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Metallurgical and Materials Transactions B
Erschienen in: Metallurgical and Materials Transactions B 1/2013

01.02.2013

Al-Cd Alloy Formation by Aluminum Underpotential Deposition from AlCl3+NaCl Melts on Cadmium Substrate

verfasst von: Niko Jovićević, Vesna S. Cvetković, Željko J. Kamberović, Jovan N. Jovićević

Erschienen in: Metallurgical and Materials Transactions B | Ausgabe 1/2013

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Abstract

Aluminum was incorporated into a polycrystalline cadmium electrode surface by underpotential deposition from equimolar AlCl3+ NaCl melt at 473 K, 523 K, and 573 K (200 °C, 250 °C, and 300 °C). The process was studied by linear sweep voltammetry and potentiostatic deposition/galvanostatic striping. The deposits were characterized X-ray diffraction (XRD), Auger electron spectroscopy (AES), and electron probe microanalyzer (EPMA). The electrochemical measurements showed evidence of Cd-Al alloys being formed but they could not be identified. The growth kinetics of the Cd-Al layers of various proportion and depths that depended on temperature and deposition time were described.
Vorheriger Artikel Limestone Dissolution in Converter Slag at 1873 K (1600 °C)
Nächster Artikel Novel Process for Solid State Reduction of Metal Oxides and Hydroxides

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Metadaten
Titel
Al-Cd Alloy Formation by Aluminum Underpotential Deposition from AlCl3+NaCl Melts on Cadmium Substrate
verfasst von
Niko Jovićević
Vesna S. Cvetković
Željko J. Kamberović
Jovan N. Jovićević
Publikationsdatum
01.02.2013
Verlag
Springer US
Erschienen in
Metallurgical and Materials Transactions B / Ausgabe 1/2013
Print ISSN: 1073-5615
Elektronische ISSN: 1543-1916
DOI
https://doi.org/10.1007/s11663-012-9750-3

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