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2022 | OriginalPaper | Buchkapitel

7. Bio-derived and Waste Fats Use for the Production of Drop-In Fuels

verfasst von : Mattia Bartoli, Mauro Giorcelli, Ruggero Vigliaturo, Pravin Jagdale, Massimo Rovere, Alberto Tagliaferro

Erschienen in: Clean Fuels for Mobility

Verlag: Springer Singapore

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Abstract

The global energy transition has started and the mankind actively looking for new way to replace the fossil fuels based technology. This paradigm change is quite hard to accomplished due the many drawbacks related to a complete rethinking of the engines. So, a solid solution could be represented by the use of oil derived analogue fuels produced using renewable sources known as drop-in fuels. In this field, the thermal conversion of fats has played a main role due the easily conversion in hydrocarbon mixture very close to diesel fraction.

In this chapter, we overview the use of lipid as feedstock for the production of drop-in fuels through pyrolytic conversions. We overview the main mechanisms behind the cracking of fatty acids and triglycerides, providing a reference point for understanding the process described. We have also reported the most relevant achievement in this field. We included both the early studies and the most recent advancements. A section is also dedicated to catalytic conversions and upgrading to provide a solid background to the reader.

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Vorheriges Kapitel Bioethanol from Wastes for Mobility: Europe on the Road to Sustainability

Nächstes Kapitel Biodiesel as a Clean Fuel for Mobility

Aboulkas A, El Bouadili A (2010) Thermal degradation behaviors of polyethylene and polypropylene: Part I Pyrolysis kinetics and mechanisms. Energy Convers Manage 51(7):1363–1369

Adebanjo AO, Dalai AK, Bakhshi NN (2005) Production of diesel-like fuel and other value-added chemicals from pyrolysis of animal fat. Energy Fuels 19(4):1735–1741. https://doi.org/10.1021/ef040091bCrossRef

Alencar J, Alves P, Craveiro A (1983) Pyrolysis of tropical vegetable oils. J Agric Food Chem 31(6):1268–1270CrossRef

Asomaning J, Mussone P, Bressler DC (2014a) Pyrolysis of polyunsaturated fatty acids. Fuel Process Technol 120:89–95. https://doi.org/10.1016/j.fuproc.2013.12.007CrossRef

Asomaning J, Mussone P, Bressler DC (2014b) Thermal cracking of free fatty acids in inert and light hydrocarbon gas atmospheres. Fuel 126:250–255. https://doi.org/10.1016/j.fuel.2014.02.069CrossRef

Asomaning J, Mussone P, Bressler DC (2014c) Thermal deoxygenation and pyrolysis of oleic acid. J Anal Appl Pyrol 105:1–7. https://doi.org/10.1016/j.jaap.2013.09.005CrossRef

Asomaning J, Mussone P, Bressler DC (2014d) Two-stage thermal conversion of inedible lipid feedstocks to renewable chemicals and fuels. Biores Technol 158:55–62. https://doi.org/10.1016/j.biortech.2014.01.136CrossRef

Atabani A, Silitonga A, Ong H, Mahlia T, Masjuki H, Badruddin IA, Fayaz H (2013) Non-edible vegetable oils: a critical evaluation of oil extraction, fatty acid compositions, biodiesel production, characteristics, engine performance and emissions production. Renew Sustain Energy Rev 18:211–245CrossRef

Bartoli M, Frediani F, Briens C, Berruti F, Rosi L (2019) An overview of temperature issues in microwave-assisted pyrolysis. Processes 7(10)

Bashir MJK, Wong LP, Hilaire DS, Kim J, Salako O, Jean MJ, Adeyemi R, James S, Foster T, Pratt LM (2020) Biodiesel fuel production from brown grease produced by wastewater treatment plant: optimization of acid catalyzed reaction conditions. J Environ Chem Eng 8(4):103848. https://doi.org/10.1016/j.jece.2020.103848CrossRef

