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Physics of Metals and Metallography
Erschienen in: Physics of Metals and Metallography 1/2019

01.01.2019 | STRUCTURE, PHASE TRANSFORMATIONS, AND DIFFUSION

Anion Mobility and Cation Diffusion in Alkali Metal Borohydrides

verfasst von: A. V. Soloninin

Erschienen in: Physics of Metals and Metallography | Ausgabe 1/2019

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Abstract

This study presents a wide spectrum of experimental investigations of alkali borohydrides МВН4 (М = Li, Na, K, Rb, Cs) and complex hydrides with substituted anions Li(BH4)1– yIy, LiLa(BH4)3Cl, and Na2(BH4)(NH2) obtained by the nuclear magnetic resonance method, quasielastic neutron scattering spectroscopy, and X-ray diffraction analysis. Activation energies for reorientational motion of anions in alkali borohydrides have been systematized, and possible configurations and types of jumps of ВН4 groups have been discussed. It has been shown that the activation energy of reorientations of ВН4 groups change nonmonotonously with the growth of the cation radius. Substitution of halides and amides for anions in complex hydrides leads to an enhancement in the frequency of anion reorientations at low temperatures, a change in the translational diffusion of cations at the expense of a change in the crystalline structure, the appearance of vacancies in the lattice, and influence of the paddle-wheel effect. Interrelation between the type of anion reorientations, cation diffusion, and the crystal lattice has been demonstrated.
Vorheriger Artikel Texture and Microstructure Development of Tensile Deformed High-Mn Steel during Early Stage of Recrystallization
Nächster Artikel Structural Vacancy Model of Grain Boundaries

