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Journal of Nanoparticle Research

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01.02.2013 | Research Paper

Amorphous dysprosium carbonate: characterization, stability, and crystallization pathways

verfasst von: Beatriz Vallina, Juan Diego Rodriguez-Blanco, Andrew P. Brown, Jesus A. Blanco, Liane G. Benning

Erschienen in: Journal of Nanoparticle Research | Ausgabe 2/2013

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Abstract

The crystallization of amorphous dysprosium carbonate (ADC) has been studied in air (21–750 °C) and in solution (21–250 °C). This poorly ordered precursor, Dy₂(CO₃)₃·4H₂O, was synthesized in solution at ambient temperature. Its properties and crystallization pathways were studied by powder X-ray diffraction, Fourier transform infrared spectroscopy, scanning and transmission electron microscopy, thermogravimetric analysis, and magnetic techniques. ADC consists of highly hydrated spherical nanoparticles of 10–20 nm diameter that are exceptionally stable under dry treatment at ambient and high temperatures (<550 °C). However, ADC transforms in solution to a variety of Dy-carbonates, depending on the temperature and reaction times. The transformation sequence is (a) poorly crystalline metastable tengerite-type phase, Dy₂(CO₃)₃·2–3H₂O; and (b) the orthorhombic kozoite-type phase DyCO₃(OH) at 165 °C after prolonged times (15 days) or faster (12 h) at 220 °C. Both the amorphous phase and the kozoite-type phase DyCO₃(OH) are paramagnetic in the range of temperatures measured from 1.8 to 300 K.

Vorheriger Artikel Size dependence study of the ordering temperature in the Fast Monte Carlo method

Nächster Artikel On the observation of the need for an unusually high concentration of cysteine and homocysteine to induce aggregation of polymer-stabilized gold nano particles

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Titel: Amorphous dysprosium carbonate: characterization, stability, and crystallization pathways
verfasst von: Beatriz Vallina
Juan Diego Rodriguez-Blanco
Andrew P. Brown
Jesus A. Blanco
Liane G. Benning
Publikationsdatum: 01.02.2013
Verlag: Springer Netherlands
Erschienen in: Journal of Nanoparticle Research / Ausgabe 2/2013
Print ISSN: 1388-0764
Elektronische ISSN: 1572-896X
DOI: https://doi.org/10.1007/s11051-013-1438-3

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