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Journal of Materials Science: Materials in Electronics
Erschienen in: Journal of Materials Science: Materials in Electronics 13/2019

04.06.2019

Comparative study of La0.6R0.1Ca0.3Mn0.9Cr0.1O3 (R = La, Eu and Ho) nanoparticles: effect of A-cation size and sintering temperature

verfasst von: Mukesh Kumar Verma, Narayan Dutt Sharma, Nisha Choudhary, Suman Sharma, Devinder Singh

Erschienen in: Journal of Materials Science: Materials in Electronics | Ausgabe 13/2019

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Abstract

A systematic study of nanocrystalline La0.6R0.1Ca0.3Mn0.9Cr0.1O3 (R = La, Eu and Ho) manganites has been undertaken to analyse the effect of sintering temperature and A-site cation radius on the structural and magnetic properties. In order to acquire a series of samples with different particle sizes, the samples were prepared by a solution combustion method and were subjected to annealing at four different temperatures. Rietveld analysis of X-ray diffraction (XRD) data confirmed the presence of orthorhombic symmetry with Pbnm space group for all the samples. The grain size retrieved from the TEM analysis is greater than the noted crystallite size calculated from XRD by the Scherrer’s equation. A paramagnetic-ferromagnetic transition is shown by all our investigated compounds at low temperature. With increasing sintering temperature or particle size, the Curie temperature (Tc) was found to increase, which is attributed to the magnetically disordered surface layer. All the phases obey Curie–Weiss law in the high temperature region and the effective magnetic moment calculated from the high temperature paramagnetic region shows an increase with sintering temperature.
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Metadaten
Titel
Comparative study of La0.6R0.1Ca0.3Mn0.9Cr0.1O3 (R = La, Eu and Ho) nanoparticles: effect of A-cation size and sintering temperature
verfasst von
Mukesh Kumar Verma
Narayan Dutt Sharma
Nisha Choudhary
Suman Sharma
Devinder Singh
Publikationsdatum
04.06.2019
Verlag
Springer US
Erschienen in
Journal of Materials Science: Materials in Electronics / Ausgabe 13/2019
Print ISSN: 0957-4522
Elektronische ISSN: 1573-482X
DOI
https://doi.org/10.1007/s10854-019-01591-8

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