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Erschienen in: Journal of Materials Engineering and Performance 12/2013

01.12.2013

Aluminum Pitting Corrosion in Halide Media: A Quantum Model and Empirical Evidence

verfasst von: Mohsen Lashgari, Effat Kianpour, Esmaeil Mohammadi

Erschienen in: Journal of Materials Engineering and Performance | Ausgabe 12/2013

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Abstract

The phenomenon of localized damage of aluminum oxide surface in the presence of halide anions was scrutinized at an atomistic level, through the cluster approach and density functional theory. The phenomenon was also investigated empirically through Tafel polarization plots and scanning electron microscopy. A distinct behavior witnessed in the fluoride medium was justified through the hard-soft acid-base principle. The atomistic investigations revealed the greatest potency for chloride entrance into the metal oxide lattice and rationalized to the severity of damage. The interaction of halide anions with the oxide surface causing some displacements on the position of Al atoms provides a mechanistic insight of the phenomenon.

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Metadaten
Titel
Aluminum Pitting Corrosion in Halide Media: A Quantum Model and Empirical Evidence
verfasst von
Mohsen Lashgari
Effat Kianpour
Esmaeil Mohammadi
Publikationsdatum
01.12.2013
Verlag
Springer US
Erschienen in
Journal of Materials Engineering and Performance / Ausgabe 12/2013
Print ISSN: 1059-9495
Elektronische ISSN: 1544-1024
DOI
https://doi.org/10.1007/s11665-013-0669-x

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