Chang C-C, Wan S-W (1947) China’s motor fuels from tung oil. Ind Eng Chem 39(12):1543–1548CrossRef

Cherubini F (2010) The biorefinery concept: using biomass instead of oil for producing energy and chemicals. Energy Convers Manage 51(7):1412–1421CrossRef

Dandik L, Aksoy HA (1998) Converting used oil to fuel and chemical feedstock through a fractionating pyrolysis reactor. In: Kaseoglu SS, Rhee KC, Wilson RF (eds) Proceedings of the world conference on oilseed and edible oil processing, Istanbul, Turkey

Dandik L, Aksoy HA, Erdem-Senatalar A (1998) Catalytic conversion of used oil to hydrocarbon fuels in a fractionating pyrolysis reactor. Energy Fuels 12(6):1148–1152. https://doi.org/10.1021/ef980012uCrossRef

Das UN (2006) Essential fatty acids-a review. Curr Pharm Biotechnol 7(6):467–482CrossRef

Demirbaş A (2002) Diesel fuel from vegetable oil via transesterification and soap pyrolysis. Energy Sources 24(9):835–841CrossRef

Dorian JP, Franssen HT, Simbeck DR (2006) Global challenges in energy. Energy Policy 34(15):1984–1991. https://doi.org/10.1016/j.enpol.2005.03.010CrossRef

Firoz S (2017) A review: advantages and disadvantages of biodiesel. Int Res J Eng Technol 4(11):530–533

Fortes I, Baugh P (1994) Study of calcium soap pyrolysates derived from Macauba fruit (Acrocomia sclerocarpa M.). Derivatization and analysis by GC/MS and CI-MS. J Anal Appl Pyrol 29(2):153–167

Frusteri F, Cannilla C, Bonura G, Spadaro L, Mezzapica A, Beatrice C, Di Blasio G, Guido C (2013) Glycerol ethers production and engine performance with diesel/ethers blend. Top Catal 56(1):378–383. https://doi.org/10.1007/s11244-013-9983-7CrossRef

Fukushima K (1983) Investigation of the possible role of fatty acids and alcohols as precursors of normal hydrocarbons generated during vacuum pyrolysis of a young kerogen. J Anal Appl Pyrol 5(3):245–256. https://doi.org/10.1016/0165-2370(83)80031-XCrossRef

Gad MS, Abu-Elyazeed OS, Mohamed MA, Hashim AM (2021) Effect of oil blends derived from catalytic pyrolysis of waste cooking oil on diesel engine performance, emissions and combustion characteristics. Energy 223:120019. https://doi.org/10.1016/j.energy.2021.120019CrossRef

Gasparatos A, Doll CNH, Esteban M, Ahmed A, Olang TA (2017) Renewable energy and biodiversity: Implications for transitioning to a green economy. Renew Sustain Energy Rev 70:161–184. https://doi.org/10.1016/j.rser.2016.08.030CrossRef

Geng Z, Zhang M, Yu Y (2012) Theoretical investigation on pyrolysis mechanism of glycerol. Fuel 93:92–98. https://doi.org/10.1016/j.fuel.2011.08.021CrossRef

Giorcelli M, Das O, Sas G, Försth M, Bartoli M (2021) A review of bio-oil production through microwave-assisted pyrolysis. Processes 9(3):561CrossRef

Gunstone F (2009) The chemistry of oils and fats: sources, composition, properties and uses. John Wiley & Sons, New York, U.S.

