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Journal of Polymer Research
Erschienen in: Journal of Polymer Research 5/2021

01.05.2021 | ORIGINAL PAPER

Blending of cyclic carbonate based on soybean oil and glycerol: a non-isocyanate approach towards the synthesis of polyurethane with high performance

verfasst von: Simanta Doley, Anindita Bora, Priyankamoni Saikia, Shahnaz Ahmed, Swapan K. Dolui

Erschienen in: Journal of Polymer Research | Ausgabe 5/2021

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Abstract

This work demonstrates the synthesis of bio-based polyurethane from soybean oil and glycerol derived highly branched structure via non-isocyanate route. The soybean oil based cyclic carbonates were synthesized by coupling of CO2 with epoxidized soybean oil. In the second step, glycerol derived highly branched cyclic carbonate was synthesized from diglycidal ether of bisphenol A (DGEBA) and CO2. The structure of prepared monomer was confirmed from FT-IR, 1H and 13C NMR spectra. Then a series of non-isocyanate polyurethanes (NIPUs) were synthesized. They exhibited satisfactory mechanical properties (Tensile strength = 10.1 MPa) and thermal stability (283 °C). These results indicate the prospect of this eco-friendly approach for preparing renewable NIPU without the use of isocyanate.
Nächster Artikel Effect of different surface properties of nanosilica on retrogradation behavior and structures of thermoplastic cassava starch

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Metadaten
Titel
Blending of cyclic carbonate based on soybean oil and glycerol: a non-isocyanate approach towards the synthesis of polyurethane with high performance
verfasst von
Simanta Doley
Anindita Bora
Priyankamoni Saikia
Shahnaz Ahmed
Swapan K. Dolui
Publikationsdatum
01.05.2021
Verlag
Springer Netherlands
Erschienen in
Journal of Polymer Research / Ausgabe 5/2021
Print ISSN: 1022-9760
Elektronische ISSN: 1572-8935
DOI
https://doi.org/10.1007/s10965-021-02485-2

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