlands
Erschienen in: Cellulose / Ausgabe 16/2020
Print ISSN: 0969-0239
Elektronische ISSN: 1572-882X
DOI: https://doi.org/10.1007/s10570-020-03417-x

Springer Professional

Abstract

Graphic abstract

Bitte loggen Sie sich ein, um Zugang zu Ihrer Lizenz zu erhalten.

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Technik"

Springer Professional "Wirtschaft+Technik"

Weitere Artikel der Ausgabe 16/2020

Drainage of high-consistency fiber-laden aqueous foams

Nanocellulose from fractionated sulfite wood pulp

Cellulose dissolution and regeneration using a non-aqueous, non-stoichiometric protic ionic liquid system

MRI visualization of shiitake mycelium growing in logs in order to support shiitake mushroom log cultivation

Cellulose nanofibril/polypyrrole hybrid aerogel supported form-stable phase change composites with superior energy storage density and improved photothermal conversion efficiency

Exploring the innovation landscape of bamboo fiber technologies from global patent data perspective