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Literatur
1.
W. Grochala and P. P. Edwards, “Thermal decomposition of the non-interstitial hydrides for the storage and production of hydrogen,” Chem. Rev. 104, 1283−1315 (2004).CrossRef
2.
L. George and S. K. Saxena, “Structural stability of metal hydrides, alanates and borohydrides of alkali and alkali-earth elements: a review,” Int. J. Hydrogen Energy 35, 5454−5470 (2010).CrossRef
3.
R. Mohtadi, A. Remhof, and P. Jena, “Complex metal borohydrides: multifunctional materials for energy storage and conversion,” J. Phys.: Condens. Matter 28, 353001 (2016).
4.
S.-i. Orimo, Y. Nakamori, J. R. Eliseo, A. Züttel, and C. M. Jensen, “Complex hydrides for hydrogen storage,” Chem. Rev. 107, 4111−4132 (2007).CrossRef
5.
M. Paskevicius, L. H. Jepsen, P. Schouwink, R. Černy, D. B. Ravnsbæk, Y. Filinchuk, M. Dornheim, F. Besenbacher, and T. R. Jensen, “Metal borohydrides and derivatives—Synthesis, structure and properties,” Chem. Soc. Rev. 46, 1565−1634 (2017).CrossRef
6.
P. E. de Jongh, D. Blanchard, M. Matsuo, T. J. Udovic, and S. Orimo, “Complex hydrides as room-temperature solid electrolytes for rechargeable batteries,” Appl. Phys. A 122, 251 (2016).CrossRef
7.
A. Züttel, A. Borgschulte, and S. Orimo, “Tetrahydroborates as new hydrogen storage materials,” Scr. Mater. 56, 823−828 (2007).CrossRef
8.
A. F. Gross, J. J. Vajo, S. L. Van Atta, and G. L. Olson, “Enhanced hydrogen storage kinetics of LiBH4 in nanoporous carbon scaffolds,” J. Phys. Chem. C 112, 5651−5657 (2008).CrossRef
9.
J. J. Vajo and G. L. Olson, “Hydrogen storage in destabilized chemical systems,” Scr. Mater. 56, 829−834 (2007).CrossRef
10.
R. Retnamma, A. Q. Novais, and C. M. Rangel, “Kinetics of hydrolysis of sodium borohydride for hydrogen production in fuel cell applications: A review,” Int. J. Hydrogen Energy 36, 9772−9790 (2011).CrossRef
11.
A. V. Skripov, A. V. Soloninin, and O. A. Babanova, “Nuclear magnetic resonance studies of atomic motion in borohydrides,” J. Alloys Compd. 509S, S535−S539 (2011).CrossRef
12.
A. Remhof, Z. Łodziana, P. Martelli, O. Friedrichs, A. Züttel, A. V. Skripov, J. P. Embs, and T. Strässle, “Rotational motion of BH4 units in MBH4 (M = Li, Na, K) from quasielastic neutron scattering and density functional calculations,” Phys. Rev. B 81, 214304 (2010).CrossRef
13.
Y. Filinchuk, D. Chernyshov, and R. Cerny, “Lightest borohydride probed by synchrotron X-ray diffraction: Experiment calls for a new theoretical revision,” J. Phys. Chem. C 112, 10579−10584 (2008).CrossRef
14.
G. Renaudin, S. Gomes, H. Hagemann, L. Keller, and K. Yvon, “Structural and spectroscopic studies on the alkali borohydrides MBH4 (M = Na, K, Rb, Cs),” J. Alloys Compd. 375, 98−106 (2004).CrossRef
15.
A. V. Skripov, A. V. Soloninin, Y. Filinchuk, and D. Chernyshov, “Nuclear magnetic resonance study of the rotational motion and the phase transition in LiBH4,” J. Phys. Chem. C 112, 18701−18705 (2008).CrossRef
16.
A. V. Soloninin, A. V. Skripov, A. L. Buzlukov, and A. P. Stepanov, “Nuclear magnetic resonance study of Li and H diffusion in the high-temperature solid phase of LiBH4,” J. Solid State Chem. 182, 2357−2361 (2009).CrossRef
17.
O. A. Babanova, A. V. Soloninin, A. P. Stepanov, A. V. Skripov, and Y. Filinchuk, “Structural and dynamical properties of NaBH4 and KBH4: NMR and synchrotron X-ray diffraction studies,” J. Phys. Chem. C 114, 3712−3718 (2010).CrossRef
18.
O. A. Babanova, A. V. Soloninin, A. V. Skripov, D. B. Ravnsbæk, T. R. Jensen, and Y. Filinchuk, “Reorientational motion in alkali-metal borohydrides: NMR data for RbBH4 and CsBH4 and systematics of the activation energy variations,” J. Phys. Chem. C 115, 10305−10309 (2011).CrossRef
19.
A. Abragam, The Principles of Nuclear Magnetism (Clarendon Press, Oxford, 1961; Inostrannaya literatura, Moscow, 1963) [in Russian].
20.
M. R. Hartman, J. J. Rush, T. J. Udovic, and R. C. Bowman, and S.-J. Hwang, “Structure and vibrational dynamics of isotopically labeled lithium borohydride using neutron diffraction and spectroscopy,” J. Solid State Chem. 180, 1298−1305 (2007).CrossRef
21.
Y. Filinchuk, A. V. Talyzin, H. Hagemann, V. Dmitriev, D. Chernyshov, and B. Sundqvist, “Cation size and anion anisotropy in structural chemistry of metal borohydrides. The peculiar pressure evolution of RbBH4,” Inorg. Chem. 49, 5285−5292 (2010).CrossRef
22.
K. Jimura and S. Hayashi, “Reorientational motion of BH4 ions in alkali borohydrides MBH4 (M = Li, Na, K) as studied by solid-state NMR,” J. Phys. Chem. C 116, 4883−4891 (2012).CrossRef
23.
A. Remhof, A. Züttel, T. Ramirez-Cuesta, V. García-Sakai, and B. Frick, “Hydrogen dynamics in the low temperature phase of LiBH4 probed by quasielastic neutron scattering,” Chem. Phys. 427, 18−21 (2013).CrossRef
24.
