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Colloid and Polymer Science
Erschienen in: Colloid and Polymer Science 4/2017

01.03.2017 | Original Contribution

Adhesive and self-healing soft gel based on metal-coordinated imidazole-containing polyaspartamide

verfasst von: Ngoc Bich Tran, Jong Ryul Moon, Young Sil Jeon, Jaeyun Kim, Ji-Heung Kim

Erschienen in: Colloid and Polymer Science | Ausgabe 4/2017

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Abstract

A supramolecular gel formed by coordination of Ni(II) with poly(2-hydroxyethyl-co-1-(3-imidazolyl)propyl aspartamide) (PHEA-API) is reported. Novel polyaspartamide copolymers, PHEA-API, were prepared from polysuccinimide, which is the thermal polycondensation product of aspartic acid, via a successive ring-opening reaction using 1-(3-aminopropyl imidazole) (API) and ethanolamine (EA). Ni(II)-mediated gels, cross-linked by metal–ligand coordination, showed self-healing viscoelastic behavior in rheological analysis, which was also well reflected in high bulk adhesion strength on various different substrates. The approach described here results in a promising self-healing adhesive hydrogel with potential for a variety of industrial and biomedical applications including tissue adhesive, sealant, and smart drug delivery systems.
Vorheriger Artikel Weibull statistics of lap-shear strength development at partially self-healed polymer-polymer interfaces: a short-term contact
Nächster Artikel Tuning the morphology, network structure, and degradation of thermo-sensitive microgels by controlled addition of degradable cross-linker

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Metadaten
Titel
Adhesive and self-healing soft gel based on metal-coordinated imidazole-containing polyaspartamide
verfasst von
Ngoc Bich Tran
Jong Ryul Moon
Young Sil Jeon
Jaeyun Kim
Ji-Heung Kim
Publikationsdatum
01.03.2017
Verlag
Springer Berlin Heidelberg
Erschienen in
Colloid and Polymer Science / Ausgabe 4/2017
Print ISSN: 0303-402X
Elektronische ISSN: 1435-1536
DOI
https://doi.org/10.1007/s00396-017-4051-7

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