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Journal of Polymer Research
Erschienen in: Journal of Polymer Research 5/2021

01.05.2021 | ORIGINAL PAPER

Effect of different surface properties of nanosilica on retrogradation behavior and structures of thermoplastic cassava starch

verfasst von: Yu-Xin Liu, Ze-Sheng Liang, Jia-Neng Liang, Liang-Yan Liao

Erschienen in: Journal of Polymer Research | Ausgabe 5/2021

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Abstract

Thermoplastic cassava starch (TPS) /nanosilica (nano-SiO2) composites were prepared by adding different surface properties of nanosilica. The effect of different surface properties of nano-SiO2 on the retrogradation kinetics, morphology, spherulites size, molecular interactions, short-range molecular structure and crystal type of TPS was investigated by differential scanning calorimetry (DSC), polarized light microscopy (PLM), X-ray diffraction (XRD), scanning electron microscopy (SEM), Fourier transform infrared spectroscopy (FTIR) and 13C NMR. The results indicated that the retrogradation degree and rate of TPS containing hydrophobic nano-SiO2 were higher than that of hydrophilic nano-SiO2, and the spherulites were clearer. Hydrophobic nano-SiO2 could uniformly disperse in starch matrix. V-type crystal formed after adding hydrophilic nano-SiO2, and A + V types after adding hydrophobic nano-SiO2. The crystallinity of TPS adding hydrophobic nano-SiO2 was higher than that of hydrophilic nano-SiO2, but the crystal size and interplanar spacing were smaller. Hydrophobic nano-SiO2 could promote the formations of double helix structure and the ordered molecular structure.
Vorheriger Artikel Blending of cyclic carbonate based on soybean oil and glycerol: a non-isocyanate approach towards the synthesis of polyurethane with high performance
Nächster Artikel Development, thermal and dielectric investigations of PVDF-Y2O3 polymer nanocomposite films

