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10.02.2021 | Energy materials

Cd(II)-based metal–organic framework-derived CdS photocatalysts for enhancement of photocatalytic activity

verfasst von: Ligang Ma, Xiaoqian Ai, Xingming Yang, Xiaoxiao Cao, Dianrong Han, Xiang Song, Huilin Jiang, Wei Yang, Senlin Yan, Xiaoshan Wu

Erschienen in: Journal of Materials Science | Ausgabe 14/2021

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Abstract

CdS with band gaps of 2.4 eV is an essential semiconductor for optoelectronic and photocatalytic devices. In this study, Cd(II)-based metal–organic framework (MOF)-derived CdS photocatalysts are successfully synthesized using a facile chemical bath deposition method. CdS precursors are derived from Cd-based MOFs that H₂S gas was bubbled into as S source. Four kinds of CdS nano-photocatalyst are obtained through controlling the thermal annealing process of CdS precursors. The excellent photocatalytic performance of CdS and the benefits of the porous and molecular sieving properties of MOFs are well integrated. The evolution of the morphology, microstructure, and optical properties are investigated by various characterization methods. The results indicate that the sample with an annealing temperature of 500 °C is primarily nanosheet structures with sizes ranging from 20 to 30 nm, which construct a porous network structure, Moreover, the best photodegradation activity is obtained by illuminating the catalyst in rhodamine-B dye solution for 80 min and reducing the absorption intensity to nearly zero. Finally, the pollutant degradation mechanism was analyzed in detail.

Vorheriger Artikel Photoelectrochemical performance of MWCNT–Ag–ZnO ternary hybrid: a study of Ag loading and MWCNT garnishing

Nächster Artikel Ti-grafted MIL-101 as hydrophilic catalyst for efficient oxidative desulfurization of dibenzothiophene with hydrogen peroxide

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Singh V (2019) Fundamental issues of environmental crisis and sustainability of choices. J Public Policy Environ Manag 2(3):31–37

Tong H et al (2012) Nano-photocatalytic materials: possibilities and challenges. Adv Mater 24(2):229–251

Sharma VK, Feng M (2019) Water depollution using metal–organic frameworks-catalyzed advanced oxidation processes: a review. J Hazard Mater 372:3–16

Hosseini SE, Wahid MA (2016) Hydrogen production from renewable and sustainable energy resources: promising green energy carrier for clean development. Renew Sustain Energy Rev 57:850–866

Kabir E et al (2018) Solar energy: potential and future prospects. Renew Sustain Energy Rev 82:894–900

Ma L et al (2020) Development of a new synthetic strategy for highly reduced graphene oxide-CdS quantum-dot nanocomposites and their photocatalytic activity. J Alloys Compd 828:154406

Li K et al (2016) Hexagonal@ cubic CdS core@ shell nanorod photocatalyst for highly active production of H₂ with unprecedented stability. Adv Mater 28(40):8906–8911

Ma L et al (2016) Catalyst- and template-free low-temperature in situ growth of n-type CdS nanowire on p-type CdTe film and p–n heterojunction properties. Sci Rep 6(1):38858

Yuan L et al (2016) Investigation of sodium distribution in CuZnSnS thin films and its effects on the performance of the solar cells. Mater Res Bull 84:314–322

10.

Low J et al (2019) In situ irradiated X-ray photoelectron spectroscopy investigation on a direct Z-scheme TiO₂/CdS composite film photocatalyst. Adv Mater 31(6):1802981

11.

Ma L et al (2011) Microstructures and optical properties of Cu-doped ZnO films prepared by radio frequency reactive magnetron sputtering. Appl Surf Sci 257(23):10036–10041

12.

Ma L, Ai X, Wu X (2017) Effect of substrate and Zn doping on the structural, optical and electrical properties of CdS thin films prepared by CBD method. J Alloys Compd 691:399–406

13.

