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Journal of Sol-Gel Science and Technology
Erschienen in: Journal of Sol-Gel Science and Technology 3/2019

31.01.2019 | Original Paper: Sol-gel and hybrid materials for catalytic, photoelectrochemical and sensor applications

CO2 hydrogenation to methanol over CuO-ZnO-ZrO2 catalyst prepared by polymeric precursor method

verfasst von: Dawei Chen, Dongsen Mao, Guo Wang, Xiaoming Guo, Jun Yu

Erschienen in: Journal of Sol-Gel Science and Technology | Ausgabe 3/2019

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Abstract

A series of CuO-ZnO-ZrO2 catalysts were synthesized by the polymeric precursor method, and characterized by X-ray diffraction (XRD), N2 physisorption, X-ray photoelectron spectroscopy (XPS), scanning electron microscopy (SEM), transmission electron microscopy (TEM), temperature-programmed reduction with H2 (H2-TPR), reactive N2O adsorption, and adsorption of H2 and CO2 followed by temperature-programmed desorption (H2-TPD, CO2-TPD) techniques. The catalytic performances of all samples for methanol synthesis from hydrogenation of CO2 were evaluated under the experimental condition of 240 °C, 3 MPa, and SV = 1800–6000 mL·gcat−1·h−1. The effects of the calcination temperature on physicochemical and catalytic properties of all catalysts were investigated. The results indicate that the catalyst prepared under 400 °C calcination possesses the smallest Cu crystallites, largest metallic Cu surface area, and thus exhibits the highest methanol yield.
Vorheriger Artikel Correction to: Synthesis and characterization of CuZnO@GO nanocomposites and their enhanced antibacterial activity with visible light
Nächster Artikel Sol–gel synthesis of gelatin–zirconium(IV) tungstophosphate nanocomposite ion exchanger and application for the estimation of Cd(II) ions

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Metadaten
Titel
CO2 hydrogenation to methanol over CuO-ZnO-ZrO2 catalyst prepared by polymeric precursor method
verfasst von
Dawei Chen
Dongsen Mao
Guo Wang
Xiaoming Guo
Jun Yu
Publikationsdatum
31.01.2019
Verlag
Springer US
Erschienen in
Journal of Sol-Gel Science and Technology / Ausgabe 3/2019
Print ISSN: 0928-0707
Elektronische ISSN: 1573-4846
DOI
https://doi.org/10.1007/s10971-019-04924-5

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