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Literatur
1.
Hsieh C, Liu W, Whaley J, Shi Y (2019) Structure, properties, and potential applications of waxy tapioca starches – A review. Trends Food Sci Technol 83:225–234CrossRef
2.
Chen Q, Shi Y, Chen G, Cai M (2020) Enhanced mechanical and hydrophobic properties of composite cassava starch films with stearic acid modified MCC (microcrystalline cellulose)/NCC (nanocellulose) as strength agent. Int J Biol Macromol 142:846–854PubMedCrossRef
3.
Liu H, Xie F, Yu L, Chen L, Li L (2009) Thermal processing of starch-based polymers. Prog Polym Sci 34(12):1348–1368CrossRef
4.
Zhang MQ, Rong MZ, Zhang HB, Friedrich K (2003) Mechanical properties of low nano-silica filled high density polyethylene composites. Polym Eng Sci 43(2):490–500CrossRef
5.
Zhou SX, Wu LM, Sun J, Shen WD (2003) Effect of nanosilica on the properties of polyester-based polyurethane. J Appl Polym Sci 88(1):189–193CrossRef
6.
Tang S, Zou P, Xiong H, Tang H (2008) Effect of nano-SiO2 on the performance of starch/polyvinyl alcohol blend films. Carbohyd Polym 72(3):521–526CrossRef
7.
Wang Z, Gu Z, Hong Y, Cheng L, Li Z (2011) Bonding strength and water resistance of starch-based wood adhesive improved by silica nanoparticles. Carbohyd Polym 86(1):72–76CrossRef
8.
Frost K, Barthes J, Kaminski D, Lascaris E, Niere J, Shanks R (2011) Thermoplastic starch–silica–polyvinyl alcohol composites by reactive extrusion. Carbohyd Polym 84(1):343–350CrossRef
9.
Tang M, Hong Y, Gu Z, Zhang Y, Cai X (2013) The effect of xanthan on short and long-term retrogradation of rice starch. Starch - Stärke 65(7–8):702–708CrossRef
10.
Sikora M, Krystyjan M, Dobosz A, Tomasik P, Walkowiak K, Masewicz Ł, Kowalczewski PŁ, Baranowska HM (2019) Molecular analysis of retrogradation of corn starches. Polymers 11(11):1764PubMedCentralCrossRef
11.
Li W, Li C, Gu Z, Qiu Y, Cheng L, Hong Y, Li Z (2016) Relationship between structure and retrogradation properties of corn starch treated with 1,4-α-glucan branching enzyme. Food Hydrocoll 52:868–875CrossRef
12.
Fredrisson H, Silverio J, Andersson R (1998) The influence of amylose and amylopectin characteristics on gelatinization and retrogradation properties of different starches. Carbohyd Polym 35:119–134CrossRef
13.
Bertoft E, Annor GA, Shen X, Rumpagaporn P, Seetharaman K, Hamaker BR (2016) Small differences in amylopectin fine structure may explain large functional differences of starch. Carbohyd Polym 140:113–121CrossRef
14.
Zheng M, Su H, You Q, Zeng S, Zheng B, Zhang Y, Zeng H (2019) An insight into the retrogradation behaviors and molecular structures of lotus seed starch-hydrocolloid blends. Food Chem 295:548–555PubMedCrossRef
15.
Liu R, Xu C, Cong X, Wu T, Song Y, Zhang M (2017) Effects of oligomeric procyanidins on the retrogradation properties of maize starch with different amylose/amylopectin ratios. Food Chem 221:2010–2017PubMedCrossRef
16.
Fu Z, BeMiller JN (2017) Effect of hydrocolloids and salts on retrogradation of native and modified maize starch. Food Hydrocolloids 69:36–48CrossRef
17.
Wang L, Xu J, Fan X, Wang Q, Wang P, Yuan J, Yu Y, Zhang Y, Cui L (2018) The effect of branched limit dextrin on corn and waxy corn gelatinization and retrogradation. Int J Biol Macromol 106:116–122PubMedCrossRef
18.
Ji N, Liu C, Zhang S, Yu J, Xiong L, Sun Q (2017) Effects of chitin nano-whiskers on the gelatinization and retrogradation of maize and potato starches. Food Chem 214 (Supplement C):543–549
19.
Liu L, Yang M, Xu J, Fan X, Gao W, Wang Q, Wang P, Xu B, Yuan J, Yu Y (2020) Exploring the mechanism of pullulan delay potato starch long-term retrogradation from the viewpoint of amylopectin chain motion. Int J Biol Macromol 145:84–91PubMedCrossRef
20.
Chaudhary DS (2008) Understanding amylose crystallinity in starch–clay nanocomposites. J Polym Sci Part B: Polym Phys 46(10):979–987CrossRef
21.
Muller CMO, Laurindo JB, Yamashita F (2011) Effect of nanoclay incorporation method on mechanical and water vapor barrier properties of starch-based films. Ind Crops Prod 33(3):605–610CrossRef
22.
