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Journal of Polymer Research

Erschienen in:

01.09.2017 | ORIGINAL PAPER

An antibacterial composite system based on multi-responsive microgels hosting monodisperse gold nanoparticles

verfasst von: Damla Ulker, Cansel Tuncer, Serife B. Sezgin, Yagmur Toptas, Ahmet Cabuk, Vural Bütün

Erschienen in: Journal of Polymer Research | Ausgabe 10/2017

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Abstract

A multi-responsive microgel having response to pH, temperature, and salt concentration was successfully prepared using a water-soluble monomer. Microgels were readily prepared from 2-(N-morpholino)ethyl methacrylate (MEMA) via emulsion polymerization using glycidyl methacrylate as a comonomer cross-linker. The morpholino groups of MEMA residues of microgels were able to give complexation with metal containing anions such as AuCl₄ ⁻ in acidic conditions. The reduction of aurate ions with sodium borohydride led to immobilized-gold nanoparticles (AuNP) in the microgel system. Average particle diameters of AuNPs were determined to be 10 ± 2 nm. The resulting AuNP-microgel system was examined as a nanoreactor for catalyst system and determined to be very effective in the reduction of 4-nitrophenol model reaction in aqueous media. AuNPs-microgel composite system had antibacterial properties against several Gram-positive and Gram-negative bacteria similar to amoxicillin. This P(MEMA-co-GMA) microgel is also very useful for different applications such as a host for metal nanoparticle production, a drug carrier or drug delivery system.

Vorheriger Artikel Structure-property relations of novel polyamide-6 elastomers prepared through reactive processing

Nächster Artikel Synthesis, characterization and physiochemical investigation of chitosan-based multi-responsive Copolymeric hydrogels

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Titel: An antibacterial composite system based on multi-responsive microgels hosting monodisperse gold nanoparticles
verfasst von: Damla Ulker
Cansel Tuncer
Serife B. Sezgin
Yagmur Toptas
Ahmet Cabuk
Vural Bütün
Publikationsdatum: 01.09.2017
Verlag: Springer Netherlands
Erschienen in: Journal of Polymer Research / Ausgabe 10/2017
Print ISSN: 1022-9760
Elektronische ISSN: 1572-8935
DOI: https://doi.org/10.1007/s10965-017-1336-y

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