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Erschienen in: Journal of Materials Science: Materials in Electronics 6/2017

29.11.2016

Composition dependence of phase boundary and electrical properties in lead-free (K0.5Na0.5)(Nb0.96Sb0.04)O3–Bi0.5Na0.5ZrO3–Bi0.5Li0.5ZrO3 ceramics

verfasst von: Ting Mei, Tao Chen, Yuhong Liu, Jianwei Zhang, Ting Zhang, Guangchang Wang, Jifang Zhou

Erschienen in: Journal of Materials Science: Materials in Electronics | Ausgabe 6/2017

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Abstract

In this work, (K0.5Na0.5)(Nb0.96Sb0.04)O3–Bi0.5Na0.5ZrO3–Bi0.5Li0.5ZrO3 lead-free ceramics were fabricated by the conventional solid-state method, and effects of Bi0.5Li0.5ZrO3 on their phase structure and electrical properties were studied. Their piezoelectric properties are sensitive to the addition of Bi0.5Li0.5ZrO3 as well as its contents. The addition of Bi0.5Li0.5ZrO3 simultaneously increased their Curie temperature and decreased rhombohedral and tetragonal phase transition temperature. Their dielectric, ferroelectric, and piezoelectric properties were strongly dependent on Bi0.5Li0.5ZrO3 contents. With increasing Bi0.5Li0.5ZrO3 contents, their dielectric loss can be decreased, and their k p and P r values can be further optimized. However, their ε r and d 33 slightly decreased with the increase of Bi0.5Li0.5ZrO3 contents due to the deviation of rhombohedral and tetragonal phase boundary, and the ceramics with x ≤ 0.2 exhibited a high d 33 of >410 pC/N. As a result, this work could further understand the role of Bi0.5Li0.5ZrO3 in electrical properties of high-performance alkali niobate ceramics.

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Metadaten
Titel
Composition dependence of phase boundary and electrical properties in lead-free (K0.5Na0.5)(Nb0.96Sb0.04)O3–Bi0.5Na0.5ZrO3–Bi0.5Li0.5ZrO3 ceramics
verfasst von
Ting Mei
Tao Chen
Yuhong Liu
Jianwei Zhang
Ting Zhang
Guangchang Wang
Jifang Zhou
Publikationsdatum
29.11.2016
Verlag
Springer US
Erschienen in
Journal of Materials Science: Materials in Electronics / Ausgabe 6/2017
Print ISSN: 0957-4522
Elektronische ISSN: 1573-482X
DOI
https://doi.org/10.1007/s10854-016-6135-4

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