Ma L et al (2015) Facile method to prepare CdS nanostructure based on the CdTe films. Appl Surf Sci 349:740–745

14.

Ma L et al (2016) Catalyst-and template-free low-temperature in situ growth of n-type CdS nanowire on p-type CdTe film and p–n heterojunction properties. Sci Rep 6:38858

15.

Sahoo AK et al (2014) Graphene nanocomposites of CdS and ZnS in effective water purification. J Nanopart Res 16(7):2473

16.

Zyoud AH et al (2010) CdS-sensitized TiO₂ in phenazopyridine photo-degradation: catalyst efficiency, stability and feasibility assessment. J Hazard Mater 173(1–3):318–325

17.

Zhao J-H et al (2019) Enhanced photocatalytic hydrogen evolution over bimetallic zeolite imidazole framework-encapsulated CdS nanorods. Dalton Trans 48(11):3560–3565

18.

Yao W et al (2013) Enhancing solar hydrogen production via modified photochemical treatment of Pt/CdS photocatalyst. Catal Today 199:42–47

19.

Mecklenburg M et al (2012) Aerographite: ultra lightweight, flexible nanowall, carbon microtube material with outstanding mechanical performance. Adv Mater 24(26):3486–3490

20.

Yang Q, Xu Q, Jiang H-L (2017) Metal–organic frameworks meet metal nanoparticles: synergistic effect for enhanced catalysis. Chem Soc Rev 46(15):4774–4808

21.

Lin Y-Z et al (2020) Metal–organic framework-derived CdS–NiO heterostructures with modulated morphology and enhanced photocatalytic hydrogen evolution activity in pure water. J Mater Chem C 8(29):10071–10077

22.

Liu J et al (2017) Design strategies toward advanced MOF-derived electrocatalysts for energy-conversion reactions. Adv Energy Mater 7(23):1700518

23.

Huang J et al (2017) Controllable synthesis of highly uniform cuboid-shape MOFs and their derivatives for lithium-ion battery and photocatalysis applications. Chem Eng J 322:281–292

24.

Zhao X et al (2018) An efficient, visible-light-driven, hydrogen evolution catalyst NiS/Zn_xCd₁₋_xS nanocrystal derived from a metal–organic framework. Angew Chem 130(31):9938–9942

25.

Lu L et al (2019) Metal–organic framework-derived heterojunctions as nanocatalysts for photocatalytic hydrogen production. Inorg Chem Front 6(12):3456–3467

26.

Liu W et al (2020) An efficient and stable MoS₂/Zn_0.5Cd_0.5S nanocatalyst for photocatalytic hydrogen evolution. Chem Eur J 26(53):12206–12211

27.

Li K et al (2019) Versatile functional porous cobalt–nickel phosphide–carbon cocatalyst derived from a metal–organic framework for boosting the photocatalytic activity of graphitic carbon nitride. ACS Appl Mater Interfaces 11(32):28918–28927

28.

Xu M-L et al (2020) Hierarchical-metal–organic framework-templated Cu_0.5Zn_0.5In₂S₄-rGO-gC₃N₄: flexible synthesis and enhanced photocatalytic activity. J Mater Chem A 8(42):22124–22133

29.

Zhang R et al (2018) Metal–organic frameworks-derived hierarchical Co₃O₄ structures as efficient sensing materials for acetone detection. ACS Appl Mater Interfaces 10(11):9765–9773

30.

Lee DY et al (2015) Facile interfacial charge transfer across hole doped cobalt-based MOFs/TiO₂ nano-hybrids making MOFs light harvesting active layers in solar cells. J Mater Chem A 3(45):22669–22676

31.

Zhang Y et al (2018) Luminescent sensors based on metal-organic frameworks. Coord Chem Rev 354:28–45

32.

Qu C et al (2016) Nickel-based pillared MOFs for high-performance supercapacitors: design, synthesis and stability study. Nano Energy 26:66–73

33.

