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Chemistry and Technology of Fuels and Oils
Erschienen in: Chemistry and Technology of Fuels and Oils 5/2023

08.12.2023 | RESEARCH

Catalysis by Ion‑Exchange Resins Derived from Asphaltenes in the Salicylic Acid Acylation Reaction

verfasst von: O. A. Nagornova, L. E. Foss, K. V. Shabalin, D. N. Borisov

Erschienen in: Chemistry and Technology of Fuels and Oils | Ausgabe 5/2023

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Abstract

Acidic and basic ion‑exchange resins were prepared by chemical modification of petroleum asphaltenes. The resulting products were characterized by IR spectroscopy and MALDI mass spectrometry. Feasibility was demonstrated for carrying out catalytic acylation of salicylic acid in the presence of acidic and basic catalysts derived from petroleum asphaltenes to give acetylsalicylic acid. Asphaltene‑derived ion‑exchange resins containing either sulfonic acid (SA) or amino groups (AA) were used as catalysts. These catalyzed reactions gave acetylsalicylic acid in 78% and 73% yield, respectively.
Vorheriger Artikel Change in the Concentration of Stable Free Radicals and Vanadyl Complexes in the Products of Reaction of Petroleum Asphaltenes with Sulfuric Acid
Nächster Artikel Phase Behavior of Kalchinsk Oil in a Wide Range of Thermobaric Conditions

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Metadaten
Titel
Catalysis by Ion‑Exchange Resins Derived from Asphaltenes in the Salicylic Acid Acylation Reaction
verfasst von
O. A. Nagornova
L. E. Foss
K. V. Shabalin
D. N. Borisov
Publikationsdatum
08.12.2023
Verlag
Springer US
Erschienen in
Chemistry and Technology of Fuels and Oils / Ausgabe 5/2023
Print ISSN: 0009-3092
Elektronische ISSN: 1573-8310
DOI
https://doi.org/10.1007/s10553-023-01608-3

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