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Erschienen in: Journal of Sol-Gel Science and Technology 3/2019

23.01.2019 | Original Paper: Sol–gel and hybrid materials with surface modification for applications

Construction of a double-layered polyelectrolyte-coated mesoporous silica containing residues of biogenic aspartic acid and its utilization for cadmium (II) removal

verfasst von: Zakariyah A. Jamiu, Shaikh A. Ali

Erschienen in: Journal of Sol-Gel Science and Technology | Ausgabe 3/2019

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Abstract

Highly efficient porous adsorbent has been developed by simple and inexpensive surface modification of mesoporous SBA-15 via an alternate adsorption of cationic poly(diallyldimethylammonium ion) and anionic poly(diallylaspartate). The nature of the charge on the surface after modification was confirmed by Zeta potential measurement. The surface morphology, topography, and its textural properties were examined by atomic force microscopy (AFM) and Nitrogen adsorption/desorption, respectively. TGA has been performed to ascertain the amount of polymer layer on the silica material. Multi-parameter isotherm models were used for the analyses of experimental data. The new protocol is found to be very impressive in the removal of toxic Cd(II) pollutant with an experimental maximum uptake capacity of 160 mg g–1.

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Literatur
1.
Zurück zum Zitat Järup L, Åkesson A (2009) Current status of cadmium as an environmental health problem. Toxicol Appl Pharmacol 238:201–208.CrossRef Järup L, Åkesson A (2009) Current status of cadmium as an environmental health problem. Toxicol Appl Pharmacol 238:201–208.CrossRef
2.
Zurück zum Zitat Peters JL, Perlstein TS, Perry MJ, McNeely E, Weuve J (2010) Cadmium exposure in association with history of stroke and heart failure. Environ Res 110:199–206.CrossRef Peters JL, Perlstein TS, Perry MJ, McNeely E, Weuve J (2010) Cadmium exposure in association with history of stroke and heart failure. Environ Res 110:199–206.CrossRef
3.
Zurück zum Zitat Biswas B, Sarkar B, Mandal A, Naidu R (2016) Specific adsorption of cadmium on surface-engineered biocompatible organoclay under metal-phenanthrene mixed-contamination. Water Res 104:119–127.CrossRef Biswas B, Sarkar B, Mandal A, Naidu R (2016) Specific adsorption of cadmium on surface-engineered biocompatible organoclay under metal-phenanthrene mixed-contamination. Water Res 104:119–127.CrossRef
4.
Zurück zum Zitat Chen YY, Yu SH, Jiang HF, Yao QZ, Fu SQ, Zhou GT (2018) Performance and mechanism of simultaneous removal of Cd(II) and Congo red from aqueous solution by hierarchical vaterite spherulites. Appl Surf Sci 444:224–234.CrossRef Chen YY, Yu SH, Jiang HF, Yao QZ, Fu SQ, Zhou GT (2018) Performance and mechanism of simultaneous removal of Cd(II) and Congo red from aqueous solution by hierarchical vaterite spherulites. Appl Surf Sci 444:224–234.CrossRef
5.
Zurück zum Zitat Novacek M, Jankovsky O, Luxa J, Sedmidubsky D, Pumera M, Fila V et al. (2017) Tuning of graphene oxide composition by multiple oxidations for carbon dioxide storage and capture of toxic metals J Mater Chem A 5:2739–2748.CrossRef Novacek M, Jankovsky O, Luxa J, Sedmidubsky D, Pumera M, Fila V et al. (2017) Tuning of graphene oxide composition by multiple oxidations for carbon dioxide storage and capture of toxic metals J Mater Chem A 5:2739–2748.CrossRef
6.
Zurück zum Zitat Hossein Beyki M, Ghasemi MH, Jamali A, Shemirani F (2017) A novel polylysine–resorcinol base γ-alumina nanotube hybrid material for effective adsorption/preconcentration of cadmium from various matrices. J Ind Eng Chem 46:165–174.CrossRef Hossein Beyki M, Ghasemi MH, Jamali A, Shemirani F (2017) A novel polylysine–resorcinol base γ-alumina nanotube hybrid material for effective adsorption/preconcentration of cadmium from various matrices. J Ind Eng Chem 46:165–174.CrossRef
7.
