Skip to main content

2019 | OriginalPaper | Buchkapitel

12. CO2 Storage on Metal-Organic Frameworks

verfasst von : Yunsheng Ma, Hideki Tanaka, Ryotaro Matsuda

Erschienen in: Nanoporous Materials for Gas Storage

Verlag: Springer Singapore

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config
loading …

Abstract

Metal-organic frameworks (MOFs) have received continuous attention because of their highly porous, diversified structures and potential applications as novel adsorbents. In this chapter, the recent progress in developing MOFs for CO2 capture is reviewed. Several strategies being used to improve CO2 adsorption uptake at low pressure are highlighted. These strategies are generation of interaction sites in the pores as well as controlling of pore size of MOFs, building of flexible MOFs, and construction of water-stable MOFs. In addition, the high-pressure CO2 adsorption in highly porous MOFs is reviewed. At last, the studies of CO2-loaded structures with crystallographic technique are summarized.

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Literatur
6.
9.
Zurück zum Zitat (a) Wade CR, Dincã M (2012) Investigation of the synthesis, activation, and isosteric heats of CO2 adsorption of the isostructural series of metal–organic frameworks M3(BTC)2 (M = Cr, Fe, Ni, Cu, Mo, Ru). Dalton Trans 41(26):7931–7938. https://doi.org/10.1039/c2dt30372h; (b) Ketrat S, Maihom T, Wannakao S, Probst M, Nokbin S, Limtrakul J (2017) Coordinatively unsaturated metal-organic frameworks M3(btc)2 (M = Cr, Fe, Co, Ni, Cu, and Zn) catalyzing the oxidation of CO by N2O: insight from DFT calculations. Inorg Chem 56(22):14005–14012. https://doi.org/10.1021/acs.inorgchem.7b02143 (a) Wade CR, Dincã M (2012) Investigation of the synthesis, activation, and isosteric heats of CO2 adsorption of the isostructural series of metal–organic frameworks M3(BTC)2 (M = Cr, Fe, Ni, Cu, Mo, Ru). Dalton Trans 41(26):7931–7938. https://​doi.​org/​10.​1039/​c2dt30372h; (b) Ketrat S, Maihom T, Wannakao S, Probst M, Nokbin S, Limtrakul J (2017) Coordinatively unsaturated metal-organic frameworks M3(btc)2 (M = Cr, Fe, Co, Ni, Cu, and Zn) catalyzing the oxidation of CO by N2O: insight from DFT calculations. Inorg Chem 56(22):14005–14012. https://​doi.​org/​10.​1021/​acs.​inorgchem.​7b02143
15.
Zurück zum Zitat Qin JS, Du DY, Li WL, Zhang JP, Li SL, Su ZM, Wang XL, Xu Q, Shao KZ, Lan YQ (2012) N-rich zeolite-like metal–organic framework with sodalite topology: high CO2 uptake, selective gas adsorption and efficient drug delivery. Chem Sci 3:2114–2118. https://doi.org/10.1039/C2SC00017B CrossRef Qin JS, Du DY, Li WL, Zhang JP, Li SL, Su ZM, Wang XL, Xu Q, Shao KZ, Lan YQ (2012) N-rich zeolite-like metal–organic framework with sodalite topology: high CO2 uptake, selective gas adsorption and efficient drug delivery. Chem Sci 3:2114–2118. https://​doi.​org/​10.​1039/​C2SC00017B CrossRef
22.
Zurück zum Zitat Hwang YK, Hong DY, Chang JS, Jhung SH, Seo YK, Kim J, Vimont A, Daturi M, Serre C, Férey G (2008) Amine grafting on coordinatively unsaturated metal centers of MOFs: consequences for catalysis and metal encapsulation. Angew Chem Int Ed 47(22):4144–4148. https://doi.org/10.1002/anie.200705998 CrossRef Hwang YK, Hong DY, Chang JS, Jhung SH, Seo YK, Kim J, Vimont A, Daturi M, Serre C, Férey G (2008) Amine grafting on coordinatively unsaturated metal centers of MOFs: consequences for catalysis and metal encapsulation. Angew Chem Int Ed 47(22):4144–4148. https://​doi.​org/​10.​1002/​anie.​200705998 CrossRef
24.
