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Cellulose

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08.09.2017 | Original Paper

Comparative characteristics of TEMPO-oxidized cellulose nanofibers and resulting nanopapers from bamboo, softwood, and hardwood pulps

verfasst von: Yufei Chen, Biyao Geng, Jing Ru, Congcong Tong, Hongzhi Liu, Jinzhou Chen

Erschienen in: Cellulose | Ausgabe 11/2017

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Abstract

Bamboo, softwood, and hardwood pulp fibers were used as starting materials to prepare TEMPO-oxidized nanofibrillated cellulose (TO-NFC) dispersions. The resulting TO-NFC dispersions were then used to fabricate cellulose nanopapers and to coat poly(lactic acid) (PLA) films. The chemical and morphological characteristics of the dispersions together with the physical properties of the resultant nanopaper and PLA films were systematically compared. The maximum degree of oxidation was achieved for the bamboo pulp fiber. Transmission electron microscopy micrographs revealed that the oxidized pulp fibers were successfully disintegrated into cellulose nanofibrils with an average width of 5–6 nm. However, bamboo-derived TO-NFC was more densely entangled and crimped, with a heterogeneous distribution in width. It was further revealed that morphologies of the obtained TO-NFC may arise from the organizational structure of microfibrils in the cellulose fibers rather than the presence of hemicelluloses or the pulping process. The PLA films coated with a thin layer of TO-NFC from the bamboo pulp exhibited the highest oxygen-barrier property, which was even slightly higher than commercial ethylene–vinyl alcohol copolymer film, known for its high oxygen-barrier functionality.

Vorheriger Artikel Charge reversal system with cationized cellulose nanocrystals to promote dewatering of a cellulosic fiber suspension

Nächster Artikel Enhanced dispersion and interface compatibilization of crystalline nanocellulose in polylactide by surfactant adsorption

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Titel: Comparative characteristics of TEMPO-oxidized cellulose nanofibers and resulting nanopapers from bamboo, softwood, and hardwood pulps
verfasst von: Yufei Chen
Biyao Geng
Jing Ru
Congcong Tong
Hongzhi Liu
Jinzhou Chen
Publikationsdatum: 08.09.2017
Verlag: Springer Netherlands
Erschienen in: Cellulose / Ausgabe 11/2017
Print ISSN: 0969-0239
Elektronische ISSN: 1572-882X
DOI: https://doi.org/10.1007/s10570-017-1478-4

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