Zurück zum Zitat Das SK, Wang X, Ostwal MM, Lai Z (2016) A highly stable microporous covalent imine network adsorbent for natural gas upgrading and flue gas CO2 capture. Sep Purif Technol 170:68–77.CrossRef Das SK, Wang X, Ostwal MM, Lai Z (2016) A highly stable microporous covalent imine network adsorbent for natural gas upgrading and flue gas CO2 capture. Sep Purif Technol 170:68–77.CrossRef
8.
Zurück zum Zitat Marczewski AW, Derylo-Marczewska A, Skrzypek I, Pikus S, Kozak M (2009) Study of structure properties of organized silica sorbents synthesized on polymeric templates. Adsorption 15:300–305.CrossRef Marczewski AW, Derylo-Marczewska A, Skrzypek I, Pikus S, Kozak M (2009) Study of structure properties of organized silica sorbents synthesized on polymeric templates. Adsorption 15:300–305.CrossRef
9.
Zurück zum Zitat Beck JS, Vartuli JC, Roth WJ, Leonowicz ME, Kresge CT, Schmitt KD et al. (1992) A new family of mesoporous molecular sieves prepared with liquid crystal templates J Am Chem Soc 114:10834–10843.CrossRef Beck JS, Vartuli JC, Roth WJ, Leonowicz ME, Kresge CT, Schmitt KD et al. (1992) A new family of mesoporous molecular sieves prepared with liquid crystal templates J Am Chem Soc 114:10834–10843.CrossRef
10.
Zurück zum Zitat Feng X, Fryxell GE, Wang L-Q, Kim AY, Liu J, Kemner KM (1997) Functionalized Monolayers on Ordered Mesoporous Supports. Science (80) 276:923–926.CrossRef Feng X, Fryxell GE, Wang L-Q, Kim AY, Liu J, Kemner KM (1997) Functionalized Monolayers on Ordered Mesoporous Supports. Science (80) 276:923–926.CrossRef
11.
Zurück zum Zitat Walcarius A, Mercier L (2010) Mesoporous organosilica adsorbents: nanoengineered materials for removal of organic and inorganic pollutants. J Mater Chem 20:4478–4511.CrossRef Walcarius A, Mercier L (2010) Mesoporous organosilica adsorbents: nanoengineered materials for removal of organic and inorganic pollutants. J Mater Chem 20:4478–4511.CrossRef
12.
Zurück zum Zitat Yantasee W, Rutledge RD, Chouyyok W, Sukwarotwat V, Orr G, Warner CL et al. (2010) Functionalized nanoporous silica for the removal of heavy metals from biological systems: adsorption and application ACS Appl Mater Interfaces 2:2749–2758.CrossRef Yantasee W, Rutledge RD, Chouyyok W, Sukwarotwat V, Orr G, Warner CL et al. (2010) Functionalized nanoporous silica for the removal of heavy metals from biological systems: adsorption and application ACS Appl Mater Interfaces 2:2749–2758.CrossRef
13.
Zurück zum Zitat Netzer LSJ (1983) ω-Hexadecenyltrichlorosilane has proven to be a useful, modifiable, siloxy-anchored amphiphile. J Am Chem Soc 105:674–676.CrossRef Netzer LSJ (1983) ω-Hexadecenyltrichlorosilane has proven to be a useful, modifiable, siloxy-anchored amphiphile. J Am Chem Soc 105:674–676.CrossRef
15.
Zurück zum Zitat Dragan ES, Schwarz S, Eichhorn K-J (2010) Specific effects of the counterion type and concentration on the construction and morphology of polycation/azo dye multilayers. Colloids Surf A 372:210–216.CrossRef Dragan ES, Schwarz S, Eichhorn K-J (2010) Specific effects of the counterion type and concentration on the construction and morphology of polycation/azo dye multilayers. Colloids Surf A 372:210–216.CrossRef
16.
Zurück zum Zitat Yasmin T, Müller K (2011) Synthesis and characterization of surface modified SBA-15 silica materials and their application in chromatography. J Chromatogr A 1218:6464–6475.CrossRef Yasmin T, Müller K (2011) Synthesis and characterization of surface modified SBA-15 silica materials and their application in chromatography. J Chromatogr A 1218:6464–6475.CrossRef
17.
Zurück zum Zitat Jamiu ZA, Al-Muallem HA, Ali SA (2015) Aspartic acid in a new role: Synthesis and application of a pH-responsive cyclopolymer containing residues of the amino acid. React Funct Polym 93:120–129.CrossRef Jamiu ZA, Al-Muallem HA, Ali SA (2015) Aspartic acid in a new role: Synthesis and application of a pH-responsive cyclopolymer containing residues of the amino acid. React Funct Polym 93:120–129.CrossRef
18.
