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Journal of Nanoparticle Research

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01.07.2019 | Research Paper

Bimetallic AuCu nanoparticles supported on CeO₂ as selective catalysts for glycerol conversion to lactic acid in aqueous basic medium

verfasst von: Ruben Palacio, Diana López, Diana Hernández

Erschienen in: Journal of Nanoparticle Research | Ausgabe 7/2019

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Abstract

Gold-based catalysts, monometallic Au/CeO₂ or bimetallic AuCu/CeO₂, evaluated on the glycerol conversion to lactic acid, demonstrated to be active and selective at a reaction temperature of 220 °C in aqueous basic medium at low base concentration. The concentration of NaOH slightly modified the activity of AuCu/CeO₂ for converting glycerol, while selectivity toward lactic acid increased on AuCu/CeO₂ catalyst but had no influence on Au/CeO₂ catalytic performance. Recyclability tests demonstrated that AuCu/CeO₂ kept high conversion for up to the fourth catalytic cycle and selectivity remained stable, while conversion on Au/CeO₂ significantly decreased in the second cycle. For instance, copper stabilized gold on AuCu/CeO₂ catalysts for converting glycerol to lactic acid in aqueous medium at relatively high temperature of 220 °C. Characterization of AuCu/CeO₂ catalyst using H₂-TPR showed that the presence of Au modified the reduction events of Cu species, while HRTEM analysis of nanoparticles showed particles of an average size of 6.3 nm and lattice fringes for metallic Au and Cu. These results suggest that Au and Cu might be in close proximity.

Vorheriger Artikel Mechanisms of nucleation and growth in the formation of charge transfer nanocrystals

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Titel: Bimetallic AuCu nanoparticles supported on CeO2 as selective catalysts for glycerol conversion to lactic acid in aqueous basic medium
verfasst von: Ruben Palacio
Diana López
Diana Hernández
Publikationsdatum: 01.07.2019
Verlag: Springer Netherlands
Erschienen in: Journal of Nanoparticle Research / Ausgabe 7/2019
Print ISSN: 1388-0764
Elektronische ISSN: 1572-896X
DOI: https://doi.org/10.1007/s11051-019-4594-2

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