nach oben

Biomass Conversion and Biorefinery

Erschienen in:

10.02.2017 | Original Article

An optimisation study on biomass delignification process using alkaline wash

verfasst von: Ashraf Zin Zawawi, Law Poh Gaik, Noor Haida Sebran, Jofry Othman, Azlan Shah Hussain

Erschienen in: Biomass Conversion and Biorefinery | Ausgabe 1/2018

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config

KI-gestützte Suche

Aus

Abstract

A statistical based study employing response surface method (RSM) was conducted to ascertain the optimum pretreatment conditions using an alkaline wash technique i.e. at different temperature, time and base concentration using Malaysian oil palm empty fruit bunches (EFB) as a model substrate. Strong acid-dilute acid hydrolysis and dietary fibre methods were used in order to determine structural carbohydrates and lignin content of pretreated EFB and analysed using one-way analysis of variance (ANOVA). Based on the RSM model, 17 runs of different pretreatment conditions were carried out. ANOVA analysis on the different techniques yielded an F value of 5.32 leading to the rejection of null hypothesis. As such, both techniques were determined to be statistically different. Response surface model with quadratic function was generated for biomass pretreatment using alkaline wash which has indicated that sodium hydroxide concentration is the most important factor in determining lignin removal, followed by time of reaction. The final lignin content of pretreated biomass shall be 9.04 wt.% which is 62.7% of lignin removal.

Vorheriger Artikel Greenhouse gas assessment of palm oil mill biorefinery in Thailand from a life cycle perspective

Nächster Artikel Comparative studies on catalytic properties of immobilized lipase on low-cost support matrix for transesterification of pinnai oil

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

über 102.000 Bücher
über 537 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Finance + Banking
Management + Führung
Marketing + Vertrieb
Maschinenbau + Werkstoffe
Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

über 67.000 Bücher
über 390 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Maschinenbau + Werkstoffe

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Fernando S, Adhikari S, Chandrapal C, Murali N (2006) Biorefineries: current status, challenges and future direction. Energy Fuel 20:1727–1737CrossRef

Garcia-Nunez JA, Ramirez-Contreras NE, Rodriguez DT, Silva-Lora E, Frear CS, Stockle C, Garcia-Perez M (2016) Evolution of palm oil mills into bio-refineries: literature review on current and potential use of residual biomass and effluents. Resour Conser Recycling 110:99–114CrossRef

Esposito D, Antonietti M (2015) Redefining biorefinery: the search for unconventional building blocks. Chem Soc Rev 44:5821–5835CrossRef

Kumar P, Barrett DM, Delwiche MJ, Stroeve P (2009) Methods for lignocellulosic biomass for efficient hydrolysis and biofuel production. Ind Eng Chem Res 48:3713–3729CrossRef

Awalludin MF, Sulaiman O, Hashim R, Wan Nadhari WNA (2015) An overview of the oil palm industry in Malaysia and its waste utilization through thermochemical conversion, specifically via liquefaction. Renew Sus Energy Rev 50:1469–1484CrossRef

Abnisa F, Daud WMAW, Husin W, Sahu JN (2011) Utilization possibilities of palm shell as a source of biomass energy in Malaysia by producing bio-oil in pyrolysis process. Biomass Bioenergy 35:1863–1872CrossRef

Goh CS, Tan KT, Lee KT (2010) Bio-ethanol from lignocellulose: status, perspective and challenges in Malaysia. Bioresour. Tech. 101:4834–4841CrossRef

Karim RA, Hussain AS, Zain AM (2014) Production of bioethanol from empty fruit bunches cellulosic biomass and Avicel PH-101 cellulose. Biomass Conv Bioref 4:333–340CrossRef

Katahira R, Mittal A, McKinney K, Chen X, Tucker MP, Johnson DK, Beckham GT (2016) Base catalysed depolymerisation of biorefinery lignin. ACS Sustainable Chem & Eng 4:1474–1486CrossRef

10.

Roberts VM, Stein V, Reiner T, Lemonidou A, Li X, Lercher JA (2011) Towards quantitative catalytic lignin depolymerisation. Chem Eur Jour 17:5939–5948CrossRef

11.

Dabral S, Mottweiler J, Rinesch T, Bolm C (2015) Base-catalysed cleavage of lignin β-O-4 model compounds in dimethyl carbonate. Green Chem 17:4908–4912CrossRef

12.

Xu C, Arancon RAD, Labidi J, Luque R (2014) Lignin: depolymerisation strategies: towards valuable chemicals and fuels. Chem Soc Rev 43(22):7485–7500CrossRef

13.

Wang H, Tucker M, Ji Y (2013) Recent development in chemical depolymerisation of lignin: a review. Jour Appl Chem. doi:10.1155/2013/838645

14.

ASTM International, ASTM E1690 Standard method for determination of ethanol extractives in biomass (2016)

15.

Goering HK and PJ Van Soest (1970) Forage fiber analysis (apparatus, reagents, procedures, and some applications). Agricultural Research Service (ARS) Handbook. No. 379. Washington, DC

16.

Van Soest PJ, Robertson JB, Lewis BA (1991) Methods for dietary fiber, neutral detergent fiber, and non-starch polysaccharides in relation to animal nutrition. J Dairy Sci 74:3583–3597CrossRef

17.

Chaves AV, Waghorn GC, Tavendale MH (2002) A simplified method for lignin measurement in a range of forage species. Proceedings of the New Zealand Grassland Association 64:129–133

18.

Sluiter, A. Ruiz, R., Scarlata, C., Sluiter, J., D. Templeton and D. Crocker (2008) Determination of structural carbohydrates and lignin in biomass. Colorado: National Renewable Energy Laboratory. Laboratory Analytical Procedure. NREL/TP-510-42618

19.