Zurück zum Zitat Zhao D, Huo Q, Feng J, Chmelka BF, Stucky GD (1998) Nonionic triblock and star diblock copolymer and oligomeric surfactant syntheses of highly ordered, hydrothermally stable, mesoporous silica structures. J Am Chem Soc 120:6024–6036.CrossRef Zhao D, Huo Q, Feng J, Chmelka BF, Stucky GD (1998) Nonionic triblock and star diblock copolymer and oligomeric surfactant syntheses of highly ordered, hydrothermally stable, mesoporous silica structures. J Am Chem Soc 120:6024–6036.CrossRef
19.
Zurück zum Zitat Zhao D, Feng J, Huo Q, Melosh N, Fredrickson GH, Chmelka BF et al. (1998) Triblock copolymer syntheses of mesoporous silica with periodic 50 to 300 Angstrom pores Science (80) 279:548–552CrossRef Zhao D, Feng J, Huo Q, Melosh N, Fredrickson GH, Chmelka BF et al. (1998) Triblock copolymer syntheses of mesoporous silica with periodic 50 to 300 Angstrom pores Science (80) 279:548–552CrossRef
20.
Zurück zum Zitat HP B (1966) Chemical identification of surface groups. In: Eley, DD, Pines Herman WPB (eds) Advances in catalysis. Academic Press Inc., New York, pp. 179–274. HP B (1966) Chemical identification of surface groups. In: Eley, DD, Pines Herman WPB (eds) Advances in catalysis. Academic Press Inc., New York, pp. 179–274.
21.
Zurück zum Zitat Salis A, Parsons DF, Boström M, Medda L, Barse B, Ninham BW et al. (2010) Ion specific surface charge density of SBA-15 mesoporous silica Langmuir 26:2484–2490.CrossRef Salis A, Parsons DF, Boström M, Medda L, Barse B, Ninham BW et al. (2010) Ion specific surface charge density of SBA-15 mesoporous silica Langmuir 26:2484–2490.CrossRef
22.
Zurück zum Zitat Boehm HP (1994) Some aspects of the surface-chemistry of carbonblacks and other. Carbons Carbon N Y 32:759–69.CrossRef Boehm HP (1994) Some aspects of the surface-chemistry of carbonblacks and other. Carbons Carbon N Y 32:759–69.CrossRef
23.
Zurück zum Zitat Leonardelli S, Facchini L, Fretigny C, Tougne P, Legrand AP (1992) Silicon-29 NMR study of silica. J Am Chem Soc 114:6412–6418.CrossRef Leonardelli S, Facchini L, Fretigny C, Tougne P, Legrand AP (1992) Silicon-29 NMR study of silica. J Am Chem Soc 114:6412–6418.CrossRef
24.
Zurück zum Zitat Sindorf DW, Maciel GE (1981) Silicon-29 CP/MAS NMR studies of methylchlorosilane reactions on silica gel. J Am Chem Soc 103:4263–4265.CrossRef Sindorf DW, Maciel GE (1981) Silicon-29 CP/MAS NMR studies of methylchlorosilane reactions on silica gel. J Am Chem Soc 103:4263–4265.CrossRef
25.
Zurück zum Zitat Maciel GE, Sindorf DW (1980) Silicon-29 NMR study of the surface of silica gel by cross polarization and magic-angle spinning. J Am Chem Soc 102:7606–7607.CrossRef Maciel GE, Sindorf DW (1980) Silicon-29 NMR study of the surface of silica gel by cross polarization and magic-angle spinning. J Am Chem Soc 102:7606–7607.CrossRef
26.
Zurück zum Zitat Sindorf DW, Maciel GE (1983) Silicon-29 NMR study of dehydrated/rehydrated silica gel using cross polarization and magic-angle spinning. J Am Chem Soc 105:1487–1493.CrossRef Sindorf DW, Maciel GE (1983) Silicon-29 NMR study of dehydrated/rehydrated silica gel using cross polarization and magic-angle spinning. J Am Chem Soc 105:1487–1493.CrossRef
27.
Zurück zum Zitat Legrand AP, Hommel H, Taïbi H, Miquel JL, Tougne P (1990) Contribution of solid state NMR spectroscopy to the characterization of materials. Colloids Surf 45:391–411.CrossRef Legrand AP, Hommel H, Taïbi H, Miquel JL, Tougne P (1990) Contribution of solid state NMR spectroscopy to the characterization of materials. Colloids Surf 45:391–411.CrossRef
28.
Zurück zum Zitat Grünberg A, Yeping X, Breitzke H, Buntkowsky G (2010) Solid-state NMR characterization of Wilkinson’s catalyst immobilized in mesoporous SBA-3 silica. Chemistry 16:6993–8.CrossRef Grünberg A, Yeping X, Breitzke H, Buntkowsky G (2010) Solid-state NMR characterization of Wilkinson’s catalyst immobilized in mesoporous SBA-3 silica. Chemistry 16:6993–8.CrossRef
29.
Zurück zum Zitat Groen JC, Peffer LA, Pérez-Ramı́rez J (2003) Pore size determination in modified micro- and mesoporous materials. Pitfalls and limitations in gas adsorption data analysis. Microporous Mesoporous Mater 60:1–17.CrossRef Groen JC, Peffer LA, Pérez-Ramı́rez J (2003) Pore size determination in modified micro- and mesoporous materials. Pitfalls and limitations in gas adsorption data analysis. Microporous Mesoporous Mater 60:1–17.CrossRef