N. Verdal, M. R. Hartman, T. Jenkins, D. J. DeVries, J. J. Rush, and T. J. Udovic, “Reorientational dynamics of NaBH4 and KBH4,” J. Phys. Chem. C 114, 10027−10033 (2010).CrossRef
25.
A. Remhof, Z. Łodziana, F. Buchter, P. Martelli, F. Pendolino, O. Friedrichs, A. Züttel, and J. P. Embs, “Rotational diffusion in NaBH4,” J. Phys. Chem. C 113, 16834−16837 (2009).CrossRef
26.
M. Matsuo, Y. Nakamori, S-i. Orimo, H. Maekawa, and H. Takamura, “Lithium superionic conduction in lithium borohydride accompanied by structural transition,” Appl. Phys. Lett. 91, 224103−224105 (2007).CrossRef
27.
M. Matsuo and S-i. Orimo, “Lithium fast-ionic conduction in complex hydrides: review and prospects,” Adv. Energy Mater. 1, 161−172 (2011).CrossRef
28.
R. L. Corey, D. T. Shane, R. C. Bowman, and M. S. Conradi, “Atomic motions in LiBH4 by NMR,” J. Phys. Chem. C 112, 18706−18710 (2008).CrossRef
29.
V. Epp and M. Wilkening, “Fast Li diffusion in crystalline LiBH4 due to reduced dimensionality: frequency-dependent NMR spectroscopy,” Phys. Rev. B 82, 020301(R) (2010).
30.
A. Lundén, “On the paddle-wheel mechanism for cation conduction in lithium sulphate,” Z. Naturforsch. 50a, 1067−1076 (1995).
31.
A. V. Skripov, A. V. Soloninin, M. B. Ley, T. R. Jensen, and Y. Filinchuk, “Nuclear magnetic resonance studies of BH4 reorientations and Li diffusion in LiLa(BH4)3Cl,” J. Phys. Chem. C 117, 14965−14972 (2013).CrossRef
32.
T. Ikeshoji, E. Tsuchida, T. Morishita, K. Ikeda, M. Matsuo, Y. Kawazoe, and S-i. Orimo, “Fast-ionic conductivity of Li+ in LiBH4,” Phys. Rev. B 83, 144301 (2011).CrossRef
33.
D. T. Shane, R. C. Bowman, and M. S. Conradi, “Exchange of hydrogen atoms between BH4 in LiBH4,” J. Phys. Chem. C 113, 5039−5042 (2009).CrossRef
34.
A. V. Skripov, A. V. Soloninin, L. H. Rude, T. R. Jensen, and Y. Filinchuk, “Nuclear magnetic resonance studies of reorientational motion and Li diffusion in LiBH4-LiI solid solutions,” J. Phys. Chem. C 116, 26177−26184 (2012).CrossRef
35.
A. V. Soloninin, O. A. Babanova, E. Y. Medvedev, A. V. Skripov, M. Matsuo, and S-i. Orimo, “Nuclear magnetic resonance study of atomic motion in the mixed borohydride-amide Na2(BH4)(NH2),” J. Phys. Chem. C 118, 14805−14812 (2014).CrossRef
36.
H. Maekawa, M. Matsuo, H. Takamura, M. Ando, Y. Noda, T. Karahashi, and S-i. Orimo, “Halide-stabilized LiBH4, a room-temperature lithium fast-ion conductor,” J. Am. Chem. Soc. 131, 894−895 (2009).CrossRef
37.
R. Miyazaki, T. Karahashi, N. Kumatani, Y. Noda, M. Ando, H. Takamura, M. Matsuo, S. Orimo, and H. Maekawa, “Room temperature lithium fast-ion conduction and phase relationship of LiI stabilized LiBH4,” Solid State Ionics 192, 143–147 (2011).CrossRef
38.
P. Martelli, A. Remhof, A. Borgschulte, R. Ackermann, T. Strässle, J. P. Embs, M. Ernst, M. Matsuo, S. Orimo, and A. Züttel, “Rotational motion in LiBH4/LiI solid solutions,” J. Phys. Chem. A 115, 5329−5334 (2011).CrossRef
39.
A. V. Skripov, A. V. Soloninin, O. A. Babanova, and R. V. Skoryunov, “Nuclear magnetic resonance studies of atomic motion in borohydride-based materials: Fast anion reorientations and cation diffusion,” J. Alloys Compd. 645, S428−S433 (2015).CrossRef
40.
N. Verdal, T. J. Udovic, and J. J. Rush, “The nature of \({\text{BH}}_{4}^{ - }\) reorientations in hexagonal LiBH4,” J. Phys. Chem. C 116, 1614−1618 (2012).CrossRef
41.
N. Verdal, T. J. Udovic, J. J. Rush, H. Wu, and A. V. Skripov, “Evolution of the reorientational motions of the tetrahydroborate anions in hexagonal LiBH4−LiI solid solution by high-Q quasielastic neutron scattering,” J. Phys. Chem. C 117, 12010−12018 (2013).CrossRef
42.
M. B. Ley, S. Boulineau, R. Janot, Y. Filinchuk, and T. R. Jensen, “New Li ion conductors and solid state hydrogen storage materials: LiM(BH4)3Cl, M = La, Gd,” J. Phys. Chem. C 116, 21267−21276 (2012).CrossRef
43.
Y-S. Lee, M. B. Ley, T. R. Jensen, and Y. W. Cho, “Lithium ion disorder and conduction mechanism in LiCe(BH4)3Cl,” J. Phys. Chem. C 120, 19035−19042 (2016).CrossRef
44.
M. Matsuo, S. Kuromoto, T. Sato, H. Oguchi, H. Takamura, and S. Orimo, “Sodium ionic conduction in complex hydrides with [BH4]− and [NH2]− anions,” Appl. Phys. Lett. 100, 203904 (2012).CrossRef
45.
M. Somer, S. Acar, C. Koz, I. Kokal, P. Höhn, R. Cardoso-Gil, U. Aydemir, and L. Akselrud, “α- and β‑Na2[BH4][NH2]: two modifications of a complex hydride in the system NaNH2–NaBH4; syntheses, crystal structures, thermal analyses, mass and vibrational spectra,” J. Alloys Compd. 491, 98−105 (2010).CrossRef
Metadaten
Titel
Anion Mobility and Cation Diffusion in Alkali Metal Borohydrides
verfasst von
A. V. Soloninin
Publikationsdatum
01.01.2019
Verlag
Pleiades Publishing
Erschienen in
Physics of Metals and Metallography / Ausgabe 1/2019
Print ISSN: 0031-918X
Elektronische ISSN: 1555-6190
DOI
https://doi.org/10.1134/S0031918X19010046

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