25.
Zurück zum Zitat Lee WR, Hwang SY, Ryu DW, Lim KS, Han SS, Moon D, Choi J, Hong CS (2014) Diamine-functionalized metal–organic framework: exceptionally high CO2 capacities from ambient air and flue gas, ultrafast CO2 uptake rate, and adsorption mechanism. Energy Environ Sci 7:744–751. https://doi.org/10.1039/C3EE42328J CrossRef Lee WR, Hwang SY, Ryu DW, Lim KS, Han SS, Moon D, Choi J, Hong CS (2014) Diamine-functionalized metal–organic framework: exceptionally high CO2 capacities from ambient air and flue gas, ultrafast CO2 uptake rate, and adsorption mechanism. Energy Environ Sci 7:744–751. https://​doi.​org/​10.​1039/​C3EE42328J CrossRef
26.
31.
Zurück zum Zitat Liu B, Yang Q, Xue C, Zhong C, Chen B, Smit B (2008) Enhanced adsorption selectivity of hydrogen/methane mixtures in metal−organic frameworks with interpenetration: a molecular simulation study. J Phys Chem C 112(26):9854–9860. https://doi.org/10.1021/jp802343n CrossRef Liu B, Yang Q, Xue C, Zhong C, Chen B, Smit B (2008) Enhanced adsorption selectivity of hydrogen/methane mixtures in metal−organic frameworks with interpenetration: a molecular simulation study. J Phys Chem C 112(26):9854–9860. https://​doi.​org/​10.​1021/​jp802343n CrossRef
33.
Zurück zum Zitat Ramsahye NA, Maurin G, Bourrelly S, Llewellyn PL, Devic T, Serre C, Loiseau T, Férey G (2007) Adsorption of CO2 in metal organic frameworks of different metal centres: Grand Canonical Monte Carlo simulations compared to experiments. Adsorption 13(5–6):461–467. https://doi.org/10.1007/s10450-007-9025-5 CrossRef Ramsahye NA, Maurin G, Bourrelly S, Llewellyn PL, Devic T, Serre C, Loiseau T, Férey G (2007) Adsorption of CO2 in metal organic frameworks of different metal centres: Grand Canonical Monte Carlo simulations compared to experiments. Adsorption 13(5–6):461–467. https://​doi.​org/​10.​1007/​s10450-007-9025-5 CrossRef
34.
Zurück zum Zitat Vimont A, Travert A, Bazin P, Lavalley JC, Daturi M, Serre C, Férey G, Bourrelly S, Llewellyn PL (2007) Evidence of CO2 molecule acting as an electron acceptor on a nanoporous metal–organic-framework MIL-53 or Cr3+(OH)(O2C–C6H4–CO2). Chem Commun:3291–3293. https://doi.org/10.1039/B703468G Vimont A, Travert A, Bazin P, Lavalley JC, Daturi M, Serre C, Férey G, Bourrelly S, Llewellyn PL (2007) Evidence of CO2 molecule acting as an electron acceptor on a nanoporous metal–organic-framework MIL-53 or Cr3+(OH)(O2C–C6H4–CO2). Chem Commun:3291–3293. https://​doi.​org/​10.​1039/​B703468G
40.
Zurück zum Zitat Hamon L, Llewellyn PL, Devic T, Ghoufi A, Clet G, Guillerm V, Pirngruber GD, Maurin G, Serre C, Driver G, Beek W, Jolimaître E, Vimont A, Daturi M, Férey G (2009) Co-adsorption and separation of CO2−CH4 mixtures in the highly flexible MIL-53(Cr) MOF. J Am Chem Soc 131(47):17490–17499. https://doi.org/10.1021/ja907556q CrossRef Hamon L, Llewellyn PL, Devic T, Ghoufi A, Clet G, Guillerm V, Pirngruber GD, Maurin G, Serre C, Driver G, Beek W, Jolimaître E, Vimont A, Daturi M, Férey G (2009) Co-adsorption and separation of CO2−CH4 mixtures in the highly flexible MIL-53(Cr) MOF. J Am Chem Soc 131(47):17490–17499. https://​doi.​org/​10.​1021/​ja907556q CrossRef
43.