Hsu H-L, Osburn J, Grove C (1950) Pyrolysis of the calcium salts of fatty acids. Ind Eng Chem 42(10):2141–2145CrossRef

Idem RO, Katikaneni SPR, Bakhshi NN (1997) Catalytic conversion of canola oil to fuels and chemicals: roles of catalyst acidity, basicity and shape selectivity on product distribution. Fuel Process Technol 51(1):101–125. https://doi.org/10.1016/S0378-3820(96)01085-5CrossRef

Jaw K-S, Hsu C-K, Lee J-S (2001) The thermal decomposition behaviors of stearic acid, paraffin wax and polyvinyl butyral. Thermochim Acta 367:165–168CrossRef

Jenab E, Mussone P, Nam G, Bressler D (2014) Production of renewable hydrocarbons from thermal conversion of abietic acid and tall oil fatty acids. Energy Fuels 28(11):6988–6994. https://doi.org/10.1021/ef501746bCrossRef

Kajaste R (2014) Chemicals from biomass–managing greenhouse gas emissions in biorefinery production chains–a review. J Clean Prod 75:1–10CrossRef

Katikaneni SPR, Adjaye JD, Idem RO, Bakhshi NN (1996) Catalytic conversion of canola oil over potassium-impregnated HZSM-5 catalysts: C2–C4 olefin production and model reaction studies. Ind Eng Chem Res 35(10):3332–3346. https://doi.org/10.1021/ie950740uCrossRef

Kitamura K (1971) Studies of the pyrolysis of triglycerides. Bull Chem Soc Jpn 44(6):1606–1609CrossRef

Krishania N, Rajak U, Verma TN, Birru AK, Pugazhendhi A (2020) Effect of microalgae, tyre pyrolysis oil and Jatropha biodiesel enriched with diesel fuel on performance and emission characteristics of CI engine. Fuel 278:118252

Kumar BR, Saravanan S, Rana D, Nagendran A (2016) A comparative analysis on combustion and emissions of some next generation higher-alcohol/diesel blends in a direct-injection diesel engine. Energy Convers Manage 119:246–256CrossRef

Lappi H, Alén R (2009) Production of vegetable oil-based biofuels—thermochemical behavior of fatty acid sodium salts during pyrolysis. J Anal Appl Pyrol 86(2):274–280. https://doi.org/10.1016/j.jaap.2009.07.005CrossRef

Lima DG, Soares VC, Ribeiro EB, Carvalho DA, Cardoso ÉC, Rassi FC, Mundim KC, Rubim JC, Suarez PA (2004) Diesel-like fuel obtained by pyrolysis of vegetable oils. J Anal Appl Pyrol 71(2):987–996CrossRef

Liu PR, Raftery AE (2021) Country-based rate of emissions reductions should increase by 80% beyond nationally determined contributions to meet the 2 ℃ target. Commun Earth Environ 2(1):29. https://doi.org/10.1038/s43247-021-00097-8CrossRef

Maher K, Bressler D (2007) Pyrolysis of triglyceride materials for the production of renewable fuels and chemicals. Biores Technol 98(12):2351–2368CrossRef

Maher KD, Kirkwood KM, Gray MR, Bressler DC (2008) Pyrolytic decarboxylation and cracking of stearic acid. Ind Eng Chem Res 47(15):5328–5336. https://doi.org/10.1021/ie0714551CrossRef

Mahmudul H, Hagos F, Mamat R, Adam AA, Ishak W, Alenezi R (2017) Production, characterization and performance of biodiesel as an alternative fuel in diesel engines–a review. Renew Sustain Energy Rev 72:497–509CrossRef

Mao X, Xie Q, Yi X, Duan Y, Yu S, Wu Z, Liang X, Nie Y (2021) Fast pyrolysis of methyl ricinoleate in an inductively heated reactor coupled with atomization feeding. Appl Therm Eng 194:117093. https://doi.org/10.1016/j.applthermaleng.2021.117093CrossRef

Meher L, Sagar DV, Naik S (2006) Technical aspects of biodiesel production by transesterification—a review. Renew Sustain Energy Rev 10(3):248–268CrossRef

Morgan T, Grubb D, Santillan-Jimenez E, Crocker M (2010) Conversion of triglycerides to hydrocarbons over supported metal catalysts. Top Catal 53(11–12):820–829CrossRef

Nakicenovic N, Grübler A, McDonald A (1998) Global energy perspectives. Cambridge University Press, Cambridge, U.K.

