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Journal of Materials Science
Erschienen in: Journal of Materials Science 23/2017

14.08.2017 | Biomaterials

A thin PANI and carrageenan–gold nanoparticle film on a flexible gold electrode as a conductive and low-cost platform for sensing in a physiological environment

verfasst von: Emanuel Airton de Oliveira Farias, Silvania Siqueira Nogueira, Aline Márcia de Oliveira Farias, Monialine Sousa de Oliveira, Maria de Fátima Cardoso Soares, Helder Nunes da Cunha, José Ribeiro dos Santos Junior, Durcilene Alves da Silva, Peter Eaton, Carla Eiras

Erschienen in: Journal of Materials Science | Ausgabe 23/2017

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Abstract

In this work, we report the production of a layer-by-layer (LbL) film of gold nanoparticles stabilized with carrageenan (carr-AuNPs) interspersed with a conductive polyaniline (PANI) layer. Conventionally, PANI has poor electroactivity in physiological buffers, limiting its using in electrochemical biosensors. The films were prepared on low cost and easy to manufacture flexible gold electrodes (FEAu). Two adsorption sequences were tested for production of the films—PANI/carr-AuNP and carr-AuNP/PANI. The gold nanoparticle size and colloidal stability were characterized. The films were characterized by cyclic voltammetry, UV–visible spectroscopy and atomic force microscopy. The results showed the synergistic effects of the carr-AuNPs (120 nm) and PANI, which improved both the electrochemical response and the stability of the conductive polymer in physiological medium by three times. The presence of the carr-AuNPs in the film caused a significant increase in roughness of the FEAu-modified electrode compared to that of an unmodified electrode, resulting in an increased active electrode area. Studies of film growth by UV–Vis spectroscopy indicated that the deposition mechanisms of both films involved an auto-regulating adsorption process, with the same amount of material adsorbed in each coating step. The PANI/carr-AUNP film showed considerable improvement in stability and conductivity compared to PANI-only films in the physiological environment, which confers advantages for use as a biosensor.
Vorheriger Artikel RGD-conjugated titanium dioxide nanoparticles: targeted near-infrared photothermal therapy for αvβ3 integrin overexpressed cancer cells
Nächster Artikel Hydrochar as protein support: preservation of biomolecule properties with non-covalent immobilization

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Metadaten
Titel
A thin PANI and carrageenan–gold nanoparticle film on a flexible gold electrode as a conductive and low-cost platform for sensing in a physiological environment
verfasst von
Emanuel Airton de Oliveira Farias
Silvania Siqueira Nogueira
Aline Márcia de Oliveira Farias
Monialine Sousa de Oliveira
Maria de Fátima Cardoso Soares
Helder Nunes da Cunha
José Ribeiro dos Santos Junior
Durcilene Alves da Silva
Peter Eaton
Carla Eiras
Publikationsdatum
14.08.2017
Verlag
Springer US
Erschienen in
Journal of Materials Science / Ausgabe 23/2017
Print ISSN: 0022-2461
Elektronische ISSN: 1573-4803
DOI
https://doi.org/10.1007/s10853-017-1438-2

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