Skip to main content
Erschienen in: Journal of Polymer Research 5/2021

01.05.2021 | ORIGINAL PAPER

CoFe2O4@methylcellulose synthesized as a new magnetic nanocomposite to tetracycline adsorption: modeling, analysis, and optimization by response surface methodology

verfasst von: Alireza Nasiri, Mohammad Malakootian, Marziyeh Ansari Shiri, Ghazal Yazdanpanah, Majid Nozari

Erschienen in: Journal of Polymer Research | Ausgabe 5/2021

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config
loading …

Abstract

In this study, CoFe2O4@methycellulose (MC) was prepared as a novel magnetic nanocomposite by a facile, fast, and new microwave-assisted method using iron and cobalt salts in the presence of MC as a green biopolymer in alkaline medium and was then structurally evaluated by FESEM, EDS, Mapping, BET, VSM, XRD, TGA, and FTIR. Effective parameters on tetracycline (TC) removal such as pH, initial TC concentration, adsorbent dosage, and contact time were examined. The central composite design (CCD)–based response surface methodology (RSM) was employed to design the experiments and find optimal conditions. CoFe2O4@MC was synthesized with the particle size of about 50 nm, magnetic properties, and high specific surface area. The maximum TC adsorption efficiencies using CoFe2O4@MC from synthetic and real wastewater samples under optimal conditions were 79.45% and 74.85%, respectively. The data of TC adsorption on CoFe2O4@MC were fitted well with pseudo–second order kinetic and Langmuir isotherm models. The results of thermodynamic data indicated the exothermic and spontaneous nature of TC adsorption process using CoFe2O4@MC. CoFe2O4@MC showed high efficiency and chemical stability after 5 runs. Therefore, CoFe2O4@MC nanocomposite can be applied as a good and practical adsorbent for removing TC from synthetic and real wastewater.

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Literatur
11.
Zurück zum Zitat Amirmahani N, Mahdizadeh H, Malakootian M, Pardakhty A, Mahmoodi N (2020) Evaluating Nanoparticles Decorated on Fe3O4@SiO2-Schiff Base (Fe3O4@SiO2-APTMS-HBA) in Adsorption of Ciprofloxacin from Aqueous Environments. J Inorg Organometallic Polym Mater 30(9):3540–3551. https://doi.org/10.1007/s10904-020-01499-5CrossRef Amirmahani N, Mahdizadeh H, Malakootian M, Pardakhty A, Mahmoodi N (2020) Evaluating Nanoparticles Decorated on Fe3O4@SiO2-Schiff Base (Fe3O4@SiO2-APTMS-HBA) in Adsorption of Ciprofloxacin from Aqueous Environments. J Inorg Organometallic Polym Mater 30(9):3540–3551. https://​doi.​org/​10.​1007/​s10904-020-01499-5CrossRef
13.
19.
Zurück zum Zitat Nasiri A, Tamaddon F, Mosslemin MH, Amiri Gharaghani M, Asadipour A (2019) Magnetic nano-biocomposite CuFe2O4@methylcellulose (MC) prepared as a new nano-photocatalyst for degradation of ciprofloxacin from aqueous solution, Environ Health Eng. Manag J 6(1): 41–51. https://doi.org/10.15171/ehem.2019.05. Nasiri A, Tamaddon F, Mosslemin MH, Amiri Gharaghani M, Asadipour A (2019) Magnetic nano-biocomposite CuFe2O4@methylcellulose (MC) prepared as a new nano-photocatalyst for degradation of ciprofloxacin from aqueous solution, Environ Health Eng. Manag J 6(1): 41–51. https://​doi.​org/​10.​15171/​ehem.​2019.​05.
31.
Zurück zum Zitat Foroughi M, Rahmani AR, Asgari G, Nematollahi D, Yetilmezsoy K, Samarghandi MR (2019) Optimization and Modeling of Tetracycline Removal from Wastewater by Three-Dimensional Electrochemical System: Application of Response Surface Methodology and Least Squares Support Vector Machine. Environ Model Assess 25:327–341. https://doi.org/10.1007/s10666-019-09675-9CrossRef Foroughi M, Rahmani AR, Asgari G, Nematollahi D, Yetilmezsoy K, Samarghandi MR (2019) Optimization and Modeling of Tetracycline Removal from Wastewater by Three-Dimensional Electrochemical System: Application of Response Surface Methodology and Least Squares Support Vector Machine. Environ Model Assess 25:327–341. https://​doi.​org/​10.​1007/​s10666-019-09675-9CrossRef
34.
35.
40.
Zurück zum Zitat De Carvalho OG, Filho GR, Vieira JG, De Assunção RM, da Silva MC, Cerqueira DA, de Oliveira RJ, Silva WG, De Castro Motta LA (2010) Synthesis and application of methylcellulose extracted from waste newspaper in CPV-ARI Portland cement mortars. J Appl Polym Sci 118(3):1380–1385. https://doi.org/10.1002/app.32477CrossRef De Carvalho OG, Filho GR, Vieira JG, De Assunção RM, da Silva MC, Cerqueira DA, de Oliveira RJ, Silva WG, De Castro Motta LA (2010) Synthesis and application of methylcellulose extracted from waste newspaper in CPV-ARI Portland cement mortars. J Appl Polym Sci 118(3):1380–1385. https://​doi.​org/​10.​1002/​app.​32477CrossRef
51.
Zurück zum Zitat Malakootian M, Bahraini S, Zarrabi M, Malakootian M (2016) Removal of Tetracycline antibiotic from aqueous solutions using natural and modified pumice with magnesium chloride, Adv Environ Biol 10: 46–56. https://doi.org/10.17795/jjhr-37583. Malakootian M, Bahraini S, Zarrabi M, Malakootian M (2016) Removal of Tetracycline antibiotic from aqueous solutions using natural and modified pumice with magnesium chloride, Adv Environ Biol 10: 46–56. https://​doi.​org/​10.​17795/​jjhr-37583.
67.
Metadaten
Titel
CoFe2O4@methylcellulose synthesized as a new magnetic nanocomposite to tetracycline adsorption: modeling, analysis, and optimization by response surface methodology
verfasst von
Alireza Nasiri
Mohammad Malakootian
Marziyeh Ansari Shiri
Ghazal Yazdanpanah
Majid Nozari
Publikationsdatum
01.05.2021
Verlag
Springer Netherlands
Erschienen in
Journal of Polymer Research / Ausgabe 5/2021
Print ISSN: 1022-9760
Elektronische ISSN: 1572-8935
DOI
https://doi.org/10.1007/s10965-021-02540-y

Weitere Artikel der Ausgabe 5/2021

Journal of Polymer Research 5/2021 Zur Ausgabe

    Marktübersichten

    Die im Laufe eines Jahres in der „adhäsion“ veröffentlichten Marktübersichten helfen Anwendern verschiedenster Branchen, sich einen gezielten Überblick über Lieferantenangebote zu verschaffen.