Medina JDC, Woiciechowski A, Filho AZ, Noseda MD, Kaur BS, Soccol CR (2015) Lignin preparation from oil palm empty fruit bunches by sequential acid/alkaline treatment—a biorefinery approach. Bioresour. Tech. 194:172–178CrossRef

20.

Chiesa S, Gnansounou E (2014) Use of empty fruit bunches from the oil palm for bioethanol production: a thorough comparison between dilute acid and dilute alkali pretreatment. Bioresour Tech 159:355–364CrossRef

21.

Nieves DC, Karimi K, Horvath IS (2011) Improvement of biogas production from oil palm empty fruit bunches (OPEFB). Ind Crops Prods 34:1097–1101CrossRef

22.

Isroi, Mofoluwake MI, Ria M, Siti S, Muhammad NC, Claes N, Taherzadeh MJ (2012) Structural changes of oil palm empty fruit bunch (OPEFB) after fungal and phosphoric acid pretreatment. Molecules 17:14995–15012CrossRef

23.

Abdullah N, Sulaiman F, Gerhauser H (2011) Characterisation of oil palm empty fruit bunches for fuel application. Jour Phy Sci 20:1–24

24.

Financie R, Moniruzzaman M, Uemura Y (2016) Enhanced enzymatic delignification of oil palm biomass with ionic liquid pretreatment. BioChem Eng Jour 110:1–7CrossRef

25.

Abdul PM, Jahim JM, Harun S, Markom M, Lutpi NA, Hassan O, Balan V, Dale BE, Mohd. Nor MT (2016) Effects of changes in chemical and structural characteristic of ammonia fibre expansion (AFEX) pretreated oil palm empty fruit bunch fibre on enzymatic saccharification and fermentability for biohydrogen. Bioresource Tech 211:200–208CrossRef

26.

Taherzadeh MI, Karimi K (2008) Pretreatment of lignocellulosic wastes to improve ethanol and biogas production: a review. Intl Jour Mol Sci 9:1621–1651CrossRef

27.

Mirahmadi K, Kabir MM, Jeihanipour A, Karimi K, Taherzadeh MJ (2010) Alkaline pretreatment of spruce and birch to improve bioethanol and biogas production. Bioresources 5(2):928–938

28.

Myers RH, Montomery DC (2009) Response surface methodology: process and product optimization using designed experiments, 3rd edn. Wiley, New York, pp 317–321

29.

Khuri AI, Mukhopadhyay S (2010) Response surface methodology. WIREs Computational Statistics:128–149

30.

Bas D, Boyaci IH (2007) Modelling and optimization I: usability of response surface methodology. J Food Eng 78(3):836–845CrossRef

31.

Bezerra MA, Santelli RE, Oliveira EP, Villar LS, Escaleira LA (2008) Response surface methodology (RSM) as a tool for optimization in analytical chemistry. Talanta 76:965–977CrossRef

32.

Whitcomb, P. J., Larntz, K., (1992) The role of pure error on normal probability plots, presented at Transactions of the 46th Annual Quality Congress, Milwaukee

33.

Akhtar J, Teo CL, Lai LW, Hassan N, Idris A, Aziz RA (2015) Factors affecting delignification of oil palm empty fruit bunch by microwave-assisted dilute acid/alkali pretreatment. Bioresources 10(1):588–596

34.

Muryanto, Eka T, Haznan A, Agung. C, Effendi TC, Yanni S (2015) Alkaline delignification of oil palm empty fruit bunch using black liquor from pretreatment. Procedia Chemistry 16:99–105CrossRef

35.

Hong JY, Kim YS, Oh KK (2013) Fractionation and delignification of empty fruit bunches with low reaction severity for high sugar recovery. Bioresour Technol 146:176–183CrossRef

36.

Choi, W. I., Park, J. Y., Lee, J. P., Oh, Y. K., Park, Y. C., Kim, J. S., Park, J. M., Kim, C. H., Lee, J. S. (2013) Optimization of NaOH-catalyzed steam pretreatment of empty fruit bunch, Biotechnology for Biofuels, 6 (170)

37.

Hamisan AF, Aziz SA, Kamaruddin K, Md Shah UK, Shahab N, Hassan MA (2009) Delignification of oil palm empty fruit bunch using chemical and microbial pretreatment methods. Int J of Agricultural Research 4(8):250–256CrossRef

Titel: An optimisation study on biomass delignification process using alkaline wash
verfasst von: Ashraf Zin Zawawi
Law Poh Gaik
Noor Haida Sebran
Jofry Othman
Azlan Shah Hussain
Publikationsdatum: 10.02.2017
Verlag: Springer Berlin Heidelberg
Erschienen in: Biomass Conversion and Biorefinery / Ausgabe 1/2018
Print ISSN: 2190-6815
Elektronische ISSN: 2190-6823
DOI: https://doi.org/10.1007/s13399-017-0246-x

Springer Professional

Abstract

Bitte loggen Sie sich ein, um Zugang zu Ihrer Lizenz zu erhalten.

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Springer Professional "Technik"

Weitere Artikel der Ausgabe 1/2018

Greenhouse gas assessment of palm oil mill biorefinery in Thailand from a life cycle

Glyceraldehyde-3-phosphate dehydrogenase promoter from enoki mushroom drove gene expression of exogenous cellulase in Aspergillus niger

A study of black liquor and pyrolysis oil co-gasification in pilot scale

Comparative studies on catalytic properties of immobilized lipase on low-cost support matrix for transesterification of pinnai oil

Characteristics of hydrochar and hydrothermal liquid products from hydrothermal carbonization of corncob

Characterization of fat and biodiesel from mango seeds using 1H NMR spectroscopy