Zurück zum Zitat Mason JA, Oktawiec J, Taylor MK, Hudson MR, Rodriguez J, Bachman JE, Gonzalez MI, Cervellino A, Guagliardi A, Brown CM, Llewellyn PL, Masciocchi N, Long JR (2015) Methane storage in flexible metal–organic frameworks with intrinsic thermal management. Nature 527(7578):357–361. https://doi.org/10.1038/nature15732 CrossRef Mason JA, Oktawiec J, Taylor MK, Hudson MR, Rodriguez J, Bachman JE, Gonzalez MI, Cervellino A, Guagliardi A, Brown CM, Llewellyn PL, Masciocchi N, Long JR (2015) Methane storage in flexible metal–organic frameworks with intrinsic thermal management. Nature 527(7578):357–361. https://​doi.​org/​10.​1038/​nature15732 CrossRef
45.
Zurück zum Zitat Low JJ, Benin AI, Jakubczak P, Abrahamian JF, Faheem SA, Willis RR Virtual high throughput screening confirmed experimentally: porous coordination polymer hydration. J Am Chem Soc 131(43):15834–15842. https://doi.org/10.1021/ja9061344 Low JJ, Benin AI, Jakubczak P, Abrahamian JF, Faheem SA, Willis RR Virtual high throughput screening confirmed experimentally: porous coordination polymer hydration. J Am Chem Soc 131(43):15834–15842. https://​doi.​org/​10.​1021/​ja9061344
48.
Zurück zum Zitat Soubeyrand-Lenoir E, Vagner C, Yoon JW, Bazin P, Ragon F, Hwang YK, Serre C, Chang JS, Llewellyn PL (2012) How water fosters a remarkable 5-fold increase in low-pressure CO2 uptake within mesoporous MIL-100(Fe). J Am Chem Soc 134(24):10174–10181. https://doi.org/10.1021/ja302787x CrossRef Soubeyrand-Lenoir E, Vagner C, Yoon JW, Bazin P, Ragon F, Hwang YK, Serre C, Chang JS, Llewellyn PL (2012) How water fosters a remarkable 5-fold increase in low-pressure CO2 uptake within mesoporous MIL-100(Fe). J Am Chem Soc 134(24):10174–10181. https://​doi.​org/​10.​1021/​ja302787x CrossRef
53.
Zurück zum Zitat Farha OK, Yazaydin AO, Eryazici I, Malliakas CD, Hauser BG, Kanatzidis MG, Nguyen ST, Snurr RQ, Hupp JT (2010) De novo synthesis of a metal–organic framework material featuring ultrahigh surface area and gas storage capacities. Nat Chem 2:944–948. https://doi.org/10.1038/NCHEM.834 CrossRef Farha OK, Yazaydin AO, Eryazici I, Malliakas CD, Hauser BG, Kanatzidis MG, Nguyen ST, Snurr RQ, Hupp JT (2010) De novo synthesis of a metal–organic framework material featuring ultrahigh surface area and gas storage capacities. Nat Chem 2:944–948. https://​doi.​org/​10.​1038/​NCHEM.​834 CrossRef
54.
Zurück zum Zitat Alezi D, Belmabkhout Y, Suyetin M, Bhatt PM, Weselinski LJ, Solovyeva V, Adil K, Spanopoulos I, Trikalitis PN, Emwas AH, Eddaoudi M (2015) MOF crystal chemistry paving the way to gas storage needs: aluminum-based soc-MOF for CH4, O2, and CO2 storage. J Am Chem Soc 137(41):13308–13318. https://doi.org/10.1021/jacs.5b07053 CrossRef Alezi D, Belmabkhout Y, Suyetin M, Bhatt PM, Weselinski LJ, Solovyeva V, Adil K, Spanopoulos I, Trikalitis PN, Emwas AH, Eddaoudi M (2015) MOF crystal chemistry paving the way to gas storage needs: aluminum-based soc-MOF for CH4, O2, and CO2 storage. J Am Chem Soc 137(41):13308–13318. https://​doi.​org/​10.​1021/​jacs.​5b07053 CrossRef
61.
