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Adsorption
Erschienen in: Adsorption 4/2019

16.04.2019

Adsorption characteristics of light gases on basalt rock-based zeolite 4A

verfasst von: Kyung-Jun Hwang, Min Jin Hwang, M. S. Balathanigaimani, Kathy Nwe, Yongjoon Youn, Won-Seok Choi, Hyun-A Kim, Jae Woon Nah, Wang Geun Shim

Erschienen in: Adsorption | Ausgabe 4/2019

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Abstract

The adsorption characteristics of light gases on basalt rock-based zeolite 4A (BR zeolite-4A) were systematically investigated to evaluate its potential application as an alternative adsorbent for adsorption-based separation processes. We used alkali fusion and hydrothermal procedure to prepare the nanostructured adsorbent, BR zeolite-4A, which was characterized with field emission scanning electron microscopy, X-ray diffraction, and carbon dioxide adsorption apparatus. The single component adsorption equilibrium for CO2, CH4, N2 and H2 on the BR zeolite-4A was volumetrically determined using a nanoPOROSITY adsorption analyzer at the temperature range from (288.15 to 308.15) K and pressure range from (0.1 to 110) kPa. The experimental results indicate that BR zeolite-4A showed higher adsorption capacities for CO2 compared to other light gases, indicating the suitable porous material for selective separation by adsorption. Three different isotherm equations, Langmuir, Toth, and Sips, were used to correlate the adsorption isotherm data and the most reasonable results obtained from the Sips model irrespective of the adsorption isotherm types. Isosteric heat of adsorption and adsorption energy distribution function values were calculated and used to further examine the surface energetic heterogeneity of BR zeolite-4A. The pure component adsorption isotherm results were also used to predict the adsorption selectivity for CO2/N2, CO2/CH4, CO2/H2, and CH4/H2 binary mixtures (50:50) at different pressure ranges using ideal adsorbed solution theory.
Vorheriger Artikel Adsorption of toxic gases on molecularly imprinted polymer coated QCM: measurements and modeling for partial pressure in gas mixture
Nächster Artikel n-Hexane conversion on γ-alumina supported palladium–platinum catalysts

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Metadaten
Titel
Adsorption characteristics of light gases on basalt rock-based zeolite 4A
verfasst von
Kyung-Jun Hwang
Min Jin Hwang
M. S. Balathanigaimani
Kathy Nwe
Yongjoon Youn
Won-Seok Choi
Hyun-A Kim
Jae Woon Nah
Wang Geun Shim
Publikationsdatum
16.04.2019
Verlag
Springer US
Erschienen in
Adsorption / Ausgabe 4/2019
Print ISSN: 0929-5607
Elektronische ISSN: 1572-8757
DOI
https://doi.org/10.1007/s10450-019-00086-6

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