Nawar WW (1969) Thermal degradation of lipids. J Agric Food Chem 17(1):18–21CrossRef

Nichols PC, Holman RT (1972) Pyrolysis of saturated triglycerides. Lipids 7(12):773–779CrossRef

Noshadi I, Kanjilal B, Du S, Bollas GM, Suib SL, Provatas A, Liu F, Parnas RS (2014) Catalyzed production of biodiesel and bio-chemicals from brown grease using ionic liquid functionalized ordered mesoporous polymer. Appl Energy 129:112–122. https://doi.org/10.1016/j.apenergy.2014.04.090CrossRef

Omar R, Robinson JP (2014) Conventional and microwave-assisted pyrolysis of rapeseed oil for bio-fuel production. J Anal Appl Pyrol 105:131–142. https://doi.org/10.1016/j.jaap.2013.10.012CrossRef

Omidghane M, Bartoli M, Asomaning J, Xia L, Chae M, Bressler DC (2020) Pyrolysis of fatty acids derived from hydrolysis of brown grease with biosolids. Environ Sci Pollut Res:1–11

Prasad Y, Bakhshi N, Mathews J, Eager R (1986a) Catalytic conversion of canola oil to fuels and chemical feedstocks: Part I Effect of process conditions on the performance of HZSM‐5 catalyst. Can J Chem Eng 64(2):278–284

Prasad Y, Bakhshi N, Mathews J, Eager R (1986) Catalytic conversion of canola oil to fuels and chemical feedstocks: Part II effect of co-feeding steam on the performance of HZSM-5 catalyst. Can J Chem Eng 64(2):285–292CrossRef

Pratt LM, Kim J, Lo H-Y, Xiao D (2021) Brown grease pyrolysis under pressure: extending the range of reaction conditions and hydrocarbon product distributions. Fuel 289:119782. https://doi.org/10.1016/j.fuel.2020.119782CrossRef

Rao KVC (1978) Production of hydrocarbons by thermolysis of vegetable oils

Ratton Coppos AR, Kahn S, Borges LEP (2018) Biofuels production by thermal cracking of soap from brown grease. Ind Crops Prod 112:561–568. https://doi.org/10.1016/j.indcrop.2017.12.010CrossRef

Schwab A, Dykstra G, Selke E, Sorenson S, Pryde E (1988) Diesel fuel from thermal decomposition of soybean oil. J Am Oil Chem Soc 65(11):1781–1786CrossRef

Semieniuk G, Taylor L, Rezai A, Foley DK (2021) Plausible energy demand patterns in a growing global economy with climate policy. Nat Clim Chang 11(4):313–318. https://doi.org/10.1038/s41558-020-00975-7CrossRef

Shitao Y, Cao X, Wu S, Chen Q, Li L, Li H (2020) Effective pyrolysis of waste cooking oils into hydrocarbon rich biofuel on novel mesoporous catalyst with acid and alkali coexisting. Ind Crops Prod 150:112362. https://doi.org/10.1016/j.indcrop.2020.112362CrossRef

Sim Y-L, Meyappan N, Yen NS, Swarna Kamala S, Khoo CH, Cheah WL, Hilaire DS, Pinnock T, Bacolod B, Cai ZB, Gurung D, Hasnat R, Strothers J, Remy CT, Gentles PK, Groveman S, Vittadello M, Kim J, Pratt LM (2017) Chemical reactions in the pyrolysis of brown grease. Fuel 207:274–282.https://doi.org/10.1016/j.fuel.2017.06.101

Snåre M, Kubičková I, Mäki-Arvela P, Chichova D, Eränen K, Murzin DY (2008) Catalytic deoxygenation of unsaturated renewable feedstocks for production of diesel fuel hydrocarbons. Fuel 87(6):933–945. https://doi.org/10.1016/j.fuel.2007.06.006CrossRef