30.
Zurück zum Zitat Jaroniec C, Gilpin R, Jaroniec M (1997) Adsorption and thermogravimetric studies of silica-based amide bonded phases. J Phys 44242:6861–6866. Jaroniec C, Gilpin R, Jaroniec M (1997) Adsorption and thermogravimetric studies of silica-based amide bonded phases. J Phys 44242:6861–6866.
31.
Zurück zum Zitat Iler RK (1979) The chemistry of silica: solubility, polymerization, colloid and surface properties and biochemistry. John Wiley, New York. Iler RK (1979) The chemistry of silica: solubility, polymerization, colloid and surface properties and biochemistry. John Wiley, New York.
32.
Zurück zum Zitat Erto A, Di Natale F, Musmarra D, Lancia A (2015) Modeling of single and competitive adsorption of cadmium and zinc onto activated carbon. Adsorption 21:611–621.CrossRef Erto A, Di Natale F, Musmarra D, Lancia A (2015) Modeling of single and competitive adsorption of cadmium and zinc onto activated carbon. Adsorption 21:611–621.CrossRef
33.
Zurück zum Zitat Huang J, Yuan F, Zeng G, Li X, Gu Y, Shi L et al. (2017) Influence of pH on heavy metal speciation and removal from wastewater using micellar-enhanced ultrafiltration Chemosphere 173:199–206.CrossRef Huang J, Yuan F, Zeng G, Li X, Gu Y, Shi L et al. (2017) Influence of pH on heavy metal speciation and removal from wastewater using micellar-enhanced ultrafiltration Chemosphere 173:199–206.CrossRef
34.
Zurück zum Zitat Abbas M, Kaddour S, Trari M (2014) Kinetic and equilibrium studies of cobalt adsorption on apricot stone activated carbon. J Ind Eng Chem 20:745–751.CrossRef Abbas M, Kaddour S, Trari M (2014) Kinetic and equilibrium studies of cobalt adsorption on apricot stone activated carbon. J Ind Eng Chem 20:745–751.CrossRef
35.
Zurück zum Zitat Morris WJW, JC (1963) Intraparticle diffusion during the sorption of surfactants onto activated carbon. Eng Div Am Soc Civ Eng 89:31–60. Morris WJW, JC (1963) Intraparticle diffusion during the sorption of surfactants onto activated carbon. Eng Div Am Soc Civ Eng 89:31–60.
36.
Zurück zum Zitat Kavitha D, Namasivayam C (2007) Experimental and kinetic studies on methylene blue adsorption by coir pith carbon. Bioresour Technol 98:14–21.CrossRef Kavitha D, Namasivayam C (2007) Experimental and kinetic studies on methylene blue adsorption by coir pith carbon. Bioresour Technol 98:14–21.CrossRef
37.
Zurück zum Zitat Wu F-C, Tseng R-L, Juang R-S (2009) Initial behavior of intraparticle diffusion model used in the description of adsorption kinetics. Chem Eng J 153:1–8.CrossRef Wu F-C, Tseng R-L, Juang R-S (2009) Initial behavior of intraparticle diffusion model used in the description of adsorption kinetics. Chem Eng J 153:1–8.CrossRef
38.
Zurück zum Zitat Ho YS, Porter JF, Mckay G (2002) Divalent metal ions onto peat: copper, nickel and lead single component systems. Water Air Soil Pollut 141:1–33.CrossRef Ho YS, Porter JF, Mckay G (2002) Divalent metal ions onto peat: copper, nickel and lead single component systems. Water Air Soil Pollut 141:1–33.CrossRef
39.
Zurück zum Zitat Lima EC, Adebayo MA, Machado FM (2015) In: Bergmann CP, Machado FM (eds.) Carbon nanomaterials as adsorbents for environmental and biological applications, Springer International Publishing, Switzerland, pp. 33–69. Lima EC, Adebayo MA, Machado FM (2015) In: Bergmann CP, Machado FM (eds.) Carbon nanomaterials as adsorbents for environmental and biological applications, Springer International Publishing, Switzerland, pp. 33–69.
Metadaten
Titel
Construction of a double-layered polyelectrolyte-coated mesoporous silica containing residues of biogenic aspartic acid and its utilization for cadmium (II) removal
verfasst von
Zakariyah A. Jamiu
Shaikh A. Ali
Publikationsdatum
23.01.2019
Verlag
Springer US
Erschienen in
Journal of Sol-Gel Science and Technology / Ausgabe 3/2019
Print ISSN: 0928-0707
Elektronische ISSN: 1573-4846
DOI
https://doi.org/10.1007/s10971-019-04920-9

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