Zurück zum Zitat Llewellyn PL, Bourrelly S, Serre C, Vimont A, Daturi M, Hamon L, Weireld GD, Chang JS, Hong DY, Hwang YK, Jhung SH, Ferey G (2008) High uptakes of CO2 and CH4 in mesoporous metal—organic frameworks MIL-100 and MIL-101. Langmuir 24(14):7245–7250. https://doi.org/10.1021/la800227x CrossRef Llewellyn PL, Bourrelly S, Serre C, Vimont A, Daturi M, Hamon L, Weireld GD, Chang JS, Hong DY, Hwang YK, Jhung SH, Ferey G (2008) High uptakes of CO2 and CH4 in mesoporous metal—organic frameworks MIL-100 and MIL-101. Langmuir 24(14):7245–7250. https://​doi.​org/​10.​1021/​la800227x CrossRef
64.
Zurück zum Zitat Bourrelly S, Llewellyn PL, Serre C, Millange F, Loiseau T, Férey G (2005) Different adsorption behaviors of methane and carbon dioxide in the isotypic nanoporous metal terephthalates MIL-53 and MIL-47. J Am Chem Soc 127(39):13519–13521. https://doi.org/10.1021/ja054668v CrossRef Bourrelly S, Llewellyn PL, Serre C, Millange F, Loiseau T, Férey G (2005) Different adsorption behaviors of methane and carbon dioxide in the isotypic nanoporous metal terephthalates MIL-53 and MIL-47. J Am Chem Soc 127(39):13519–13521. https://​doi.​org/​10.​1021/​ja054668v CrossRef
65.
Zurück zum Zitat Wiersum AD, Soubeyrand-Lenoir E, Yang QY, Moulin B, Guillerm V, Yahia MB, Bourrelly S, Vimont A, Miller S, Vagner C, Daturi M, Clet G, Serre C, Maurin G, Llewellyn PL (2011) An evaluation of UiO-66 for gas-based applications. Chem Asian J 6(12):3270–3280. https://doi.org/10.1002/asia.201100201 CrossRef Wiersum AD, Soubeyrand-Lenoir E, Yang QY, Moulin B, Guillerm V, Yahia MB, Bourrelly S, Vimont A, Miller S, Vagner C, Daturi M, Clet G, Serre C, Maurin G, Llewellyn PL (2011) An evaluation of UiO-66 for gas-based applications. Chem Asian J 6(12):3270–3280. https://​doi.​org/​10.​1002/​asia.​201100201 CrossRef
66.
Zurück zum Zitat (a) Matsuda R, Kitaura R, Kitagawa S, Kubota Y, Belosludov RV, Kobayashi TC, Sakamoto H, Chiba T, Takata M, Kawazoe Y, Mita Y (2005) Highly controlled acetylene accommodation in a metal–organic microporous material. Nature 436(7048):238–241. https://doi.org/10.1038/nature03852; (b) Kubota Y, Takata M, Matsuda R, Kitaura R, Kitagawa S, Kobayashi TC (2006) Metastable sorption state of a metal–organic porous material determined by in situ synchrotron powder diffraction. Angew Chem Int Ed 45(30):4932–4936. https://doi.org/10.1002/anie.200600976 (a) Matsuda R, Kitaura R, Kitagawa S, Kubota Y, Belosludov RV, Kobayashi TC, Sakamoto H, Chiba T, Takata M, Kawazoe Y, Mita Y (2005) Highly controlled acetylene accommodation in a metal–organic microporous material. Nature 436(7048):238–241. https://​doi.​org/​10.​1038/​nature03852; (b) Kubota Y, Takata M, Matsuda R, Kitaura R, Kitagawa S, Kobayashi TC (2006) Metastable sorption state of a metal–organic porous material determined by in situ synchrotron powder diffraction. Angew Chem Int Ed 45(30):4932–4936. https://​doi.​org/​10.​1002/​anie.​200600976
68.
Zurück zum Zitat Ma Y, Matsuda R, Sato H, Hijikata Y, Li L, Kusaka S, Foo M, Xue F, Akiyama G, Yuan R, Kitagawa S (2005) A convenient strategy for designing a soft nanospace: an atomic exchange in a ligand with isostructural frameworks. J Am Chem Soc 137(50):15825–15832. https://doi.org/10.1021/jacs.5b09666 CrossRef Ma Y, Matsuda R, Sato H, Hijikata Y, Li L, Kusaka S, Foo M, Xue F, Akiyama G, Yuan R, Kitagawa S (2005) A convenient strategy for designing a soft nanospace: an atomic exchange in a ligand with isostructural frameworks. J Am Chem Soc 137(50):15825–15832. https://​doi.​org/​10.​1021/​jacs.​5b09666 CrossRef
69.