Strothers J, Matthews RB, Toney A, Cobham MR, Cox S, Ford W, Joseph S, Joyette W, Khadka S, Pinnock S, Burns M, Noel M, Tamang MG, Saint Hilaire D, Kim J-H, Pratt LM (2019) Hydrocarbon fuel from brown grease: effects of reaction temperature profile on yields and product distribution. Fuel 239:573–578. https://doi.org/10.1016/j.fuel.2018.11.053CrossRef

Tan Y, Abdullah A, Hameed B (2019) Product distribution of the thermal and catalytic fast pyrolysis of karanja (Pongamia pinnata) fruit hulls over a reusable silica-alumina catalyst. Fuel 245:89–95CrossRef

Twaiq FA, Zabidi NA, Bhatia S (1999) Catalytic conversion of palm oil to hydrocarbons: performance of various zeolite catalysts. Ind Eng Chem Res 38(9):3230–3237CrossRef

Twaiq FAA, Mohamad AR, Bhatia S (2004) Performance of composite catalysts in palm oil cracking for the production of liquid fuels and chemicals. Fuel Process Technol 85(11):1283–1300. https://doi.org/10.1016/j.fuproc.2003.08.003CrossRef

Vonghia E, Boocock DG, Konar SK, Leung A (1995) Pathways for the deoxygenation of triglycerides to aliphatic hydrocarbons over activated alumina. Energy Fuels 9(6):1090–1096CrossRef

Wang H, Brown SL, Magesan GN, Slade AH, Quintern M, Clinton PW, Payn TW (2008) Technological options for the management of biosolids. Environ Sci Poll Res Int 15(4):308–317CrossRef

Wang Y, Dai L, Shan S, Zeng Q, Fan L, Liu Y, Ruan R, Zhao Y, Zhou Y (2016) Effect of unsaturation degree on microwave-assisted pyrolysis of fatty acid salts. J Anal Appl Pyrol 120:247–251. https://doi.org/10.1016/j.jaap.2016.05.012CrossRef

Wang Y, Ke L, Peng Y, Yang Q, Du Z, Dai L, Zhou N, Liu Y, Fu G, Ruan R, Xia D, Jiang L (2020) Characteristics of the catalytic fast pyrolysis of vegetable oil soapstock for hydrocarbon-rich fuel. Energy Convers Manage 213:112860. https://doi.org/10.1016/j.enconman.2020.112860CrossRef

Wang F, Yu F, Wei Y, Li A, Xu S, Lu X (2021) Promoting hydrocarbon production from fatty acid pyrolysis using transition metal or phosphorus modified Al-MCM-41 catalyst. J Anal Appl Pyrol 156:105146. https://doi.org/10.1016/j.jaap.2021.105146CrossRef

Welsby D, Price J, Pye S, Ekins P (2021) Unextractable fossil fuels in a 1.5 ℃ world. Nature 597(7875):230–234. https://doi.org/10.1038/s41586-021-03821-8

Zheng Y, Wang J, Liu C, Lu Y, Lin X, Li W, Zheng Z (2020) Efficient and stable Ni-Cu catalysts for ex situ catalytic pyrolysis vapor upgrading of oleic acid into hydrocarbon: Effect of catalyst support, process parameters and Ni-to-Cu mixed ratio. Renew Energy 154:797–812. https://doi.org/10.1016/j.renene.2020.03.058CrossRef

Zhenyi C, Xing JI, Shuyuan LI, Li LI (2004) Thermodynamics calculation of the pyrolysis of vegetable oils. Energy Sources 26(9):849–856. https://doi.org/10.1080/00908310490465902CrossRef

Titel: Bio-derived and Waste Fats Use for the Production of Drop-In Fuels
verfasst von: Mattia Bartoli
Mauro Giorcelli
Ruggero Vigliaturo
Pravin Jagdale
Massimo Rovere
Alberto Tagliaferro
Verlag: Springer Singapore
Buch: Clean Fuels for Mobility
Print ISBN: 978-981-16-8746-4

Electronic ISBN: 978-981-16-8747-1

Copyright-Jahr: 2022
DOI: https://doi.org/10.1007/978-981-16-8747-1_7

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