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2021 | OriginalPaper | Buchkapitel

2. Catalytic Oxidation of Volatile Organic Compounds over Porous Manganese Oxides Prepared via Sol-Gel Method

verfasst von : Miguel Jose Marin Figueredo, Marco Piumetti, Samir Bensaid, Debora Fino, Russo Nunzio

Erschienen in: Nanostructured Catalysts for Environmental Applications

Verlag: Springer International Publishing

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Abstract

A set of transition metal oxides was prepared via a sol-gel synthesis using different metal (Mn, Cu, and Fe) nitrates to ensure a proper manganese to metal ratio in the final product. Specifically, three pure metal oxides (Mn₂O₃, CuO, and Fe₂O₃) and mixed oxides (MnCu₁₅, MnFe₁₅, and MnCu_7.5Fe_7.5) were synthesized and characterized by means of XRD, N₂-physisorption at −196 °C, H₂-TPR, FESEM, and XPS techniques. The catalysts were tested for the catalytic oxidation of volatile organic compounds (VOCs) using two probe molecules, namely ethylene and propylene. As a result, the best reaction rates were observed for the MnCu_7.5Fe_7.5 powder sample and were attributed to the synergistic interactions occurring between the Mn, Cu, and Fe species in the crystalline structure. Similarly, Mn₂O₃ showed a good catalytic performance. The excellent catalytic activity of the oxides was correlated with the high amount of reactive chemisorbed oxygen species located on the surface, since these species are useful for the oxidation of VOCs. As well, the improvement of the catalytic activity corresponded to the enhanced reducibility of the catalysts at lower temperatures (i.e., better lattice-oxygen mobility) observed during the temperature-programmed reduction studies.

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Titel: Catalytic Oxidation of Volatile Organic Compounds over Porous Manganese Oxides Prepared via Sol-Gel Method
verfasst von: Miguel Jose Marin Figueredo
Marco Piumetti
Samir Bensaid
Debora Fino
Russo Nunzio
Verlag: Springer International Publishing
Buch: Nanostructured Catalysts for Environmental Applications
Print ISBN: 978-3-030-58933-2

Electronic ISBN: 978-3-030-58934-9

Copyright-Jahr: 2021
DOI: https://doi.org/10.1007/978-3-030-58934-9_2

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