71.
Zurück zum Zitat Miller SR, Wright PA, Devic T, Serre C, Férey G, Llewellyn PL, Denoyel R, Gaberova L, Filinchuk Y (2009) Single crystal X-ray diffraction studies of carbon dioxide and fuel-related gases adsorbed on the small pore scandium terephthalate metal organic framework, Sc2(O2CC6H4CO2)3. Langmuir 25(6):3618–3626. https://doi.org/10.1021/la803788u CrossRef Miller SR, Wright PA, Devic T, Serre C, Férey G, Llewellyn PL, Denoyel R, Gaberova L, Filinchuk Y (2009) Single crystal X-ray diffraction studies of carbon dioxide and fuel-related gases adsorbed on the small pore scandium terephthalate metal organic framework, Sc2(O2CC6H4CO2)3. Langmuir 25(6):3618–3626. https://​doi.​org/​10.​1021/​la803788u CrossRef
74.
Zurück zum Zitat Serre C, Bourrelly S, Vimont A, Ramsahye NA, Maurin G, Llewellyn PL, Daturi M, Filinchuk Y, Leynaud O, Barnes P, Férey G (2007) An explanation for the very large breathing effect of a metal–organic framework during CO2 adsorption. Adv Mater 19(17):2246–2251. https://doi.org/10.1002/adma.200602645 CrossRef Serre C, Bourrelly S, Vimont A, Ramsahye NA, Maurin G, Llewellyn PL, Daturi M, Filinchuk Y, Leynaud O, Barnes P, Férey G (2007) An explanation for the very large breathing effect of a metal–organic framework during CO2 adsorption. Adv Mater 19(17):2246–2251. https://​doi.​org/​10.​1002/​adma.​200602645 CrossRef
75.
Zurück zum Zitat Dietzel PDC, Johnsen RE, Fjellvåg H, Bordiga S, Groppo E, Chavan S, Blom R Adsorption properties and structure of CO2 adsorbed on open coordination sites of metal–organic framework Ni2(dhtp) from gas adsorption, IR spectroscopy and X-ray diffraction. Chem Commun:5125–5127. https://doi.org/10.1039/B810574J Dietzel PDC, Johnsen RE, Fjellvåg H, Bordiga S, Groppo E, Chavan S, Blom R Adsorption properties and structure of CO2 adsorbed on open coordination sites of metal–organic framework Ni2(dhtp) from gas adsorption, IR spectroscopy and X-ray diffraction. Chem Commun:5125–5127. https://​doi.​org/​10.​1039/​B810574J
77.
Zurück zum Zitat Leclerc H, Devic T, Devautour-Vinot S, Bazin P, Audebrand N, Férey G, Daturi M, Vimont A, Clet G (2011) Influence of the oxidation state of the metal center on the flexibility and adsorption properties of a porous metal organic framework: MIL-47(V). J Phys Chem C 115(40):19828–19840. https://doi.org/10.1021/jp206655y CrossRef Leclerc H, Devic T, Devautour-Vinot S, Bazin P, Audebrand N, Férey G, Daturi M, Vimont A, Clet G (2011) Influence of the oxidation state of the metal center on the flexibility and adsorption properties of a porous metal organic framework: MIL-47(V). J Phys Chem C 115(40):19828–19840. https://​doi.​org/​10.​1021/​jp206655y CrossRef
78.
Zurück zum Zitat Henke S, Wieland DCF, Meilikhov M, Paulus M, Sternemann C, Yusenko K, Fischer RA (2011) Multiple phase-transitions upon selective CO2 adsorption in an alkyl ether functionalized metal–organic framework—an in situ X-ray diffraction study. CrystEngComm 13:6399–6404. https://doi.org/10.1039/C1CE05446E CrossRef Henke S, Wieland DCF, Meilikhov M, Paulus M, Sternemann C, Yusenko K, Fischer RA (2011) Multiple phase-transitions upon selective CO2 adsorption in an alkyl ether functionalized metal–organic framework—an in situ X-ray diffraction study. CrystEngComm 13:6399–6404. https://​doi.​org/​10.​1039/​C1CE05446E CrossRef
79.