Liu Y, Fan L, Mo X, Yang F, Pang J (2018) Effects of nanosilica on retrogradation properties and structures of thermoplastic cassava starch. J Appl Polym Sci 135(2):45687CrossRef
23.
Liu S, Li X, Chen L, Li L, Li B, Zhu J, Liang X (2017) Investigating the H2O/O2 selective permeability from a view of multi-scale structure of starch/SiO2 nanocomposites. Carbohyd Polym 173:143–149CrossRef
24.
Liu S, Li X, Chen L, Li L, Li B, Zhu J (2017) Understanding physicochemical properties changes from multi-scale structures of starch/CNT nanocomposite films. Int J Biol Macromol 104:1330–1337PubMedCrossRef
25.
Maiti P, Nam PH, Okamoto M, Hasegawa N, Usuki A (2002) Influence of crystallization on intercalation, morphology, and mechanical properties of polypropylene/clay nanocomposites. Macromolecules 35(6):2042–2049CrossRef
26.
Hakim RH, Cailloux J, Santana OO, Bou J, Sánchez-Soto M, Odent J, Raquez JM, Dubois P, Carrasco F, Maspoch ML (2017) PLA/SiO2 composites: Influence of the filler modifications on the morphology, crystallization behavior, and mechanical properties. J Appl Polym Sci 134(40):45367CrossRef
27.
Strawhecker KE, Manias E (2003) Crystallization Behavior of Poly(ethylene oxide) in the Presence of Na+ Montmorillonite Fillers. Chem Mater 15(4):844–849CrossRef
28.
Liu S, Li X, Chen L, Li L, Li B, Zhu J (2018) Tunable d-limonene permeability in starch-based nanocomposite films reinforced by cellulose nanocrystals. J Agric Food Chem 66(4):979–987PubMedCrossRef
29.
Imberty A, Chanzy H, Perez S, Buleon A, Tran V (1988) The double-helical nature of the crystalline part of A-starch. J Mol Biol 201(2):365–378PubMedCrossRef
30.
Jiping P, Shujun W, Jinglin Y, Hongyan L, Jiugao Y, Wenyuan G (2007) Comparative studies on morphological and crystalline properties of B-type and C-type starches by acid hydrolysis. Food Chem 105(3):989–995CrossRef
31.
Schmitt H, Guidez A, Prashantha K, Soulestin J, Lacrampe MF, Krawczak P (2015) Studies on the effect of storage time and plasticizers on the structural variations in thermoplastic starch. Carbohyd Polym 115:364–372CrossRef
32.
van Soest JJG, Hulleman SHD, de Wit D, Vliegenthart JFG (1996) Crystallinity in starch bioplastics. Ind Crops Prod 5(1):11–22CrossRef
33.
Zhang QX, Yu ZZ, Xie XL, Naito K, Kagawa Y (2007) Preparation and crystalline morphology of biodegradable starch/clay nanocomposites. Polymer 48(24):7193–7200CrossRef
34.
Seligra PG, Medina Jaramillo C, Famá L, Goyanes S (2016) Biodegradable and non-retrogradable eco-films based on starch–glycerol with citric acid as crosslinking agent. Carbohyd Polym 138:66–74CrossRef
35.
Wang N, Zhang X, Han N, Bai S (2009) Effect of citric acid and processing on the performance of thermoplastic starch/montmorillonite nanocomposites. Carbohyd Polym 76(1):68–73CrossRef
36.
Baik MY, Dickinson LC, Chinachoti P (2003) Solid-State 13C CP/MAS NMR studies on aging of starch in white bread. J Agric Food Chem 51(5):1242–1248PubMedCrossRef
37.
Garbow JR, Schaefer J (1991) Magic-angle carbon-13 NMR study of wheat flours and doughs. J Agric Food Chem 39(5):877–880CrossRef
38.
Magalhaes NF, Andrade CT (2009) Thermoplastic corn starch/clay hybrids: Effect of clay type and content on physical properties. Carbohyd Polym 75(4):712–718CrossRef
39.
Singh V, Ali SZ, Divakar S (1993) 13C CP/MAS NMR spectroscopy of native and acid modified starches. Starch-Starke 45(2):59–62CrossRef
40.
Zhang B, Chen L, Li X, Li L, Zhang H (2015) Understanding the multi-scale structure and functional properties of starch modulated by glow-plasma: A structure-functionality relationship. Food Hydrocolloids 50(50):228–236CrossRef
Metadaten
Titel
Effect of different surface properties of nanosilica on retrogradation behavior and structures of thermoplastic cassava starch
verfasst von
Yu-Xin Liu
Ze-Sheng Liang
Jia-Neng Liang
Liang-Yan Liao
Publikationsdatum
01.05.2021
Verlag
Springer Netherlands
Erschienen in
Journal of Polymer Research / Ausgabe 5/2021
Print ISSN: 1022-9760
Elektronische ISSN: 1572-8935
DOI
https://doi.org/10.1007/s10965-021-02507-z

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