Zou F et al (2014) MOF-derived porous ZnO/ZnFe₂O₄/C octahedra with hollow interiors for high-rate lithium-ion batteries. Adv Mater 26(38):6622–6628

34.

Liu S et al (2013) Nanosized Cu-MOFs induced by graphene oxide and enhanced gas storage capacity. Energy Environ Sci 6(3):818–823

35.

Giménez-Marqués M et al (2019) Exploring the catalytic performance of a series of bimetallic MIL-100 (Fe, Ni) MOFs. J Mater Chem A 7(35):20285–20292

36.

Tang X et al (2017) Co-doped Zn_1–_xCd_xS nanocrystals from metal–organic framework precursors: porous microstructure and efficient photocatalytic hydrogen evolution. Dalton Trans 46(32):10553–10557

37.

Ma L et al (2019) Facile and novel in situ low-temperature growth of Cu₂S nanoarrays based on Cu substrates. Appl Phys A 125(6):373

38.

Tsai C-W et al (2019) Photoluminescence of metal-imidazolate complexes with Cd (II), Zn (II), Co (II) and Ni (II) cation nodes and 2-methylimidazole organic linker. J Lumin 207:454–459

39.

Tsai CW et al (2019) Photoluminescence of metal-imidazolate complexes with Cd(II), Zn(II), Co(II) and Ni(II) cation nodes and 2-methylimidazole organic linker. J Lumin 207:454–459

40.

Nagaraju G et al (2009) A facile low temperature hydrothermal route to CdSO₄ nanotubes/rods. Mater Lett 63(3–4):492–495

41.

Thambidurai M et al (2010) Strong quantum confinement effect in nanocrystalline CdS. J Mater Sci 45(12):3254–3258. https://doi.org/10.1007/s10853-010-4333-7CrossRef

42.

Al Balushi BSM et al (2018) Hydrothermal synthesis of CdS sub-microspheres for photocatalytic degradation of pharmaceuticals. Appl Surf Sci 457:559–565

43.

Chang X et al (2015) A miniature room temperature formaldehyde sensor with high sensitivity and selectivity using CdSO₄ modified ZnO nanoparticles. RSC Adv 5(92):75098–75104

44.

Ganesh RS et al (2017) Growth, microstructure, structural and optical properties of PVP-capped CdS nanoflowers for efficient photocatalytic activity of Rhodamine B. Mater Res Bull 94:190–198

45.

Ganesh RS et al (2017) Visible light induced photocatalytic degradation of methylene blue and rhodamine B from the catalyst of CdS nanowire. Chem Phys Lett 684:126–134

46.

Bera R, Kundu S, Patra A (2015) 2D hybrid nanostructure of reduced graphene oxide–CdS nanosheet for enhanced photocatalysis. ACS Appl Mater Interfaces 7(24):13251–13259

47.

Johnson JA et al (2015) Porphyrin-metalation-mediated tuning of photoredox catalytic properties in metal–organic frameworks. ACS Catal 5(9):5283–5291

48.

Zhu L et al (2018) Hierarchical ZnO decorated with CeO₂ nanoparticles as the direct Z-scheme heterojunction for enhanced photocatalytic activity. ACS Appl Mater Interfaces 10(46):39679–39687

Titel: Cd(II)-based metal–organic framework-derived CdS photocatalysts for enhancement of photocatalytic activity
verfasst von: Ligang Ma
Xiaoqian Ai
Xingming Yang
Xiaoxiao Cao
Dianrong Han
Xiang Song
Huilin Jiang
Wei Yang
Senlin Yan
Xiaoshan Wu
Publikationsdatum: 10.02.2021
Verlag: Springer US
Erschienen in: Journal of Materials Science / Ausgabe 14/2021
Print ISSN: 0022-2461
Elektronische ISSN: 1573-4803
DOI: https://doi.org/10.1007/s10853-021-05855-9

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