Zurück zum Zitat Devic T, Salles F, Bourrelly S, Moulin B, Maurin G, Horcajada P, Serre C, Vimont A, Lavalley JC, Leclerc H, Clet G, Daturi M, Llewellyn PL, Filinchuk Y, Férey G (2012) Effect of the organic functionalization of flexible MOFs on the adsorption of CO2. J Mater Chem 22:10266–10273. https://doi.org/10.1039/C2JM15887F CrossRef Devic T, Salles F, Bourrelly S, Moulin B, Maurin G, Horcajada P, Serre C, Vimont A, Lavalley JC, Leclerc H, Clet G, Daturi M, Llewellyn PL, Filinchuk Y, Férey G (2012) Effect of the organic functionalization of flexible MOFs on the adsorption of CO2. J Mater Chem 22:10266–10273. https://​doi.​org/​10.​1039/​C2JM15887F CrossRef
80.
Zurück zum Zitat Chen L, Mowat JP, Fairen-Jimenez D, Morrison CA, Thompson SP, Wright PA, Duren T (2013) Elucidating the breathing of the metal–organic framework MIL-53(Sc) with ab initio molecular dynamics simulations and in situ X-ray powder diffraction experiments. J Am Chem Soc 135(42):15763–15773. https://doi.org/10.1021/ja403453g CrossRef Chen L, Mowat JP, Fairen-Jimenez D, Morrison CA, Thompson SP, Wright PA, Duren T (2013) Elucidating the breathing of the metal–organic framework MIL-53(Sc) with ab initio molecular dynamics simulations and in situ X-ray powder diffraction experiments. J Am Chem Soc 135(42):15763–15773. https://​doi.​org/​10.​1021/​ja403453g CrossRef
81.
Zurück zum Zitat (a) Tanaka H, Hiraide S, Kondo A, Miyahara MT (2015) Modeling and visualization of CO2 adsorption on elastic layer-structured metal–organic framework-11: toward a better understanding of gate adsorption behavior. J Phys Chem C 119(21):11533–11543. https://doi.org/10.1021/jp512870p; (b) Hiraide S, Tanaka H, Miyahara MT (2016) Understanding gate adsorption behaviour of CO2 on elastic layer-structured metal–organic framework-11. Dalton Trans 45:4193–4202. https://doi.org/10.1039/C5DT03476K (a) Tanaka H, Hiraide S, Kondo A, Miyahara MT (2015) Modeling and visualization of CO2 adsorption on elastic layer-structured metal–organic framework-11: toward a better understanding of gate adsorption behavior. J Phys Chem C 119(21):11533–11543. https://​doi.​org/​10.​1021/​jp512870p; (b) Hiraide S, Tanaka H, Miyahara MT (2016) Understanding gate adsorption behaviour of CO2 on elastic layer-structured metal–organic framework-11. Dalton Trans 45:4193–4202. https://​doi.​org/​10.​1039/​C5DT03476K
82.
Zurück zum Zitat Wu H, Simmons JM, Srinivas G, Zhou W, Yildirim T (2010) Adsorption sites and binding nature of CO2 in prototypical metal−organic frameworks: a combined neutron diffraction and first-principles study. J Phys Chem Lett 1(13):1946–1951. https://doi.org/10.1021/jz100558r CrossRef Wu H, Simmons JM, Srinivas G, Zhou W, Yildirim T (2010) Adsorption sites and binding nature of CO2 in prototypical metal−organic frameworks: a combined neutron diffraction and first-principles study. J Phys Chem Lett 1(13):1946–1951. https://​doi.​org/​10.​1021/​jz100558r CrossRef
Metadaten
Titel
CO2 Storage on Metal-Organic Frameworks
verfasst von
Yunsheng Ma
Hideki Tanaka
Ryotaro Matsuda
Copyright-Jahr
2019
Verlag
Springer Singapore
DOI
https://doi.org/10.1007/978-981-13-3504-4_12